公开(公告)号：WO2007007498A1

公开(公告)日：2007-01-18

申请号：PCT/JP2006/311722

申请日：2006-06-12

Applicant: 日鉱金属株式会社 ,  新藤 裕一朗

Inventor： 新藤 裕一朗

IPC: C22B34/14 ,  B22D27/02 ,  C22B9/22 ,  C22C28/00 ,  C23C14/34

CPC classification number: C22B34/14 ,  B22D27/02 ,  C22B9/228 ,  C22B34/1295 ,  C22C27/00 ,  C22C28/00 ,  C23C14/165 ,  C23C14/3414 ,  H01L21/28079 ,  H01L21/28194 ,  H01L29/495 ,  H01L29/517

Abstract: 【課題】　ジルコニウムを低減させたハフニウムスポンジを原料として使用し、さらにハフニウム中に含まれるＦｅ，Ｃｒ，Ｎｉの不純物、Ｃａ，Ｎａ，Ｋの不純物、Ａｌ，Ｃｏ，Ｃｕ，Ｔｉ，Ｗ，Ｚｎの不純物、さらにα線のカウント数、Ｕ，Ｔｈの不純物、Ｐｂ，Ｂｉの不純物、さらにはガス成分であるＣ量を、それぞれ低減させた高純度ハフニウムの製造方法に関し、効率的かつ安定した製造技術及びそれによって得られた高純度ハフニウム材料、同材料からなるスパッタリング用ターゲット及びゲート絶縁膜又はメタルゲート用薄膜を提供する。 【解決手段】　Ｚｒとガス成分を除き純度６Ｎ以上であって、Ｆｅ，Ｃｒ，Ｎｉがそれぞれ０．２ｐｐｍ以下、Ｃａ，Ｎａ，Ｋがそれぞれ０．１ｐｐｍ以下、Ａｌ，Ｃｏ，Ｃｕ，Ｔｉ，Ｗ，Ｚｎがそれぞれ０．１ｐｐｍ以下であることを特徴とする高純度ハフニウム。

Abstract translation: [问题]提供：从以锆为原料的铪海绵生产高纯度铪的方法，高纯度铪的Fe，Cr和Ni杂质含量降低，Ca含量， Na和K杂质，Al，Co，Cu，Ti，W和Zn杂质的含量，a射线计数，U和Th杂质含量，Pb和Bi杂质含量以及作为可气化物质的碳含量; 高效稳定的生产技术; 通过该技术获得的高纯度铪材料; 以及用于金属浇口使用的溅射靶和栅极绝缘体或薄膜，其各自包括该材料。 [解决问题的手段]高纯度铪的特征在于，不含Zr和可气化物质的铪的纯度为6N以上，Fe，Cr，Ni的含量分别为0.2ppm以下， 的Ca，Na和K分别为0.1ppm以下，Al，Co，Cu，Ti，W，Zn的含量分别为0.1ppm以下。

公开(公告)号：WO02052051A3

公开(公告)日：2002-09-12

申请号：PCT/US0148989

申请日：2001-12-19

Applicant: RMI TITANIUM CO

Inventor： SPADAFORA FRANK P ,  YU KUANG-O

IPC: B22D11/00 ,  C21C5/52 ,  C21C5/56 ,  C22B9/22 ,  C22B34/12 ,  C22C14/00 ,  B22D11/10 ,  B22D27/02

CPC classification number: B22D11/001 ,  B22D11/041 ,  B22D11/11 ,  B22D21/005 ,  B22D27/06 ,  C21C5/5205 ,  C21C5/567 ,  C22B9/226 ,  C22B9/228 ,  C22B34/1295 ,  C22C14/00 ,  Y02P10/216

Abstract: A method for heartless processing of a solid metallic material consisting essentially of titanium or other metal or alloy thereof which includes providing a solid metal block (10) having processing surface (14) and a base surface (12) and consisting essentially of titanium or a metal, forming a pool of molten metal (22) on the processing surface of the solid block provided in step, adding the metallic material (30) to be processed to the pool of molten metal formed in step, and melting the metallic material to be processed, and removing metallic material melted in step from the pool of molten metal.

