公开(公告)号：WO2013015998A2

公开(公告)日：2013-01-31

申请号：PCT/US2012/046366

申请日：2012-07-12

Applicant: UOP LLC ,  DALIAN INSTITUTE OF CHEMICAL PHYSICS ,  KALNES, Tom N. ,  CHEN, John Q. ,  KOCAL, Joseph A. ,  ZHANG, Tao ,  WANG, Aiqin ,  ZHENG, Mingyuan ,  LI, Changzhi ,  PANG, Jifeng

Inventor： KALNES, Tom N. ,  CHEN, John Q. ,  KOCAL, Joseph A. ,  ZHANG, Tao ,  WANG, Aiqin ,  ZHENG, Mingyuan ,  LI, Changzhi ,  PANG, Jifeng

IPC: C07C29/94 ,  C07C31/26 ,  C07C31/18 ,  B01J23/755

CPC classification number: C07C29/132 ,  C07C31/20

Abstract: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.

Abstract translation: 用于以包含纤维素的原料生成至少一种多元醇的催化方法以连续方式进行。 该方法包括使氢气，水和包含纤维素的原料与催化剂连续接触以产生包含至少一种多元醇，水，氢气和至少一种副产物的流出物料流。 将水，氢气和至少一种副产物从流出物流中分离出来并循环到反应区。 多元醇从流出物流中回收。

公开(公告)号：WO2012012046A2

公开(公告)日：2012-01-26

申请号：PCT/US2011/040515

申请日：2011-06-15

Applicant: UOP LLC ,  BORESKOV INSTITUTE OF CATALYSIS ,  BHATTACHARYYA, Alakananda ,  KOCAL, Joseph A. ,  WALENGA, Joel T. ,  ADONIN, Nikolay Y. ,  KUZNETSOVA, Nina I. ,  BAL'ZHINIMAEV, Bair S.

Inventor： BHATTACHARYYA, Alakananda ,  KOCAL, Joseph A. ,  WALENGA, Joel T. ,  ADONIN, Nikolay Y. ,  KUZNETSOVA, Nina I. ,  BAL'ZHINIMAEV, Bair S.

IPC: C07C63/14 ,  C07C51/21 ,  C07C49/76 ,  C07C47/52 ,  C07C39/06

CPC classification number: C07C51/265 ,  C07C63/06 ,  C07C63/16 ,  C07C63/26

Abstract: A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium.

Abstract translation: 用于氧化烷基 - 芳族化合物的方法和混合物包括形成包含烷基 - 芳族化合物，溶剂，溴源和催化剂的混合物; 以及在氧化条件下使所述混合物与氧化剂接触以产生包含芳族醛，芳族醇，芳族酮和芳族羧酸中的至少一种的氧化产物。 溶剂包括具有1至7个碳原子的羧酸和选自咪唑鎓离子液体，吡啶鎓离子液体，鏻离子液体，四烷基铵离子液体及其组合的离子液体。 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。

公开(公告)号：WO2011103054A2

公开(公告)日：2011-08-25

申请号：PCT/US2011024722

申请日：2011-02-14

Applicant: UOP LLC ,  MARINANGELI RICHARD ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

Inventor： MARINANGELI RICHARD ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

IPC: C10B53/02 ,  B01J23/38 ,  B01J29/04 ,  C10G3/00 ,  F25J1/00

CPC classification number: C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G2400/30 ,  Y02E50/14 ,  Y02P30/20

Abstract: Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal- based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

Abstract translation: 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 碳质生物质原料在催化剂存在下热解，该催化剂包含基于贱金属的催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合以产生热解气体。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。

公开(公告)号：WO2011090616A3

公开(公告)日：2011-07-28

申请号：PCT/US2010/060718

申请日：2010-12-16

Applicant: UOP LLC ,  BHATTACHARYYA, Alakananda ,  SERBAN, Manuela ,  MEZZA, Beckay J. ,  VANDEN BUSSCHE, Kurt M. ,  NICHOLAS, Christopher P. ,  KOCAL, Joseph, A. ,  BENNION, Warren K.

