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公开(公告)号：US20240166523A1
公开(公告)日：2024-05-23
申请号：US18522842
申请日：2023-11-29
CPC分类号： C01B32/50 , B01J23/80 , C07C29/154 , C25B1/23 , C25B9/19 , C25B13/07 , C25B15/081
摘要： A method of treating a brine composition includes hydrolyzing a metal halide salt in the brine composition to form a hydrolysis product including a hydrohalic acid. The metal includes an alkaline earth metal or an alkali metal.
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公开(公告)号：US11878287B2
公开(公告)日：2024-01-23
申请号：US17570655
申请日：2022-01-07
申请人： QATAR UNIVERSITY
发明人： Sardar Ali , Dharmesh Kumar , Muftah El-Naas
IPC分类号： B01J21/04 , B01J23/06 , B01J23/10 , B01J23/72 , B01J23/80 , B01J23/83 , B01J35/02 , B01J35/10 , B01J37/04 , B01J37/18 , B01J6/00 , C07C29/154 , B82Y40/00 , B82Y30/00
CPC分类号： B01J23/83 , B01J6/001 , B01J21/04 , B01J35/023 , B01J35/1014 , B01J37/04 , B01J37/18 , C07C29/154 , B82Y30/00 , B82Y40/00 , C07C2523/83
摘要： This invention relates to development of novel Cu-based nanocatalysts synthesized via one-pot solution combustion synthesis for CO2 hydrogenation to methanol. The novel Cu-based catalyst has exceptional activity for CO2 hydrogenation with high methanol selectivity in the reaction temperature range between 250° C.-350° C. The novel catalyst also exhibits excellent resilience to deactivation due to sintering.
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公开(公告)号：US11858819B2
公开(公告)日：2024-01-02
申请号：US18170392
申请日：2023-02-16
CPC分类号： C01B32/50 , B01J23/80 , C07C29/154 , C25B1/23 , C25B9/19 , C25B13/07 , C25B15/081
摘要： A method of producing a syngas composition includes hydrolyzing a metal halide salt to form a hydrohalic acid and a hydroxide salt of the metal in the metal halide salt. The metal includes an alkaline earth metal or an alkali metal. The method includes reacting the hydrohalic acid with a metal carbonate salt, wherein the metal carbonate salt is a carbonate salt of the alkaline earth metal or alkali metal, to form CO2 and the metal halide salt. At least some of the metal halide salt formed from the reacting of the hydrohalic acid with the metal carbonate salt is recycled as at least some of the metal halide salt in the hydrolyzing of the metal halide salt to form the hydrohalic acid and the hydroxide salt. The method also includes electrolytically converting the CO2 and the water into the syngas composition including carbon monoxide and hydrogen.
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公开(公告)号：US11773039B2
公开(公告)日：2023-10-03
申请号：US17937099
申请日：2022-09-30
发明人： Siva Rama Krishna Garapati , Meeta Sharma , Mani Ramya , Rajesh Muralidhar Badhe , Alok Sharma , Gurpreet Kapur Singh , Sankara Sri Venkata Ramakumar
IPC分类号： C07C29/151 , C01B3/16 , C07C29/154
CPC分类号： C07C29/1518 , C01B3/16 , C07C29/154 , C01B2203/061 , C01B2203/1076
摘要： The present disclosure provides an integrated process and a Cu/Zn-based catalyst system for synthesizing methanol from CO2 and generating electricity from hydrocarbon feedstock. The process includes steps of gasifying hydrocarbon feedstock into syngas by using oxygen and using the produced syngas as a fuel in a power generation unit, reusing a first part of an exhaust stream of the power generation unit as a reactant in the gasification unit. Using a second part of the said exhaust stream as a reactant for methanol synthesis in a methanol reactor, wherein, the second part is treated to separate CO2 and water, and CO2 is used as the reactant for methanol synthesis. Operating an electrolyzer during non-peak hours to produce hydrogen, wherein, a required stoichiometric ratio of the produced hydrogen is transferred into the methanol reactor for methanol synthesis, wherein, a Cu/Zn-based catalyst system is used for methanol synthesis through a direct hydrogenation reaction of CO2.
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公开(公告)号：US20230265028A1
公开(公告)日：2023-08-24
申请号：US18040990
申请日：2020-09-14
发明人： Richard LONG , Tian RUAN
IPC分类号： C07C29/154
CPC分类号： C07C29/154
摘要： A process for the production of propanol and/or isobutanol is disclosed. The process comprises reacting ethanol or propanol with synthesis gas in the presence of an alkali or alkaline earth doped CuMn oxide catalyst under reaction conditions to produce propanol and/or isobutanol. The catalyst may include one or more additional metal oxides as catalyst support.
