公开(公告)号：WO2019223761A1

公开(公告)日：2019-11-28

申请号：PCT/CN2019/088123

申请日：2019-05-23

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： PARVULESCU, Andrei-Nicolae ,  MCGUIRE, Robert ,  MUELLER, Ulrich ,  ZHANG, Weiping ,  MENG, Xiangju ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  GIES, Hermann ,  MARLER, Bernd ,  KOLB, Ute ,  DE VOS, Dirk

IPC分类号： B01J29/06

摘要： The present invention relates to a rare earth element containing zeolitic material having a framework structure selected from the group consisting of AEI, AFT, AFV, AFX, AVL, CHA, EMT, GME, KFI, LEV, LTN, and SFW, including mixtures of two or more thereof, the framework structure of the zeolitic material comprising SiO 2 and X 2 O 3 , wherein X stands for a trivalent element, wherein the zeolitic material displays an SiO 2 : X 2 O 3 molar ratio in the range of from 2 to 20, and wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure. Furthermore, the present invention relates to a process for the production of the inventive rare earth element containing zeolitic material as well as to the use of the inventive rare earth element containing zeolitic material as such and as obtainable and/or obtained according to the inventive process.

公开(公告)号：WO2019024909A1

公开(公告)日：2019-02-07

申请号：PCT/CN2018/098471

申请日：2018-08-03

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  KOLB, Ute ,  MARLER, Bernd ,  WANG, Tong ,  DE BAERDEMAEKER, Trees ,  SHI, Chuan ,  PAN, Xiulian ,  MENG, Xiangju

IPC分类号： B01J29/064 ,  B01D53/94

摘要： A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In.A process for preparing such a zeolitic material. Use of such a zeolitic material.

公开(公告)号：WO2014060982A2

公开(公告)日：2014-04-24

申请号：PCT/IB2013/059417

申请日：2013-10-17

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED ,  TOKYO INSTITUTE OF TECHNOLOGY

发明人： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  TATSUMI, Takashi ,  XIAO, Feng-Shou ,  GIES, Hermann ,  IMAI, Hiroyuki

CPC分类号： C07C1/044 ,  B01J29/76 ,  B01J29/89 ,  B01J35/1019 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J2229/186 ,  C10G25/003 ,  C10G25/03

摘要： The present invention relates to a process for the production of a pillared silicate comprising: (i) providing a layered silicate; (ii)interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii)treating the interlayer expanded silicate obtained in step (ii) with one or more hydrolyzable silicon containing compounds; (iv)treating the interlayer expanded compound obtained in step (iii) with an aqueous solution to obtain a pillared silicate; (v)removing at least a portion of the one or more swelling agents from the pillared silicate obtained in step (iv); (vi) impregnating the pillared silicate obtained in step (v) with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof, as well as to a pillared silicate optionally obtainable from said process and its use, in particular in a process for the production of one or more olefins according to the invention.

摘要翻译： 本发明涉及一种生产柱状硅酸盐的方法，包括：（i）提供层状硅酸盐; （ii）层间膨胀步骤（i）中提供的层状硅酸盐，包括用一种或多种溶胀剂处理层状硅酸盐的步骤; （iii）用一种或多种可水解含硅化合物处理在步骤（ii）中获得的层间发泡硅酸盐; （iv）用水溶液处理步骤（iii）中得到的层间发泡化合物，得到柱状硅酸盐; （v）从步骤（iv）中获得的柱状硅酸盐中去除至少一部分一种或多种溶胀剂; （vi）将步骤（v）中获得的柱状硅酸盐浸入一种或多种选自Fe，Ru，Ir的元素，以及两种或更多种的组合，以及任选地可从所述方法获得的柱状硅酸盐 及其用途，特别是用于生产根据本发明的一种或多种烯烃的方法。

公开(公告)号：WO2020156506A1

公开(公告)日：2020-08-06

申请号：PCT/CN2020/074094

申请日：2020-01-31

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  KOLB, Ute ,  MARLER, Bernd ,  WANG, Yong ,  DE BAERDEMAEKER, Trees ,  SHI, Chuan ,  MENG, Xiangju ,  PAN, Xiulian

IPC分类号： B01J29/86 ,  B01J29/70 ,  C01B39/02 ,  C01B39/04

摘要： A process for preparing a zeolitic material having framework type CHA and having a framework structure which comprises a tetravalent element Y, B, and O, comprising preparing a synthesis mixture comprising water, a source of the tetravalent element Y, a source of B, and a CHA framework structure directing agent, and heating the synthesis mixture to a temperature in the range of from 100 to 200°C and keeping the synthesis mixture at a temperature in this range under autogenous pressure, and subjecting the zeolitic material obtained to an acid treatment.