Inventor： BHATTACHARYYA, Alakananda ,  SERBAN, Manuela ,  MEZZA, Beckay J. ,  VANDEN BUSSCHE, Kurt M. ,  NICHOLAS, Christopher P. ,  KOCAL, Joseph, A. ,  BENNION, Warren K.

IPC: C10G29/00

Abstract: A process for removing a metal from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the metal with a VGO-immiscible ionic liquid to produce a vacuum gas oil and VGO-immiscible ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced metal content relative to the vacuum gas oil feed.

公开(公告)号：WO2009151692A2

公开(公告)日：2009-12-17

申请号：PCT/US2009/037072

申请日：2009-03-13

Applicant: UOP LLC ,  ANUMAKONDA, Amarendra ,  MCCALL, Michael J. ,  BRANDVOLD, Timothy A. ,  KOCAL, Joseph A.

Inventor： ANUMAKONDA, Amarendra ,  MCCALL, Michael J. ,  BRANDVOLD, Timothy A. ,  KOCAL, Joseph A.

IPC: C10G67/02 ,  C10G5/00 ,  C10L1/08

CPC classification number: C10G45/58 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/062 ,  C10G3/42 ,  C10G3/50 ,  C10G3/52 ,  C10G45/64 ,  C10G45/72 ,  C10G47/00 ,  C10G47/36 ,  C10G65/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock (2) is treated by hydrogenating and deoxygenating (4) to provide an effluent (6) comprising paraffins, isomerizing and selectively hydrogenating (22) at least a portion of the paraffins at the predetermined conditions, and separating by fractionation (42) at the predetermined fractionation conditions to generate a diesel range hydrocarbon product (46) and an aviation range hydrocarbon product (45).

Abstract translation: 控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。 该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。 确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。 确定所需的分馏区条件以分离所需的产物。 通过氢化和脱氧（4）处理可再生原料（4）以提供包含链烷烃的异构化和选择性氢化（22）至少一部分链烷烃的预定条件的流出物（6），并通过分馏（42 ），以产生柴油范围烃产物（46）和航空范围烃产物（45）。

公开(公告)号：WO2009151690A2

公开(公告)日：2009-12-17

申请号：PCT/US2009037066

申请日：2009-03-13

Applicant: UOP LLC ,  MCCALL MICHAEL J ,  KOCAL JOSEPH A ,  BHATTACHARYYA ALAKANANDA ,  KALNES TOM N ,  BRANDVOLD TIMOTHY A

Inventor： MCCALL MICHAEL J ,  KOCAL JOSEPH A ,  BHATTACHARYYA ALAKANANDA ,  KALNES TOM N ,  BRANDVOLD TIMOTHY A

IPC: C10G67/02 ,  C07C2/08 ,  C10G45/04

CPC classification number: C10G3/47 ,  C10G3/46 ,  C10G3/49 ,  C10G3/52 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/08 ,  Y02P30/20

Abstract: A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from 9 to 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.

Abstract translation: 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化，脱氧，异构化和选择性加氢裂化原料来处理可再生原料，以在含有多官能催化剂的单个反应区中产生具有9至16个碳原子和高异/正常比例的链烷烃，或一组 催化剂，具有氢化，脱氧，异构化和选择性加氢裂化功能。

公开(公告)号：WO2007073532A2

公开(公告)日：2007-06-28

申请号：PCT/US2006061830

申请日：2006-12-11

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

Inventor： BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

CPC classification number: C07C29/48 ,  C07C29/095 ,  C07C29/80 ,  C07C67/035 ,  C07C69/63 ,  C07C31/04

Abstract: A process for the production of methanol from methane has been developed. The process involves reacting methane with an oxidant such as oxygen or a peroxide in the presence of a catalyst and a solvent in a reaction zone to produce an effluent stream comprising a methanol product. The effluent stream is next separated into a gaseous stream comprising unreacted methane and carbon dioxide and a liquid stream comprising the methanol product and solvent. Next the gaseous stream is further separated to provide a methane stream which is recycled to the reaction zone. Finally, a methanol stream is isolated and a solvent stream is recycled to the reaction zone.