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公开(公告)号：US20230192499A1
公开(公告)日：2023-06-22
申请号：US18170392
申请日：2023-02-16
CPC分类号： C01B32/50 , B01J23/80 , C07C29/154 , C25B1/23 , C25B15/081 , C25B9/19 , C25B13/07
摘要： A method of producing a syngas composition includes hydrolyzing a metal halide salt to form a hydrohalic acid and a hydroxide salt of the metal in the metal halide salt. The metal includes an alkaline earth metal or an alkali metal. The method includes reacting the hydrohalic acid with a metal carbonate salt, wherein the metal carbonate salt is a carbonate salt of the alkaline earth metal or alkali metal, to form CO2 and the metal halide salt. At least some of the metal halide salt formed from the reacting of the hydrohalic acid with the metal carbonate salt is recycled as at least some of the metal halide salt in the hydrolyzing of the metal halide salt to form the hydrohalic acid and the hydroxide salt. The method also includes electrolytically converting the CO2 and the water into the syngas composition including carbon monoxide and hydrogen.
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公开(公告)号：US11602734B2
公开(公告)日：2023-03-14
申请号：US16993219
申请日：2020-08-13
发明人： Chuansheng Bai , Majosefina Cunningham , Jihad M. Dakka , Preeti Kamakoti , Aruna Ramkrishnan , Anjaneya S. Kovvali , Anita S. Lee
IPC分类号： B01J29/06 , B01J23/80 , C07C41/01 , B01J29/46 , B01J27/188 , B01J27/19 , B01J35/02 , B01J35/10 , B01J37/04 , B01J37/08 , B01J37/10 , B01J37/00 , B01J37/18 , B01J21/04 , C07C31/04 , C07C43/04 , C07C29/154
摘要： A method of producing a acid/metal bifunctional catalyst may include: mixing an acid catalyst, a metal catalyst, and a fluid to produce a slurry, wherein the acid catalyst is present at 50 wt % or less relative to a total catalyst weight in the slurry; heating the slurry; producing a powder from the slurry; and calcining the powder to produce the acid/metal bifunctional catalyst. Such acid/metal bifunctional catalyst would be useful in the direct conversion of syngas to dimethyl ether as well as other reactions.
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公开(公告)号：US20210300848A1
公开(公告)日：2021-09-30
申请号：US17250535
申请日：2019-09-16
IPC分类号： C07C29/157 , B01J23/72 , B01J23/755 , B01J21/14 , B01J35/10 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/02 , B01J37/00 , C07C29/154 , C07C41/09
摘要： Catalysts for the production of an alcohol and/or an ether from synthesis gas, methods of making the catalysts, and uses thereof are described. The catalyst can include catalytic Cu metal particles or oxides thereof and/or Ni metal particles or oxides thereof on an alkali metal or alkaline earth metal silicate support.
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9.发明授权公开(公告)号：US11008270B2
公开(公告)日：2021-05-18
申请号：US17044579
申请日：2019-04-01
IPC分类号： C07C29/151 , C07C29/153 , C07C29/154 , C07C29/156 , C07C29/157 , C07C29/158 , C07C29/136
摘要： The present disclosure relates to a new catalytic process for the production of methanol from carbon dioxide, comprising: (1) the conversion of carbon dioxide and hydrogen to formic acid or formate salts; (2) converting the formic acid or formate salts to diformate esters of diols; (3) hydrogenating the diformate esters to methanol and diols. The diols produced from the hydrogenation reaction can be recovered and re-used to prepare the diformate esters.
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公开(公告)号：US10744489B2
公开(公告)日：2020-08-18
申请号：US16006065
申请日：2018-06-12
申请人： AXENS , IFP Energies nouvelles
发明人： Delphine Bazer-Bachi , David Chiche , Joseph Lopez , Thomas Serres , Tom Frising , Olivier Ducreux , Patrick Euzen
IPC分类号： B01J23/72 , B01J21/16 , B01J35/00 , B01J37/00 , B01J37/04 , B01J37/08 , C10L3/10 , C10G25/00 , C01B3/16 , B01D15/08 , B01D53/02 , C07C29/154 , C04B35/632 , B01D53/04 , C04B35/45 , B01D53/48 , C04B35/63
摘要： The invention relates to a method for preparing a solid comprising a step of mixing a set of compounds comprising at least two Cu2(OH)2CO3 powders of different particle sizes and at least one binder and the use of the solid prepared by means of this method.
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