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    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
    2.
    发明申请
    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL 审中-公开
    将固体生物质转化为液体碳氢化合物

    公开(公告)号：WO2016001170A1

    公开(公告)日：2016-01-07

    申请号：PCT/EP2015/064749

    申请日：2015-06-29

    Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

    Inventor： URADE, Vikrant, Nanasaheb ,  CHILKOOR SOUNDARARAJAN, Laxmi, Narasimhan ,  PANCHAGNULA, Madhusudhan, Rao ,  DEL PAGGIO, Alan, Anthony

    IPC: C10K1/00 ,  C10K3/04 ,  C10G1/06 ,  C10G1/08 ,  C10G1/10 ,  C10G3/00

    CPC classification number: C10G1/002 ,  C10G1/06 ,  C10G1/086 ,  C10G1/10 ,  C10G3/42 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/202 ,  C10K1/004 ,  C10K3/04 ,  Y02P30/20

    Abstract: The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein the one or more active metals are present in an oxidic state; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H 2 O, H 2 , CO 2 , CO, C 1 - C 3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H 2 O, CO 2 , CO, H 2 , and C 1 - C 3 gas generated in step a), to produce a vapour phase product 25 comprising substantially fully deoxygenated hydrocarbon product, H 2 O, CO, CO 2 , and C 1 – C 3 gases.

    Abstract translation: 本发明提供了一种从固体生物质原料生产液态烃产物的方法，所述方法包括以下步骤：a）在第一加氢热解反应器容器中提供第一加氢热解催化剂组合物，所述组合物包含一种或多种选自钴 ，钼，镍，钨，钌，铂，钯，铱和铁在氧化物载体上，其中所述一种或多种活性金属以氧化态存在; b）将所述固体生物质原料与所述第一加氢热解催化剂组合物和所述第一加氢热解反应器容器中的分子氢在350至600℃的温度和0.50至7.50MPa的压力范围内接触，以产生 包含部分脱氧加氢热解产物，H 2 O，H 2，CO 2，CO，C 1 -C 3气体，炭和催化剂细粉的产物流; c）从所述产品流中除去所述焦炭和催化剂细粒; d）在一种或多种加氢转化催化剂和步骤a）中产生的H 2 O，CO 2，CO，H 2和C 1 -C 3气的存在下，在加氢转化反应器容器中加氢转化所述部分脱氧加氢热解产物，以产生气相产物 25，其包括基本上完全脱氧的烃产物，H 2 O，CO，CO 2和C 1 -C 3气体。

    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
    3.
    发明申请
    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL 审中-公开
    将固体生物质转化为液体碳氢化合物

    公开(公告)号：WO2016001163A1

    公开(公告)日：2016-01-07

    申请号：PCT/EP2015/064732

    申请日：2015-06-29

    Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

    Inventor： URADE, Vikrant, Nanasaheb ,  CHILKOOR SOUNDARARAJAN, Laxmi, Narasimhan ,  GOPAL, Srikant ,  PANCHAGNULA, Madhusudhan, Rao ,  DEL PAGGIO, Alan, Anthony

    IPC: C10K1/00 ,  C10K3/04 ,  C10G1/06 ,  C10G1/08 ,  C10G1/10 ,  C10G3/00

    CPC classification number: C10G1/002 ,  C10G1/06 ,  C10G1/086 ,  C10G1/10 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10K1/002 ,  C10K1/004 ,  C10K3/04 ,  Y02P30/20

    Abstract: The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolys is reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein the active metals are present in a partially sulfided form to the extent that the first hydropyrolysis catalyst composition contains sulfur in an amount of from 10 to 90% of a full stoichiometric amount; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H 2 O, H 2 , CO 2 , CO, C 1 - C 3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor 25 vessel in the presence of one or more hydroconversion catalyst and of the H 2 O, CO 2 , CO, H 2 , and C 1 - C 3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H 2 O, CO, CO 2 , and C 1 – C 3 gases.

