利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

78 条记录 (耗时 0.019 秒)

    Process of free-radical polymerization in aqueous disperasion for the preparation of polymers
    2.
    发明申请
    Process of free-radical polymerization in aqueous disperasion for the preparation of polymers 审中-公开
    用于制备聚合物的水分散中的自由基聚合方法

    公开(公告)号：US20090306302A1

    公开(公告)日：2009-12-10

    申请号：US12308977

    申请日：2007-07-04

    申请人： Patrick Lacroix-Desmazes ,  Jeff Tonnar

    发明人： Patrick Lacroix-Desmazes ,  Jeff Tonnar

    IPC分类号： C08F271/02 ,  C08F4/04 ,  C08F4/34 ,  C08F265/02 ,  C08F279/02 ,  C08F265/04 ,  C08F261/06 ,  C08F273/00 ,  C08F275/00

    CPC分类号： C08F2/18 ,  C08F2/22 ,  C08F2/38 ,  C08F4/04 ,  C08F4/40 ,  C08F214/06 ,  C08F220/14 ,  C08F293/00 ,  C08F293/005 ,  C08F2220/1825

    摘要： Process of free-radical polymerization in aqueous dispersion for the preparation of polymers, employing (A) at least one ethylenically unsaturated monomer, one of which is employed as the principal monomer and is selected from styrene and its derivatives, acrylic acid and its derivatives, methacrylic acid and its derivatives, dienes, vinyl esters, vinyl ethers, vinylic pyridine derivatives, vinylsulphonic acid and its derivatives, vinylphosphonic acid and its derivatives, and N-vinyl monomers, (B) at least one free-radical initiator selected from diazo compounds, peroxides and dialkyldiphenylalkanes, (C) molecular iodine, and (D) at least one oxidizing agent whose solubility in water is at least 10 g/l, of which at least one may be the one (B); said process comprising the steps whereby (1) at least one fraction of each of compounds (A), (B), (C) and (D) is introduced into a reactor, and (2) the contents of the reactor are reacted while introducing into the reactor the remainder, where appropriate, of each of compounds (A), (B), (C) and (D). Process of free-radical polymerization in aqueous dispersion for the preparation of block copolymers starting from polymers prepared by the abovementioned process.

    摘要翻译： 使用（A）至少一种烯键式不饱和单体，其中一种作为主要单体使用并选自苯乙烯及其衍生物，丙烯酸及其衍生物的方法，用于制备聚合物的水性分散体中的自由基聚合方法， 甲基丙烯酸及其衍生物，二烯，乙烯基酯，乙烯基醚，乙烯基吡啶衍生物，乙烯基磺酸及其衍生物，乙烯基膦酸及其衍生物和N-乙烯基单体，（B）至少一种选自重氮化合物的自由基引发剂 ，过氧化物和二烷基二苯基烷烃，（C）分子碘，和（D）至少一种在水中的溶解度至少为10g / l的氧化剂，其中至少一种可以是（B）。 所述方法包括以下步骤：（1）将化合物（A），（B），（C）和（D）中的每一种的至少一部分引入反应器中，和（2）使反应器的内容物反应，同时 在合适的情况下，将化合物（A），（B），（C）和（D）中的每一种引入反应器中。 在通过上述方法制备的聚合物开始制备嵌段共聚物的水分散体中的自由基聚合方法。

    Process for producing fluorine-containing block copolymer
    6.
    发明授权
    Process for producing fluorine-containing block copolymer 失效
    含氟嵌段共聚物的制造方法

    公开(公告)号：US6160051A

    公开(公告)日：2000-12-12

    申请号：US315771

    申请日：1999-05-20

    申请人： Haruyoshi Tatsu ,  Yasuyoshi Hisamatsu

    发明人： Haruyoshi Tatsu ,  Yasuyoshi Hisamatsu

    IPC分类号： C08F293/00 ,  C08F261/06 ,  C08F283/06

    CPC分类号： C08F261/06 ,  C08F214/22

    摘要： A fluorine-containing copolymer having a solvent resistance and a cold resistance is produced by subjecting vinylidene fluoride and at least one of other fluorine-containing monomers to copolymerization reaction in the presence of a polyfluoropolyether having iodo groups at both terminals, represented by the following formula:I(R)pCF(CF.sub.3)O[CF.sub.2 CF(CF.sub.3)O]mRf[OCF(CF.sub.3)CF.sub.2 ]nOCF(CF.sub.3)(R)pIwherein Rf: perfluoroalkylene group of C.sub.2 -C.sub.6 ; R: alkylene group or polyfluoroalkylene group of C.sub.2 -C.sub.8 ; these alkylene groups may contain an ether bond or may be an alkyleneamide-containing or phenylene diamide-containing group; m+n: 20 or more; and p: 0 or 1. The copolymerization reaction is carried out preferably in the presence of a bromine-containing or iodine-containing monomer compound.

