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11.发明申请METHOD FOR REDUCING THE C1-C2-ALDEHYDE CONTENT FORMED FROM COMPOUNDS WITH -CH2-CHR-O- OR -CH2-CH(OH)-GROUPS 审中-公开过程，用于降低由-CH 2 CHR-O-或-CH2-CH（OH）基团表示的化合物的C1-C2-醛含量
公开(公告)号：WO99051647A1
公开(公告)日：1999-10-14
申请号：PCT/EP1999/002216
申请日：1999-03-31
CPC classification number: C08F6/006 , C07B63/04 , C07C29/94 , C07C31/202 , C07C31/18
Abstract: The invention relates to a method for reducing the content of small quantities of C1-C2-aldehydes formed from organic compounds with -CH2-CHR-O- and/or -CH2-CH(OH)-groups (R=H, C1-C4-alkyl) as a result of radical action, to
Abstract translation: 从含有-CH 2 -CHR-O-和/或-CH 2（OH）基团的有机化合物（R = H，C1-C4烷基）而造成少量C1-C2-醛与自由基作用，其含量在根据本发明 可以通过添加其与醛基到<1ppm的反应的化合物，可以减少处理。 间与上述分组的物质包括许多在聚合物化学中所使用的乳化剂和保护胶体，如聚乙二醇，聚乙烯醇或长链醇的乙氧基化产物，酚或胺。 该方法是对已在这样的乳化剂或保护胶体的存在下制备了单体的自由基聚合的聚合物分散体的治疗特别重要，并且允许生产无醛的聚合物分散体以及它们用于卫生和卫生制品中使用。
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公开(公告)号：WO2022084050A1
公开(公告)日：2022-04-28
申请号：PCT/EP2021/077669
申请日：2021-10-07
Applicant: EVONIK OPERATIONS GMBH
Inventor： WIEDERHOLD, Holger , BOLZ, David , GLATZ, Patrik
Abstract: A method for preparing 1,2-propanediol by the steps of (a) continuously reacting propene with hydrogen peroxide in the presence of a catalyst mixture comprising a quaternary ammonium salt and a polytungstophosphate in a liquid reaction mixture comprising an aqueous phase with a maximum apparent pH of 6 and an organic phase comprising an alkylaromatic hydrocarbon solvent, (b) withdrawing liquid reaction mixture from step a) and adding a water-soluble sulfate salt or sulfuric acid to provide a mixture comprising from 500 to 10,000 mg/kg of sulfate ions in the aqueous phase, (c) separating the mixture obtained in step b) into an aqueous phase (Pa) comprising 1,2-propanediol and an organic phase (Po), (d) recycling at least a part of the organic phase (Po) to the reaction step a) and (e) recovering 1,2-propanediol from the aqueous phase (Pa) allows extended operation of the reaction with little loss of tungsten and phase transfer catalyst.
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公开(公告)号：WO2018070851A1
公开(公告)日：2018-04-19
申请号：PCT/KR2017/011395
申请日：2017-10-16
Applicant: 주식회사 창발켐텍
Inventor： 문경운
IPC: C07C29/147 , C07C29/94 , C07C33/46 , C07C51/06 , C07C63/70
CPC classification number: C07C29/147 , C07C29/94 , C07C33/46 , C07C51/06 , C07C63/70
Abstract: 본 발명은 할로겐이 치환된 벤조산으로부터 할로겐이 치환된 벤질 알코올의 제조방법에 관한 것이다. 본 발명의 방법을 이용하여 할로겐이 치환된 벤질 알코올을 제조하는 경우, 수소화붕소나트륨과 저가의 무기산을 사용하므로, 특수 반응기를 사용하지 않고도 벤질 알코올을 제조하는 것이 가능하여, 제조공정이 편리하고, 산업 폐기물이 감소되며, 고수율 및 고순도의 벤질 알코올을 제조할 수 있어, 제초제 및 간전제 합성의 원료로서 유용한 벤질 알코올의 대량생산에 용이하다.