    Abstract translation: 本发明提供了一种从固体生物质原料生产液态烃产物的方法，所述方法包括以下步骤：a）在第一加氢反应器中提供第一加氢热解催化剂组合物，所述组合物包含一种或多种选自 钴，钼，镍，钨，钌，铂，钯，铱和铁在氧化物载体上，其中活性金属以部分硫化形式存在，其程度为第一加氢热解催化剂组合物含有量为10 至90％的完全化学计量的量; b）将所述固体生物质原料与所述第一加氢热解催化剂组合物和所述第一加氢热解反应器容器中的分子氢在350至600℃的温度和0.50至7.50MPa的压力范围内接触，以产生 包含部分脱氧加氢热解产物，H 2 O，H 2，CO 2，CO，C 1 -C 3气体，炭和催化剂细粉的产物流; c）从所述产品流中除去所述焦炭和催化剂细粒; d）在一个或多个加氢转化催化剂和步骤a）中产生的H 2 O，CO 2，CO，H 2和C 1 -C 3气的存在下，在加氢转化反应器25容器中加氢转化所述部分脱氧加氢热解产物，以产生气相 产物包含基本上完全脱氧的烃产物，H 2 O，CO，CO 2和C 1 -C 3气体。

    PROCESS FOR CONVERTING A BIOMASS-DERIVED PYROLYSIS OIL, METHOD FOR PREPARING A CATALYST, AND A CATALYST
    5.
    发明申请
    PROCESS FOR CONVERTING A BIOMASS-DERIVED PYROLYSIS OIL, METHOD FOR PREPARING A CATALYST, AND A CATALYST 审中-公开
    用于转化生物质衍生的热解油的方法，制备催化剂的方法和催化剂

    公开(公告)号：WO2015104320A1

    公开(公告)日：2015-07-16

    申请号：PCT/EP2015/050235

    申请日：2015-01-08

    Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

    Inventor： FRANSSEN, Nicole Maria Gerarda ,  RIGUTTO, Marcello Stefano

    IPC: B01J37/04 ,  B01J23/72 ,  B01J23/755 ,  C10G3/00

    CPC classification number: C10G3/45 ,  B01J23/72 ,  B01J23/755 ,  B01J37/04 ,  B01J37/08 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/70 ,  Y02P30/20

    Abstract: A process for converting a biomass-derived pyrolysis oil in which the pyrolysis oil is contacted with hydrogen in the presence of a catalyst, comprising the following steps: i) preparing a catalyst containing at least one or more Group VIII metals, preferably in an amount of equal to or more than 2wt%, more preferably equal to or more than 16wt%, even more preferably equal to or more than 18wt%, most preferably equal to or more than 20wt%, to equal to or less than 80wt%, more preferably to equal to or less than 65wt% based on the total weight of the catalyst, by a method comprising - (a) comulling (1) a refractory oxide, (2) a small amount of liquid, chosen such that the Loss On Ignition (LOI) at 485°C of the mixture is from equal to or more than 20wt% to equal to or less than 70wt% based on the total weight of the catalyst composition,and (3) at least one or more metal component(s), which is/are at least partially insoluble in the amount of liquid used, to form a mixture, wherein the metal component(s) is/are at least one or more Group VIII metal component, preferably nickel or a nickel component; - (b) optionally shaping, and drying of the mixture thus obtained; and - (c) calcination of the composition thus obtained to provide a calcined catalyst; and ii) contacting a feed containing the biomass-derived pyrolysis oil with hydrogen at a temperature in the range from 50°C to 350°C in the presence of the catalyst prepared in step i).