公开(公告)号：WO2019242618A1

公开(公告)日：2019-12-26

申请号：PCT/CN2019/091745

申请日：2019-06-18

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： PARVULESCU, Andrei-Nicolae ,  MCGUIRE, Robert ,  MUELLER, Ulrich ,  MENG, Xiangju ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  DE VOS, Dirk ,  MARLER, Bernd ,  GIES, Hermann ,  KOLB, Ute ,  ZHANG, Weiping

IPC分类号： C01B39/02 ,  C01B39/48 ,  B01J29/70 ,  B01J37/10

摘要： The present invention relates to a process for the preparation of a zeolitic material SiO 2 and X 2 O 3 in its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiO 2 and X 2 O 3 in its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or M FI-type framework structure to a second zeolitic material comprising SiO 2 and X 2 O 3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.

公开(公告)号：WO2019001380A1

公开(公告)日：2019-01-03

申请号：PCT/CN2018/092580

申请日：2018-06-25

申请人： BASF SE ,  BASF (CHINA) COMPANY LIMITED

发明人： FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  KOLB, Ute ,  MARLER, Bernd ,  WANG, Yong ,  DE BAERDEMAEKER, Trees ,  SHI, Chuan ,  PAN, Xiulian ,  MENG, Xiangju

IPC分类号： C01B39/04 ,  C01B39/48 ,  B01D53/94 ,  B01J29/072

摘要： A composition comprising a support material which comprises silicon carbide on the surface of which a zeolitic material of the AEI/CHA family is supported, wherein at least 99 weight-% of the framework structure of the zeolitic material consist of a tetravalent element Y which is one or more of Si, Ge, Ti, Sn and V; a trivalent element X which is one or more of Al, Ga, In, and B; O; and H.

公开(公告)号：WO2015101930A1

公开(公告)日：2015-07-09

申请号：PCT/IB2014/067413

申请日：2014-12-30

申请人： BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  BASF (CHINA) COMPANY LIMITED

发明人： FEYEN, Mathias ,  MAURER, Stefan ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi ,  YILMAZ, Bilge

IPC分类号： C01B39/00 ,  B01J29/00

CPC分类号： B01D53/9418 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/502 ,  B01J29/7615 ,  B01J37/0203 ,  B01J37/04 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/34 ,  C01B39/026 ,  C01B39/46

摘要： The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YO 2 and X2O 3 , wherein said process comprises the steps of (1)preparing a mixture comprising one or more sources for YO 2 and one or more sources for X 2 O 3 ; (2)crystallizing the mixture obtained in step (1); (3)subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu; and (4) subjecting the Cu ion-exchanged zeolitic material obtained in step (3) to an ion-exchange procedure with Fe; wherein Y is a tetravalent element, and X is a trivalent element, wherein the mixture provided in step (1) and crystallized in step (2) further comprises seed crystals comprising one or more zeolitic materials having a BEA-type framework structure, and wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as a structure-directing agent, as well as to the zeolitic material having a BEA framework structure per se, and to its use, in particular in a method for the treatment of NO x by selective catalytic reduction (SCR).

摘要翻译： 本发明涉及生产具有包含YO 2和X 2 O 3的BEA型骨架结构的沸石材料的方法，其中所述方法包括以下步骤：（1）制备包含一种或多种YO 2和一种或多种源的混合物 X2O3的来源; （2）使步骤（1）中获得的混合物结晶; （3）将具有步骤（2）中获得的BEA型骨架结构的沸石材料与Cu进行离子交换程序; 和（4）使步骤（3）中获得的Cu离子交换的沸石材料与Fe的离子交换程序; 其中Y是四价元素，X是三价元素，其中在步骤（1）中提供并在步骤（2）中结晶的混合物还包含包含一种或多种具有BEA型骨架结构的沸石材料的晶种，其中 步骤（1）中提供并在步骤（2）中结晶的混合物不含作为结构导向剂的有机模板，以及本身具有BEA骨架结构的沸石材料，特别是其用途 通过选择性催化还原（SCR）处理NOx的方法。

公开(公告)号：WO2012137133A1

公开(公告)日：2012-10-11

申请号：PCT/IB2012/051629

申请日：2012-04-03

申请人： BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  BASF (CHINA) COMPANY LIMITED ,  YILMAZ, Bilge ,  MÜLLER, Ulrich ,  ÖZKIRIM, Faruk ,  DE VOS, Dirk ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  BAO, Xinhe ,  ZHANG, Weiping ,  GIES, Hermann ,  IMAI, Hiroyuki ,  TIJSEBAERT, Bart

发明人： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  ÖZKIRIM, Faruk ,  DE VOS, Dirk ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  BAO, Xinhe ,  ZHANG, Weiping ,  GIES, Hermann ,  IMAI, Hiroyuki ,  TIJSEBAERT, Bart

IPC分类号： C07C2/66 ,  C07C15/073 ,  C01B39/02 ,  B01J29/06

CPC分类号： C07C2/66 ,  C07C2529/70 ,  C07C15/073 ,  C07C15/02

摘要： Disclosed is a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO 2 and optionally comprises X 2 O 3 , wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.

