Abstract:
Provided are one-part, shelf-stable polyurethane aerosol compositions, and related articles and methods. When sprayed onto a substrate and dried, these compositions provide polyurethane films. These polyurethane films display improved moisture resistance, optical clarity, and weatherability compared to known aerosol compositions, particularly in adverse environmental conditions. The compositions generally include an aqueous polyurethane dispersion containing a urethane moiety obtained by reacting (i) a polyol or thiol having isocyanate-reactive functional groups, (ii) a neutralized water-solubilizing compound, and (iii) a diisocyanate and optionally a silane terminal group; a propellant; and optionally one or more additives.
Abstract:
A method of making a silyl-terminated polyurethane in an aqueous dispersion aqueous silyl-terminated polyurethane dispersions are described. In one embodiment, the polyurethane comprises a) urethane moieties derived from the reaction of a (i) a diol; (ii) a neutralized anionic water solubilizing compound; and iii) a diisocyanate. The polyurethane also comprises b) silyl terminal groups derived from an alkoxy silane compound having the formula (R 3 O) 3 SiR 4 -Z, wherein R 3 is independently hydrogen or a C 1 -C 4 alkyl; R 4 is a divalent group selected from alkylene, alkylarylene, oxyalkylene; and Z is selected from the group consisting of -OH, -SH, -NR, -NH 2 , wherein R is an aromatic or aliphatic cyclic group. The polyurethane also comprises c) urea moieties derived from the reaction of an isocyanate terminated prepolymer and a difunctional hydrazine or hydrazide compound.
Abstract:
A polyurethane polymer, a synthetic leather including such polymer, and a method of making such polymer, wherein the polyurethane polymer includes the reaction product of components including: a fluorinated mono-functional alcohol comprising a perfluorinated (C4-C6)alkyl group, a perfluorinated (C4-C6)alkylene group, or both; a fluorinated aliphatic diol comprising a perfluorinated (C4-C6)alkyl group, a perfluorinated (C4-C6)alkylene group, or both; a hydrocarbon diol; and a diisocyanate; wherein at least one of the following conditions is met: the total of the fluorinated aliphatic diol and the mono-functional alcohol is less than 2 wt-% of the components forming the polyurethane polymer; or the total fluorine content is less than 1 wt-% of the polyurethane polymer.
Abstract:
Coating compositions are described comprising an aqueous polymeric dispersion; a crosslinker; and an acid or salt of a polyalkylene oxide. Also described are articles comprising the dried and cured coating composition disposed on a substrate as well as a method a providing an anti-fog coating on a substrate.
Abstract:
Described herein is a multilayered paint film, which comprises in order: (i) a hard coat layer comprising a thermoplastic polyurethane having a hard segment content of 80 percent by weight or greater, wherein the thermoplastic polyurethane is a reaction product of: (a) a diisocyanate; (b) a polyol optionally comprising a cyclic structure; and (c) a chain extender, wherein at least one of the polyol or the chain extender comprises at least one side chain and at least one of the diisocyanate or the chain extender comprises a cyclic structure; (ii) a colored polymeric resin layer comprising a colorant, wherein the colored polymeric resin layer is 50-250 micrometers thick; and (c) an adhesive layer, wherein the adhesive layer comprises a pressure sensitive adhesive or a hotmelt adhesive. In one embodiment, the multilayered paint films may be used to cover parts for automotive and aerospace applications.
Abstract:
Described herein is a polyester polyol, which is derived from a first reaction product of (a) a Component A, wherein the Component A is a phthalic acid, a phthalic anhydride or mixtures thereof, (b) a Component B, wherein the Component B is a dimer fatty acid, a dimer fatty acid diol or mixtures thereof, and (c) a Component C, wherein the Component C is an aliphatic diol, an aromatic diol, or mixtures thereof, wherein Component C comprises 2 to 10 carbon atoms and optionally catenated heteroatoms selected from O, S, and N. Also disclosed herein are polyurethane polymers and pressure sensitive adhesives made from the polyurethane polymers or the polyester polyols.
Abstract:
The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
Abstract:
The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.
Abstract:
An optical system comprises a lightguide having an elongated recess formed therein. The recess divides the lightguide into a first lightguide section a second larger lightguide section. Light extractors are disposed in the second, but not the first, lightguide section for extracting light that would otherwise propagate within and along the second lightguide section via total internal reflection (TIR). The depth of the recess varies along its length. The inclusion of a recess having a depth that varies along its length provides design flexibility in the number and location of light source(s) used by the optical system.
Abstract:
A pressure sensitive adhesive composition includes a polyurethane polymer that includes the reaction product of an aliphatic polyisocyanate component, a polyol component, and a functional acid containing compound. The polyol component has a total solubility parameter ranging from 10 to 14 (cal/cm 3 ) 1/2 .
Abstract translation:压敏粘合剂组合物包括聚氨酯聚合物,其包括脂族多异氰酸酯组分,多元醇组分和含官能酸的化合物的反应产物。 多元醇组分的总溶解度参数为10-14(cal / cm 3)1/2。