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    METHOD FOR THE MANUFACTURE OF PERFLUOROVINYLETHERS
    1.
    发明申请
    METHOD FOR THE MANUFACTURE OF PERFLUOROVINYLETHERS 审中-公开
    制备全氟牛磺酸盐的方法

    公开(公告)号：WO2018011142A1

    公开(公告)日：2018-01-18

    申请号：PCT/EP2017/067275

    申请日：2017-07-10

    申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    发明人： GREGORI, Manuel ,  MILLEFANTI, Stefano ,  ALBONETTI, Stefania ,  FORNASARI, Giuseppe ,  ANDREOLI, Sara ,  MARCHIONNI, Giuseppe

    IPC分类号： C07C41/24 ,  C07C43/17 ,  C07D317/42 ,  B01J23/62

    CPC分类号： C07D317/42 ,  B01J21/18 ,  B01J23/626 ,  B01J27/135 ,  B01J35/1028 ,  C07C41/24 ,  C07C43/17

    摘要： The invention pertains to a method for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HaloFE) having general formula (l-A) or R f O-CR f 'X-CR f "R f "'X' (l-A) wherein R f represents a C 1 -C 6 perfluoro(oxy)alkyl group; R f ', R f " and R f '", equal or different from each other, independently represent fluorine atoms or C 1 -C 5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently selected from CI, Br or I; (l-B) wherein R f * and R f *', equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoro(oxy)alkyl groups; Y 1 and Y 2 , equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoroalkyl groups; X and X' are as above defined; said method comprising contacting said halofluoroether (HaloFE) with hydrogen in the presence of a catalyst comprising at least one transition metal (M) of group VI 11 B and tin.

    摘要翻译： 本发明涉及通过具有通式（IA）或R f F-O-CR'的卤代氟代醚（HaloFE）的加氢脱卤作用制备全氟乙烯基醚的方法， 其中R f表示C 1 -C 4烷基，其中R f表示C 1 -C 4烷基， （C 1-6） - 全氟（氧）烷基; R'，R'，R'，R'，R' 和R''“'，彼此相同或不同，独立地表示氟原子或C 1 -C 5全氟（氧）烷基 组; X和X'彼此相同或不同，独立地选自Cl，Br或I; （IB）其中R f *和R f *彼此相同或不同，独立地代表氟原子或C 1 -C 3个全氟（氧）烷基; Y1和Y2彼此相同或不同，各自独立地代表氟原子或C≡C≡3 全氟烷基; X和X'如上所定义; 所述方法包括在包含至少一种第VI II B族过渡金属（M）和锡的催化剂存在下使所述卤代氟醚（HaloFE）与氢气接触。

    CATALYST CARRIER
    2.
    发明申请
    CATALYST CARRIER 审中-公开
    催化剂载体

    公开(公告)号：WO2017065970A1

    公开(公告)日：2017-04-20

    申请号：PCT/US2016/054051

    申请日：2016-09-28

    申请人： SAINT-GOBAIN CERAMICS & PLASTICS, INC.

    发明人： REID, John S.

    IPC分类号： B01J32/00 ,  B01J35/02

    CPC分类号： B01J35/04 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1028

    摘要： A catalyst carrier may have a cross-sectional shape that may include a plurality of surface channels having a first channel width and a second channel width, where the first channel width may be closer to a periphery of the cross-sectional shape than the second channel width and the first channel width may be less than the second channel width. The cross-sectional shape may further include a plurality of surface features where at least one surface feature is located between at least one pair of surface channels. The cross-sectional shape may further include a ratio LOC/LSCP of at least about 1.7, where LOC is a length of a total contour of the cross-sectional shape and LSCP is a length of an outer simple convex perimeter of the cross-sectional shape.

    摘要翻译： 催化剂载体可以具有可以包括具有第一通道宽度和第二通道宽度的多个表面通道的横截面形状，其中第一通道宽度可以更接近于 横截面形状比第二通道宽度和第一通道宽度可以小于第二通道宽度。 横截面形状还可以包括多个表面特征，其中至少一个表面特征位于至少一对表面通道之间。 横截面形状还可以包括比率LOC / LSCP至少约为1.7，其中LOC是横截面形状的总轮廓的长度，并且LSCP是横截面的外简单凸形周边的长度 形状

    METHOD OF SYNTHESIS OF CMK-3-TYPE CARBON REPLICA
    10.
    发明申请
    METHOD OF SYNTHESIS OF CMK-3-TYPE CARBON REPLICA 审中-公开
    CMK-3型碳水化合物的合成方法

    公开(公告)号：WO2013122488A1

    公开(公告)日：2013-08-22

    申请号：PCT/PL2013/000015

    申请日：2013-02-08

    申请人： UNIWERSYTET JAGIELLONSKI

    发明人： KUSTROWSKI, Piotr ,  JANUS, Rafał ,  NIEBRZYDOWSKA, Paula

    IPC分类号： C01B31/02

    CPC分类号： B01J29/0308 ,  B01J20/20 ,  B01J20/28083 ,  B01J20/3057 ,  B01J20/3078 ,  B01J20/3085 ,  B01J21/18 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/06 ,  B01J37/084 ,  C01B32/00 ,  C01B32/05 ,  C01B37/00 ,  C01P2006/17

    摘要： The method of obtaining the CMK-3-type carbon replica, consisting of the introduction of SBA-15-type molecular sieve to a mixture of furfuryl alcohol and a solvent, the subsequent polycondensation of furfuryl alcohol, carbonization of the prepared, composite and removal of the hard template, according to the invention, is characterised in that the reaction of furfuryl alcohol polycondensation is carried out by the precipitation method in a slurry containing SBA-15 silica sieve, water, furfuryl alcohol and concentrated solution of hydrochloric acid in mass ratios, respectively, in the range from 1.00:32.33:1.00:6.65 to 1.00:30.83:2.50:16.64, whereas the ratio of the total mass of furfuryl alcohol and water to the mass of SBA-15 as well as the mass ratio of the concentrated HCI solution to the mass of furfuryl alcohol are kept at the constant value every time.

    摘要翻译： 获得CMK-3型碳复制品的方法，其中包括将SBA-15型分子筛引入到糠醇与溶剂的混合物中，随后糠醇缩聚，制备，复合和除去碳化 的硬模板，其特征在于，通过沉淀法在含有SBA-15二氧化硅筛，水，糠醇和浓盐酸浓盐酸的浆料中进行糠醇缩聚反应 ，分别为1.00:32.33:1.00:6.65-1.00:30.83:2.50:16.64的范围，糠醇与水的总质量与SBA-15的质量比以及质量比 浓缩的HCl溶液对糠醇的质量每次都保持恒定值。