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    POLYMERS COMPRISING SULFONATED 2,6-DIPHENYL-1,4-PHENYLENE OXIDE REPEATING UNITS
    8.
    发明申请
    POLYMERS COMPRISING SULFONATED 2,6-DIPHENYL-1,4-PHENYLENE OXIDE REPEATING UNITS 审中-公开

    公开(公告)号：US20200165387A1

    公开(公告)日：2020-05-28

    申请号：US16624317

    申请日：2018-07-05

    申请人： MxPolymers B.V.

    发明人： Doetze Jakob Sikkema

    IPC分类号： C08G65/48 ,  H01M8/1088 ,  H01M8/1067 ,  H01M8/1025 ,  C08J5/22

    摘要： The invention relates to polymers comprising sulfonated 2,6-diphenyl-1,4-phenylene oxide repeating units, to a method for their preparation, and to their use in a membrane electrode assembly, in a proton exchange membrane, in a fuel cell, in an electrolyser, in an electrolytic hydrogen compressor or in a flow battery. The invention further relates to a proton exchange membrane comprising said polymer and to a method for the preparation of a proton exchange membrane from said polymer. The invention also relates to the use of the polymers in ion exchange materials.

    CROSS-LINKED HIGH STABLE ANION EXCHANGE BLEND MEMBRANES WITH POLYETHYLENEGLYCOLS AS HYDROPHILIC MEMBRANE PHASE
    9.
    发明申请
    CROSS-LINKED HIGH STABLE ANION EXCHANGE BLEND MEMBRANES WITH POLYETHYLENEGLYCOLS AS HYDROPHILIC MEMBRANE PHASE 审中-公开

    公开(公告)号：US20200023348A1

    公开(公告)日：2020-01-23

    申请号：US16312975

    申请日：2017-06-22

    申请人： Thomas HÄRING ,  between Lizenz GmbH ,  UNIVERSITÄT STUTTGART

    发明人： Jochen KERRES

    IPC分类号： B01J41/13 ,  B01J41/14 ,  C08J5/22 ,  H01M8/1025 ,  C25B13/08 ,  H01M8/1032 ,  H01M8/18 ,  B01D71/28 ,  B01D71/52 ,  B01D71/68 ,  B01D69/02

    摘要： The invention relates to: —anion exchange blend membranes consisting the following blend components: —a halomethylated polymer (a polymer with —(CH2)x—CH2—Hal groups, Hal=F, Cl, Br, I; x=0-12), which is quaternised with a tertiary or a n-alkylated/n-arylated imidazole, an N-alkylated/N-arylated benzimidazole or an N-alkylated/N-arylated pyrazol to form an anion exchanger polymer. —an inert matrix polymer in which the anion exchange polymer is embedded and which is optionally covalently crosslinked with the halomethylated precursor of the anion exchanger polymer, —a polyethyleneglycol with epoxide or halomethyl terminal groups which are anchored by reacting with N—H-groups of the base matrix polymer using convalent cross-linking —optionally an acidic polymer which forms with the anion-exchanger polymer an ionic cross-linking (negative bound ions of the acidic polymer forming ionic cross-linking positions relative to the positive cations of the anion-exchanger polymer) —optionally a sulphonated polymer (polymer with sulphate groups —SO2Me, Me=any cation), which forms with the halomethyl groups of the halomethylated polymer convalent crosslinking bridges with sulfinate S-alkylation. The invention also relates to a method for producing said membranes, to the use of said membranes in electrochemical energy conversion processes (e.g. Redox-flow batteries and other flow batteries, PEM-electrolyses, membrane fuel cells), and in other membrane methods (e.g. electrodialysis, diffusion dialysis).