    Abstract translation: 一种转化生物质衍生的热解油的方法，其中所述热解油在催化剂存在下与氢接触，所述方法包括以下步骤：i）制备含有至少一种或多种第Ⅷ族金属的催化剂，优选量为 等于或大于2重量％，更优选等于或大于16重量％，甚至更优选等于或大于18重量％，最优选等于或大于20重量％，等于或小于80重量％ 优选等于或小于65重量％，通过包括以下的方法：（a）将（1）难熔氧化物，（2）少量液体，选择为使得点火损失 混合物的485℃下的（LOI）为基于催化剂组合物的总重量等于或大于20重量％至等于或小于70重量％，和（3）至少一种或多种金属组分 ），其至少部分不溶于所用液体的量，以形成混合物，其中 金属组分为至少一种或多种第VIII族金属组分，优选镍或镍组分; - （b）任选地成型和干燥由此获得的混合物; 和（c）煅烧由此获得的组合物以提供煅烧催化剂; 和ii）在步骤i）中制备的催化剂的存在下，将含有生物质衍生的热解油的进料与氢气在50℃至350℃的温度下接触。

    METHODS AND SYSTEMS EMPLOYING A HORIZONTALLY CONFIGURED DIGESTION UNIT FOR HYDROTHERMAL DIGESTION OF CELLULOSIC BIOMASS SOLIDS
    8.
    发明申请
    METHODS AND SYSTEMS EMPLOYING A HORIZONTALLY CONFIGURED DIGESTION UNIT FOR HYDROTHERMAL DIGESTION OF CELLULOSIC BIOMASS SOLIDS 审中-公开
    使用水平生物质固体水热消解的水平配置消毒装置的方法和系统

    公开(公告)号：WO2014179306A3

    公开(公告)日：2014-12-24

    申请号：PCT/US2014035863

    申请日：2014-04-29

    Applicant: SHELL OIL CO ,  SHELL INT RESEARCH

    Inventor： POWELL JOSEPH BROUN ,  BOS ALOUISIUS NICOLAAS RENEE ,  KLUSENER PETER ANTON AUGUST ,  PLOEMEN INGMAR HUBERTUS JOSEPHINA

    IPC: C10G3/00 ,  C07C29/09 ,  C08H7/00 ,  C08L1/10 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08

    CPC classification number: C07C29/132 ,  C08H6/00 ,  C08H8/00 ,  C10G1/002 ,  C10G1/006 ,  C10G1/065 ,  C10G1/08 ,  C10G1/083 ,  C10G3/42 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/55 ,  C10G2300/1014 ,  Y02E50/343 ,  Y02P30/20

    Abstract: Biomass compaction during hydrothermal digestion of cellulosic biomass solids may become problematic, particularly as the vertical height of a cellulosic biomass charge increases. Compaction may be decreased in a horizontally configured hydrothermal digestion unit. Methods for digesting cellulosic biomass solids may comprise: providing a hydrothermal digestion unit having a length or a width greater than its height and containing a fluid phase digestion medium and a slurry catalyst capable of activating molecular hydrogen; introducing cellulosic biomass solids to the hydrothermal digestion unit; distributing the cellulosic biomass solids laterally within the hydrothermal digestion unit; after or while the cellulosic biomass solids are being distributed, supplying an upwardly directed flow of molecular hydrogen through the cellulosic biomass solids and the fluid phase digestion medium; and heating the cellulosic biomass solids in the presence of the slurry catalyst and the molecular hydrogen, thereby forming an alcoholic component derived from the cellulosic biomass solids.

    Abstract translation: 在纤维素生物质固体的热液消解过程中的生物量压实可能变得有问题，特别是随着纤维素生物质电荷的垂直高度增加。 在水平配置的水热消解装置中压实可能会减少。 消化纤维素生物质固体的方法可以包括：提供具有大于其高度的长度或宽度的水热消化单元，并且含有流体相消化介质和能够活化分子氢的淤浆催化剂; 将纤维素生物质固体引入水热消解单元; 在水热消解单元内横向分布纤维素生物质固体; 在分配纤维素生物质固体之后或同时，通过纤维素生物质固体和流体相消化介质供应向上指向的分子氢流; 并在浆料催化剂和分子氢的存在下加热纤维素生物质固体，从而形成衍生自纤维素生物质固体的醇组分。

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