Abstract translation: 本发明涉及生产其中卤素被卤素取代的苯甲酸取代的苄醇的方法。 当使用本发明的方法制备卤素取代的苯甲醇时，由于使用硼氢化钠和廉价的无机酸，因此可以在不使用专用反应器的情况下生产苯甲醇， 工业废弃物减少，可以生产高产量和高纯度的苄醇，并且容易大量生产可用作除草剂和肝前体合成的原料的苄醇。
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公开(公告)号：WO2017172895A1
公开(公告)日：2017-10-05
申请号：PCT/US2017/024719
申请日：2017-03-29
Applicant: THE GOVERNMENT OF THE UNITED STATES OF AMERICA, AS REPRESENTED BY THE SECRETARY OF THE NAVY
Inventor： PIETRON, Jeremy, J. , DESARIO, Paul, A. , ROLISON, Debra, R. , BRINTLINGER, Todd, H. , STROUD, Rhonda, Michael
IPC: C01G23/047 , B22F9/16 , B01J21/06 , B01J23/72 , B01J35/02 , B01J35/10 , C07C29/48 , C07C29/94 , C07C31/04
Abstract: A composition having: titania aerogel having titania nanoparticles and copper nanoparticles. Each of the copper nanoparticles is in contact with more than one of the titania nanoparticles. A method of: providing a titania aerogel, and forming or depositing copper nanoparticles onto the surface of the titania aerogel.
Abstract translation: 一种组合物，其具有：具有二氧化钛纳米颗粒和铜纳米颗粒的二氧化钛气凝胶。 每个铜纳米颗粒与不止一个二氧化钛纳米颗粒接触。 一种方法：提供二氧化钛气凝胶，以及在二氧化钛气凝胶的表面上形成或沉积铜纳米粒子。
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15.发明申请METHOD OF REGENERATING A CATALYST FOR SYNTHESIS OF ALKYLENE CARBONATE AND/OR ALKYLENE GLYCOL, AND A METHOD FOR PRODUCING ALKYLENE CARBONATE AND/OR ALKYLENE GLYCOL 审中-公开再生用于合成碳酸亚烃酯和/或亚烷基二醇的催化剂的方法以及生产碳酸亚烃酯和/或亚烷基二醇的方法
公开(公告)号：WO2013028039A3
公开(公告)日：2013-05-10
申请号：PCT/KR2012006786
申请日：2012-08-24
Applicant: LOTTE CHEMICAL CORP , YANG HONG-JU , LEE SUNG-HUN , HONG JUN-TAEK
Inventor： YANG HONG-JU , LEE SUNG-HUN , HONG JUN-TAEK
CPC classification number: B01J27/32 , B01J38/74 , C07C29/106 , Y02P20/52 , Y02P20/584 , C07C31/202
Abstract: The present invention relates to a method of regenerating a catalyst and a method for producing alkylene carbonate and/or alkylene glycol which can be used by regenerating a deactivated catalyst. The method of regenerating a catalyst comprises the steps of: concentrating, through the use of a thin film evaporation apparatus, a resultant product obtained by the reaction between alkylene oxide and carbon dioxide in the presence of a catalyst of a quaternary phosphonium iodide compound and/or quaternary phosphonium bromide compound; and allowing the concentrate to react with an iodine salt and/or bromine salt.
Abstract translation: 本发明涉及再生催化剂的方法和生产可通过再生失活的催化剂使用的碳酸亚烷基酯和/或亚烷基二醇的方法。 再生催化剂的方法包括以下步骤：通过使用薄膜蒸发装置浓缩通过烯化氧和二氧化碳之间的反应获得的产物，所述产物在季鏻碘化物化合物催化剂和/ 或季鏻溴化物化合物; 并使浓缩物与碘盐和/或溴盐反应。
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Patent Agency Ranking16.发明申请알킬렌 카보네이트 및/또는 알킬렌 글리콜 합성용 촉매의 재생 방법 및 알킬렌 카보네이트 및/또는 알킬렌 글리콜의 제조 방법 审中-公开用于合成碳酸亚烷基酯和/或烷基甘氨酸的催化剂的再生方法以及生产碳酸亚烷基酯和/或烷基甘氨酸的方法
公开(公告)号：WO2013028039A2
公开(公告)日：2013-02-28
申请号：PCT/KR2012/006786
申请日：2012-08-24
Applicant: 롯데케미칼 주식회사 , 양홍주 , 이성훈 , 홍준택
CPC classification number: B01J27/32 , B01J38/74 , C07C29/106 , Y02P20/52 , Y02P20/584 , C07C31/202
Abstract: 본 발명은, 4차 포스포늄 요오드 화합물 및/또는 4차 포스포늄 브롬 화합물의 촉매 존재 하에, 알킬렌 옥사이드와 이산화탄소를 반응시켜 얻어진 결과물을, 박막 증발 장치를 이용하여 농축하는 단계; 및 상기 농축물을 요오드화 염 및/또는 브롬화 염과 반응시키는 단계;를 포함하는 촉매의 재생 방법 및 활성이 떨어진 촉매를 재생하여 사용할 수 있는 알킬렌 카보네이트 및/또는 알킬렌 글리콜의 제조 방법에 관한 것이다.