    摘要翻译： 具有耐溶剂性和耐寒性的含氟共聚物通过在具有两端具有碘基的多氟聚醚的存在下，将下列式（1）表示的偏二氟乙烯和其它含氟单体中的至少一种进行共聚反应来制造： ：C（CF 3）O] m R f [OCF（CF 3）CF 2] n OCF（CF 3）（R）p I其中R 1表示C 1 -C 6的全氟亚烷基; R：C2-C8的亚烷基或多氟亚烷基; 这些亚烷基可以含有醚键，也可以是含有亚烷基酰胺或亚苯基二酰胺的基团。 m + n：20以上; 和p：0或1.共聚反应优选在含溴或含碘单体化合物的存在下进行。

    Gels with thermotropic properties
    7.
    发明授权
    Gels with thermotropic properties 失效
    具有热致变性的凝胶

    公开(公告)号：US6140387A

    公开(公告)日：2000-10-31

    申请号：US101296

    申请日：1998-07-08

    申请人： Matthias Gerst

    发明人： Matthias Gerst

    IPC分类号： B32B17/10 ,  C08F2/46 ,  C08F2/50 ,  C08F261/06 ,  C08F271/00 ,  C08F271/02 ,  C09K9/02 ,  C09K3/28 ,  C08F291/12

    CPC分类号： C09K9/02 ,  C08F271/02 ,  G02F1/0147

    摘要： Gels for thermotropic layers, obtainable by irradiating a mixture comprisinga) an uncrosslinked polymer in amounts of less than 5% by weight, based on the sum of a), b) and c),b) monomers which can be polymerized by means of free radicals, andc) water or an organic solvent, or a mixture thereof,with high-energy light.

    摘要翻译： PCT No.PCT / EP97 / 00017 Sec。 371日期：1998年7月8日 102（e）日期1998年7月8日PCT 1997年1月3日PCT PCT。 出版物WO97 / 25358 日期1997年7月17日用于通过以a），b）和c）的总和照射含有a）未交联聚合物的量小于5重量％的混合物获得的凝胶，b）可以 通过自由基聚合，和c）水或有机溶剂或其混合物与高能量光。

    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase
    8.
    发明授权
    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase 失效
    具有改善接枝基质和接枝聚合物相之间的相结合的接枝共聚物

    公开(公告)号：US5384381A

    公开(公告)日：1995-01-24

    申请号：US152740

    申请日：1993-11-15

    申请人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    IPC分类号： C08F291/00 ,  C07C409/38 ,  C08F4/34 ,  C08F261/06 ,  C08F293/00 ,  C08F218/04

    CPC分类号： C08F261/06 ,  C08F293/00

    摘要： Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers.The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.

    摘要翻译： 具有改进的接枝基质和接枝聚合物之间的相结合的接枝共聚物由以下物质制备：a）接枝聚合物相，其含有一种或多种由具有1至10个碳的醇的（甲基）丙烯酸酯组成的组中的单体 原子，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基卤化物，苯乙烯和苯乙烯衍生物，和b）含有0.01-20重量％的烯属不饱和过氧化合物 其中R 1是化学键或具有1至10个碳原子的直链或支链烷基或具有3至10个碳原子的环烷基，所述通式I或II其中R 1， R2和R3是具有1至4个碳原子的烷基，R4是烷基或具有3-12个碳原子的烷基取代的苯基，R5是具有3-12个碳原子的环烷基，从80到 99.9重量％的一种或多种共聚单体f 由具有1-10个碳原子的（甲基）丙烯酸酯，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基芳族化合物，乙烯基卤化物和/或乙烯基醚构成的组中。 接枝共聚物可用作纺织工业中的粘合剂，作为热稳定粘合剂，作为膏药中的粘合剂和乳液涂料中的粘合剂。

    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase
    9.
    发明授权
    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase 失效
    具有改善接枝基质和接枝聚合物相之间的相结合的接枝共聚物

    公开(公告)号：US5304609A

    公开(公告)日：1994-04-19

    申请号：US967662

    申请日：1993-10-28

    申请人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    IPC分类号： C08F291/00 ,  C07C409/38 ,  C08F4/34 ,  C08F261/06 ,  C08F293/00 ,  C08F263/04

    CPC分类号： C08F261/06 ,  C08F293/00

    摘要： Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers.The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.

    摘要翻译： 具有改进的接枝基质和接枝聚合物之间的相结合的接枝共聚物由以下物质制备：a）接枝聚合物相，其含有一种或多种由具有1至10个碳的醇的（甲基）丙烯酸酯组成的组中的单体 原子，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基卤化物，苯乙烯和苯乙烯衍生物，和b）含有0.01-20重量％的烯属不饱和过氧化合物 通式I或II（*化学结构*）（I）或（*化学结构*）（II）其中R1是化学键或具有1-10个碳原子的直链或支链烷基链或具有 3〜10个碳原子，R2和R3为碳原子数1〜4的烷基，R4为碳原子数3〜12的烷基或烷基取代苯基，R5为碳原子数为3〜12的环烷基 原子，从80到99.9％ 一种或多种由具有1-10个碳原子的醇的（甲基）丙烯酸酯组成的组中的一种或多种共聚单体的重量，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基芳族化合物，乙烯基卤化物和/或乙烯基 醚类。 接枝共聚物可用作纺织工业中的粘合剂，作为热稳定粘合剂，作为膏药中的粘合剂和乳液涂料中的粘合剂。