摘要翻译： 公开了一种用于烷基化有机化合物的方法，包括：（a）提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂，其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3，其中Y是四价元素， 并且X是三价元素，（b）在一个或多个烷基化剂存在下，在一个或多个烷基化剂存在下使所述催化剂与一种或多种可烷基化的有机化合物接触，以获得一种或多种烷基化有机化合物，其中所述一种或多种沸石材料 可以从不使用有机模板作为结构导向剂的合成方法获得。

公开(公告)号：WO2012001663A1

公开(公告)日：2012-01-05

申请号：PCT/IB2011/052913

申请日：2011-07-01

申请人： BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  YILMAZ, Bilge ,  MÜLLER, Ulrich ,  DE BAERDEMAEKER, Trees ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  BASF CHINA COMPANY LIMITED

发明人： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  DE BAERDEMAEKER, Trees ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk

IPC分类号： C01B33/20 ,  C01B39/02 ,  B01J29/04

CPC分类号： B01J29/049 ,  C01B33/20 ,  C01B37/005 ,  C01B39/026 ,  C01B39/48 ,  C07C2/84 ,  C07C2523/28 ,  C07C2523/72 ,  C07C2523/755 ,  C07C2523/883 ,  C07C2523/885

摘要： The present invention relates to a pillared silicate compound comprising a layered silicate structure, and bridging metal atoms located between adjacent silicate layers of the silicate structure, wherein said bridging metal atoms form at least one covalent bond to each of the adjacent silicate layers, as well as a process for the preparation of a pillared silicate compound, and further includes a pillared silicate compound obtainable and or obtained according to said process, as well as the use of any of the aforementioned pillared silicate compounds.

摘要翻译： 本发明涉及包含层状硅酸盐结构的柱状硅酸盐化合物和位于硅酸盐结构的相邻硅酸盐层之间的桥连金属原子，其中所述桥连金属原子与每个相邻的硅酸盐层形成至少一个共价键 作为制备柱状硅酸盐化合物的方法，并且还包括根据所述方法可获得或获得的柱状硅酸盐化合物，以及任何上述柱状硅酸盐化合物的用途。

公开(公告)号：WO2011158218A1

公开(公告)日：2011-12-22

申请号：PCT/IB2011/052657

申请日：2011-06-17

申请人： BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  BASF CHINA COMPANY LIMITED ,  YILMAZ, Bilge ,  MÜLLER, Ulrich ,  BETANCUR MORENO, Bibiana Andrea ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  PFAFF, Meike ,  XIE, Bin ,  ZHANG, Haiyan

发明人： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  BETANCUR MORENO, Bibiana Andrea ,  GIES, Hermann ,  XIAO, Feng-Shou ,  TATSUMI, Takashi ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  PFAFF, Meike ,  XIE, Bin ,  ZHANG, Haiyan

IPC分类号： C01B39/48 ,  B01J20/18

CPC分类号： C01B39/48 ,  B01D2253/108 ,  B01D2255/50 ,  B01J20/186 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3007 ,  B01J20/3042 ,  B01J29/70 ,  C01B37/02 ,  C01B39/46 ,  C10G3/49 ,  C10G11/18 ,  C10G25/03 ,  C10G2300/405 ,  C10G2300/70 ,  Y02P30/20

摘要： Zeolitic materials of the LEV-type structure and methods for their production are provided. The method for the production of the zeolitic material having an LEV-type structure comprising Y0 2 and optionally comprising X 2 O 3 comprises the steps of: (1) preparing a mixture comprising one or more sources for Y0 2 ,one or more solvents, and optionally comprising seed crystals; and (2) crystallizing the mixture obtained in step (1), wherein Y is a tetravalent element, and X is a trivalent element, the zeolitic material optionally comprises one or more alkali metals M, the molar ratio of the total amount of the one or more solvents to the total amount of the one or more sources for Y0 2 based on Y0 2 is 9.5 or less, and the crystallization temperatures is 175°C or higher in step (2), the duration of crystallization at those temperatures is less than 14 days. The zeolitic materials, preferably being obtainable or obtained according to the inventive method have an LEV-type framework structure comprising Y0 2 and X 2 0 3 , one or more alkali metals M and display an Y:X atomic ratio of from 1 to 9.4.

摘要翻译： 提供LEV型结构的沸石材料及其生产方法。 制备具有包含YO 2和任选地包含X 2 O 3的LEV型结构的沸石材料的方法包括以下步骤：（1）制备包含一种或多种用于Y02，一种或多种溶剂和任选地包含晶种的源的混合物 ; 和（2）使步骤（1）中得到的混合物结晶，其中Y是四价元素，X是三价元素，所述沸石材料任选地包含一种或多种碱金属M，所述一元素的总量的摩尔比 或更多的溶剂相对于基于Y02的Y02的一种或多种来源的总量为9.5以下，并且在步骤（2）中结晶温度为175℃以上，则在这些温度下的结晶持续时间小于14 天。 优选根据本发明方法获得或获得的沸石材料具有包含YO 2和X 2 O 3的LEV型骨架结构，一种或多种碱金属M并且显示出1：9.4的Y:X原子比。