Abstract translation: 已经开发了从甲烷生产甲醇的方法。 该方法包括使甲烷与氧化剂如氧气或过氧化物在催化剂和溶剂存在下在反应区中反应以产生包含甲醇产物的流出物流。 接着将流出物流分离成包含未反应的甲烷和二氧化碳的气态物流和包含甲醇产物和溶剂的液态物流。 接下来，将气体流进一步分离以提供循环到反应区的甲烷流。 最后，分离甲醇流并将溶剂流循环至反应区。

公开(公告)号：WO2013019328A3

公开(公告)日：2013-06-13

申请号：PCT/US2012043066

申请日：2012-06-19

Applicant: UOP LLC ,  KOCAL JOSEPH A ,  BRANDVOLD TIMOTHY A

Inventor： KOCAL JOSEPH A ,  BRANDVOLD TIMOTHY A

IPC: C11B1/04 ,  C11B1/10 ,  C11B1/12

CPC classification number: C10K1/00 ,  B01J23/007 ,  B01J23/02 ,  B01J29/082 ,  C10B49/22 ,  C10B53/02 ,  C10B57/06 ,  C10B57/18 ,  C10C5/00 ,  C10G2300/1014 ,  C10K1/34 ,  C10K3/026 ,  Y02E50/14 ,  Y02P30/20

Abstract: Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.

Abstract translation: 提供了生产还原酸木质纤维素衍生的热解油的方法。 在一个过程中，木质纤维素材料被送入加热区。 碱性固体催化剂被输送到加热区。 木质纤维素材料在碱性固体催化剂存在下在加热区中被热解以产生热解气体。 热解气体中的氧在加热区中催化转化成可分离的物质。 将热解气体从加热区中除去并液化以形成还原的酸木质纤维素衍生的热解油。

公开(公告)号：WO2013019328A2

公开(公告)日：2013-02-07

申请号：PCT/US2012/043066

申请日：2012-06-19

Applicant: UOP LLC ,  KOCAL, Joseph A. ,  BRANDVOLD, Timothy A.

Inventor： KOCAL, Joseph A. ,  BRANDVOLD, Timothy A.

IPC: C11B1/04 ,  C11B1/10 ,  C11B1/12

CPC classification number: C10K1/00 ,  B01J23/007 ,  B01J23/02 ,  B01J29/082 ,  C10B49/22 ,  C10B53/02 ,  C10B57/06 ,  C10B57/18 ,  C10C5/00 ,  C10G2300/1014 ,  C10K1/34 ,  C10K3/026 ,  Y02E50/14 ,  Y02P30/20

Abstract: Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.

Abstract translation: 提供了生产降低的酸性木素纤维素衍生的裂解油的方法。 在一个过程中，将木质纤维素材料送入加热区。 碱性固体催化剂被输送到加热区。 木质纤维素材料在碱性固体催化剂存在下在加热区中热解，以产生热解气体。 热解气体中的氧气在加热区域被催化转化为可分离的物质。 热解气体从加热区被去除，并被液化以形成还原酸木质纤维素衍生的裂解油。

公开(公告)号：WO2013015955A3

公开(公告)日：2013-01-31

申请号：PCT/US2012/045343

申请日：2012-07-03

Applicant: UOP LLC ,  CHEN, John, Q. ,  KALNES, Tom, N. ,  KOCAL, Joseph, A.

Inventor： CHEN, John, Q. ,  KALNES, Tom, N. ,  KOCAL, Joseph, A.

IPC: C07C29/157 ,  C07C31/26 ,  B01J23/40

Abstract: A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.