A COMBINED FORMOSE/TRANSFER HYDROGENATION PROCESS FOR ETHYLENE GLYCOL SYNTHESIS
    13.
    发明申请
    A COMBINED FORMOSE/TRANSFER HYDROGENATION PROCESS FOR ETHYLENE GLYCOL SYNTHESIS 审中-公开
    乙烯甘油合成的组合形式/转移加氢方法

    公开(公告)号:WO2009049114A1

    公开(公告)日:2009-04-16

    申请号:PCT/US2008/079450

    申请日:2008-10-10

    Abstract: The present invention provides a process for the production of a glycol via tandem self condensation of formaldehyde via formoin condensation and transfer hydrogenation of the reaction products of the formoin condensation. In some aspects, synthetic processes of the present invention utilize a combination of a N-heterocyclic carbene catalyst and a transition metal hydrogen-transfer catalyst providing enhanced selectivity and increased yields for the production of ethylene glycol relative to conventional synthetic approaches based on formoin condensation.

    Abstract translation: 本发明提供了一种通过甲醛通过甲醛缩合和甲醛缩合的反应产物的转移氢化的串联自缩合来生产二醇的方法。 在一些方面,本发明的合成方法利用N-杂环卡宾催化剂和过渡金属氢转移催化剂的组合,相对于基于甲醛缩合的常规合成方法,提供增强的选择性和增加乙二醇生产的产率。

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