CATALYST COMPONENT COMPRISING MAGNESIUM, TITANIUM, A HALOGEN AND AN ELECTRON DONOR, ITS PREPARATION AND USE
    51.
    发明申请
    CATALYST COMPONENT COMPRISING MAGNESIUM, TITANIUM, A HALOGEN AND AN ELECTRON DONOR, ITS PREPARATION AND USE 审中-公开
    包含镁,钛,卤素和电子的催化剂组分,其制备和使用

    公开(公告)号:WO00068277A1

    公开(公告)日:2000-11-16

    申请号:PCT/FI2000/000409

    申请日:2000-05-09

    Abstract: The invention relates to a process for the preparation of an olefin polymerisation catalyst component, said catalyst component and its use. The process is mainly characterised by the steps of: (i) reacting in solution a magnesium compound containing an alkoxy group, a carboxylic acid halide and a four-valent titanium compound containing a halogen, for obtaining a dissolved reaction product and (ii) recovering a fraction of the reaction product from step (i) in particulate form by contacting the dissolved reaction product with a mixture of an aromatic and an aliphatic hydrocarbon, or by contacting the dissolved reaction product first with an aromatic hydrocarbon and then with an aliphatic hydrocarbon, the amount of aromatic and aliphatic hydrocarbon being at least 5 mol per mol of magnesium.

    Abstract translation: 本发明涉及制备烯烃聚合催化剂组分,所述催化剂组分及其用途的方法。 该方法的主要特征在于:(i)在溶液中使含有烷氧基的镁化合物,羧酸卤化物和含有卤素的4价钛化合物反应,以获得溶解的反应产物和(ii)回收 通过使溶解的反应产物与芳族烃和脂族烃的混合物接触,或通过使溶解的反应产物首先与芳族烃接触,然后与脂族烃接触,得到来自步骤(i)的反应产物的一部分, 芳族和脂族烃的量相对于每摩尔镁为至少5摩尔。

    PROCESS FOR PREPARING PROPYLENE POLYMER COMPOSITIONS
    54.
    发明申请
    PROCESS FOR PREPARING PROPYLENE POLYMER COMPOSITIONS 审中-公开
    制备丙烯聚合物组合物的方法

    公开(公告)号:WO2017001474A1

    公开(公告)日:2017-01-05

    申请号:PCT/EP2016/065139

    申请日:2016-06-29

    Applicant: BOREALIS AG

    Abstract: The present invention relates to an olefin polymerization process, wherein propylene and a C4 to C10 a-olefin, preferably 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst so as to obtain a polypropylene, wherein the polypropylene comprises C4 to C10 a-olefin, preferablyl-butene-derived comonomer units in an amount of from 0.5 wt% to 15 wt% and ethylene-derived comonomer units in an amount of 0 wt% to 3 wt%, and wherein the Ziegler-Natta catalyst comprises i) an external donor of the formula (I): (R 3 ) z (R 2 O) y Si(R 1 )x and ii) a solid Ziegler-Natta catalyst component being free of external carrier material.

    Abstract translation: 烯烃聚合方法本发明涉及一种烯烃聚合方法,其中丙烯和C 4至C 10α-烯烃,优选1-丁烯和任选的乙烯在齐格勒 - 纳塔催化剂存在下反应以获得聚丙烯,其中聚丙烯包含 C 5〜C 10α-烯烃,优选1-丁烯衍生的共聚单体单元,其量为0.5重量%〜15重量%,乙烯衍生的共聚单体单元的量为0重量%〜3重量%,其中齐格勒 - 纳塔 催化剂包括:i)式(I)的外部供体:(R3)z(R2O)ySi(R1)x和ii)不含外部载体材料的固体齐格勒 - 纳塔催化剂组分。

    POLYETHYLENE COMPOSITION FOR PIPE AND PIPE COATING APPLICATIONS
    58.
    发明申请
    POLYETHYLENE COMPOSITION FOR PIPE AND PIPE COATING APPLICATIONS 审中-公开
    用于管道和管道涂层应用的聚乙烯组合物