Abstract translation: 本发明涉及一种再生催化剂的方法和一种生产碳酸亚烷基酯和/或亚烷基二醇的方法，可通过再生失活的催化剂来使用。 再生催化剂的方法包括以下步骤：通过使用薄膜蒸发装置，在碘化鏻季碘化合物的催化剂存在下浓缩由环氧烷和二氧化碳之间的反应获得的所得产物，和/ 或季鏻化合物; 并使浓缩物与碘盐和/或溴盐反应。
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公开(公告)号：WO2013015997A2
公开(公告)日：2013-01-31
申请号：PCT/US2012046348
申请日：2012-07-12
Applicant: UOP LLC , DALIAN CHEMICAL PHYSICS INST , ZHANG TAO , WANG AIQIN , ZHENG MINGYUAN , LI CHANGZHI , PANG JIFENG , KALNES TOM N , CHEN JOHN Q , KOCAL JOSEPH A
Inventor： ZHANG TAO , WANG AIQIN , ZHENG MINGYUAN , LI CHANGZHI , PANG JIFENG , KALNES TOM N , CHEN JOHN Q , KOCAL JOSEPH A
CPC classification number: C12P7/18 , C07C29/132 , Y02P20/582 , C07C31/20
Abstract: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner using a catalyst comprising nickel tungsten carbide. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with the catalyst to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream.
Abstract translation: 使用包含碳化镍碳化物的催化剂以连续方式进行从包含纤维素的原料生成至少一种多元醇的催化方法。 该方法包括使氢气，水和包含纤维素的原料与催化剂连续接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。
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公开(公告)号：WO2013015996A2
公开(公告)日：2013-01-31
申请号：PCT/US2012046342
申请日：2012-07-12
Applicant: UOP LLC , CHEN JOHN Q , KALNES TOM N , KOCAL JOSEPH A
Inventor： CHEN JOHN Q , KALNES TOM N , KOCAL JOSEPH A
CPC classification number: C07C29/157 , B01J23/888 , B01J27/188 , Y02P20/52 , C07C31/205 , C07C31/202
Abstract: A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner using a catalyst system. The process involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.
Abstract translation: 使用催化剂体系以连续或间歇方式进行从包含糖的原料产生至少一种多元醇的方法。 该方法涉及使氢，水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种氧化态大于或等于2+的金属组分。
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公开(公告)号：WO2013015990A2
公开(公告)日：2013-01-31
申请号：PCT/US2012/046223
申请日：2012-07-11
Applicant: UOP LLC , KALNES, Tom, N. , CHEN, John, Q. , KOCAL, Joseph, A.
Inventor： KALNES, Tom, N. , CHEN, John, Q. , KOCAL, Joseph, A.
CPC classification number: C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
Abstract: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
Abstract translation: 用于以包含纤维素的原料生成至少一种多元醇的催化方法以连续方式进行。 该方法包括使氢气，水和包含纤维素的原料与催化剂连续接触以产生包含至少一种多元醇，水，氢气和至少一种副产物的流出物料流。 将水，氢气和至少一种副产物从流出物流中分离出来并循环到反应区。 多元醇从流出物流中回收。
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公开(公告)号：WO2013015989A3
公开(公告)日：2013-01-31
申请号：PCT/US2012/046202
申请日：2012-07-11
Applicant: UOP LLC , KALNES, Tom N. , CHEN, John Q. , KOCAL, Joseph A.
Inventor： KALNES, Tom N. , CHEN, John Q. , KOCAL, Joseph A.
Abstract: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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