    公开(公告)号:WO2015051881A1

    公开(公告)日:2015-04-16

    申请号:PCT/EP2014/002590

    申请日:2014-09-24

    Applicant: BOREALIS AG

    Abstract: The present application relates to a polyethylene composition comprising a base resin being a copolymer of ethylene with at least one alpha olefin comonomer having from 3 to 12 carbon atoms, the base resin having a density of more than 940.0 kg/m 3 and equal to or less than 952.5 kg/m 3 , determined according to ISO 1 183-1:2004, wherein the composition has a melt flow rate MFR5 (190°C, 5 kg) of 0.10 to 3.0 g/10min, determined according to ISO 1 133, a storage modulus of G' (2 kPa) of 600 Pa to 900 Pa, a shear thinning index SHI 2.7/210 of 20 to 50 and the composition has an elongation at break (EB) at -45°C in dependence of the molar comonomer content (mol. CC) of the base resin following the following equation EB [%] ≥ 175 [% / mol%] ⋅ mol. CC [mol%], whereby the elongation at break (EB) is determined according to ISO 527- 1 at a temperature of -45°C and the molar comonomer content (mol. CC) reflects the molar content of alpha-olefin comonomer units in the total content of monomer units of the base resin, an article comprising such a polyethylene composition and the use of such a polyethylene composition for the production of an article.

    Abstract translation: 本申请涉及一种聚乙烯组合物,其包含基础树脂,其是乙烯与至少一种具有3至12个碳原子的α-烯烃共聚单体的共聚物,所述基础树脂的密度大于940.0kg / m 3且等于或小于 根据ISO 1 183-1:2004确定的952.5kg / m 3,其中该组合物的熔体流动速率MFR5(190℃,5kg)为0.10-3.0g / 10min,根据ISO 1 133测定,a G'(2kPa)的储能模量为600Pa至900Pa,剪切稀化指数SHI2.7 / 210为20至50,组合物在-45℃下的断裂伸长率(EB)根据摩尔 基础树脂的共聚单体含量(摩尔CC)按照以下等式EB [%]≥175[%/ mol%]∙mol。 CC [mol%],其中在-45℃的温度下根据ISO 527-1测定断裂伸长率(EB),共聚单体摩尔含量(mol CC)反映了α-烯烃共聚单体单元的摩尔含量 在基础树脂的单体单元的总含量中,包含这种聚乙烯组合物的制品以及使用这种聚乙烯组合物来制造制品。

    POLYETHYLENE COMPOSITION FOR PIPE APPLICATIONS
    59.
    发明申请
    POLYETHYLENE COMPOSITION FOR PIPE APPLICATIONS 审中-公开
    用于管道应用的聚乙烯组合物

    公开(公告)号:WO2015051879A1

    公开(公告)日:2015-04-16

    申请号:PCT/EP2014/002588

    申请日:2014-09-24

    Applicant: BOREALIS AG

    Abstract: The present invention relates to a polyethylene composition for pipe applications comprising a base resin having a density of more than 946.0 kg/m 3 and equal to or less than 955.0 kg/m 3 , wherein the composition has a MFR 21 of 1.7 to 7.0 g/10 min and a FRR 21/5 of more than 10 to equal to or less than 40, and a polyethylene composition obtainable by a multistage process, the multistage process comprising polymerizing ethylene in the presence of a silica supported Ziegler Natta catalyst in a first loop reactor, transferring a first intermediate material to a second loop reactor, further polymerizing said first intermediate material for obtaining a second intermediate material and transferring said second intermediate material to a gas phase reactor, feeding ethylene and comonomer to the gas phase reactor for obtaining a base resin, and finally extruding the base resin together with stabilizers and carbon black into the polyethylene composition. The invention further concerns a multistage process for the production of the polyethylene composition and articles, preferably pipes, made from the inventive polyethylene composition.

    Abstract translation: 本发明涉及用于管道用途的聚乙烯组合物,其包含密度大于946.0kg / m 3且等于或小于955.0kg / m 3的基础树脂, 其中所述组合物具有1.7至7.0克/ 10分钟的MFR 21和大于10至100的FRR 21/5。 等于或小于40的聚乙烯组合物,以及可通过多级方法获得的聚乙烯组合物,所述多级方法包括在二氧化硅负载的齐格勒纳塔催化剂的存在下在第一回路反应器中聚合乙烯,将第一中间材料转移到第二回路反应器中, 进一步聚合所述第一中间材料以获得第二中间材料并将所述第二中间材料转移至气相反应器,将乙烯和共聚单体供给至气相反应器以获得基础树脂,最后将基础树脂与稳定剂和碳一起挤出 黑色变成聚乙烯 组成。 本发明还涉及用于生产由本发明聚乙烯组合物制成的聚乙烯组合物和制品(优选管)的多阶段方法。

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