Abstract translation: 一种用于对基本上由钛或其它金属或其合金组成的固体金属材料的无心加工的方法，其包括提供具有处理表面（14）和基底表面（12）的固体金属块（10），并且基本上由钛或 金属，在步骤中提供的固体块的加工表面上形成熔融金属池（22），将待处理的金属材料（30）加入到步骤中形成的熔融金属池中，并将金属材料熔化成 加工和去除从熔融金属池中逐步熔化的金属材料。

公开(公告)号：WO02029125A1

公开(公告)日：2002-04-11

申请号：PCT/JP2001/005612

申请日：2001-06-29

IPC: B22F9/02 ,  C22B9/22 ,  C22B34/14 ,  C22C1/04 ,  C22C16/00 ,  C22C27/00 ,  C23C14/34 ,  H01L21/28 ,  H01L23/532 ,  H01L29/51 ,  B22F9/04

CPC classification number: H01L21/28194 ,  B22F9/023 ,  C22B9/228 ,  C22B34/14 ,  C22C1/0458 ,  C22C16/00 ,  C22C27/00 ,  C23C14/3414 ,  H01L23/53257 ,  H01L29/51 ,  H01L29/517 ,  H01L2924/0002 ,  H01L2924/00

Abstract: A high purity zirconium or hafnium which is extremely reduced in the contents of an alkali metal such as Na or K, a radioactive element such as U or Th, a transition metal or heavy metal or high melting point metal such as Fe, Ni, Co, Cr, Cu, Mo, Ta or V, and a gas forming element such as C or O; and a method for producing a high purity zirconium or hafnium which allows the production thereof at a low cost; and a method for producing a powder of high purity zirconium or hafnium with safety and at a low cost which comprises using a hydrogenated high purity zirconium or hafnium as a material. The high purity zirconium or hafnium is greatly reduced in the contents of impurities which are obstacles to assurance of operational functions of a semiconductor.

Abstract translation: Na，K等碱金属，U，Th等放射性元素，过渡金属，重金属，Fe，Ni，Co等高熔点金属的含量极高的锆或铪 ，Cr，Cu，Mo，Ta或V，以及诸如C或O的气体形成元件; 以及能够以低成本制造高纯度的锆或铪的方法。 以及安全且低成本地制造高纯度锆或铪粉末的方法，其包括使用氢化高纯度锆或铪作为材料。 高纯度的锆或铪的杂质含量大大降低，这是保证半导体操作功能的障碍。

公开(公告)号：WO0023628A9

公开(公告)日：2001-10-11

申请号：PCT/US9923889

申请日：1999-10-15

Applicant: JOSEPH ADRIAN A

Inventor： JOSEPH ADRIAN A

IPC: C22B4/00 ,  C22B9/22 ,  C22B34/12 ,  C22C14/00 ,  C22B

CPC classification number: C22B34/1295 ,  C22B4/005 ,  C22B9/228 ,  C22B34/1222 ,  C22B34/1272 ,  C22C14/00 ,  Y02P10/23

Abstract: A method for refining a titanium metal containing ore such as rutile or illmenite or mixtures to produce titanium ingots or titanium alloys and compounds of titanium involves production of titanium tetrachloride as a molten slag, by processing the ore in a chlorination procedure and removing various impurities by a distillation or other procedure to form a relatively pure titanium tetrachloride (TiCl4). Thereafter, the titanium tetrachloride is introduced into the plasma focal point of a plasma reactor in a molten sodium environment for the initial reduction of gas phase titanium into titanium molten drops which are collected by a set of skulls. Thereafter, further processing are carried out in higher vacuum and the titanium is heated by electron beam guns in order to maximize titanium purity and, in a final optional stage, alloying compounds are added under yet higher vacuum and high temperature conditions.

Abstract translation: 用于精炼含金属矿的钛金属如金红石或伊玛斯特或混合物以生产钛锭或钛合金和钛的化合物的方法涉及生产四氯化钛作为熔渣，通过在氯化方法中处理矿石并通过 蒸馏或其它方法以形成相对纯的四氯化钛（TiCl 4）。 此后，将四氯化钛引入到熔融钠环境中的等离子体反应器的等离子体焦点中，以便将气相钛初始还原成由一组头骨收集的钛熔融液滴。 此后，在更高的真空中进行进一步加工，并且通过电子束枪加热钛，以使钛纯度最大化，并且在最后的任选阶段中，在更高的真空和高温条件下加入合金化合物。

公开(公告)号：WO01057284A1

公开(公告)日：2001-08-09

申请号：PCT/US2001/003325

申请日：2001-02-01

IPC: B01F3/12 ,  B01F11/02 ,  B01F13/08 ,  C22B9/22 ,  C22C47/08

CPC classification number: B82Y30/00 ,  B01F11/02 ,  B01F13/0809 ,  B01F2003/125 ,  B01F2215/0049 ,  B01F2215/0075 ,  B22F2009/0856 ,  C22B9/22 ,  C22C47/08

Abstract: The present invention relates to fullerene, nanotube, or nanofiber filled metals and polymers. This invention stems from a cross-disciplinary combination of electromagnetic and acoustic processing and property enhancement of materials through fullerene or nanofiber additives. Containerless processing (CP) in the form of electromagnetic field enduced and/or acoustic mixing leads to controlled dispersion of fullerenes, nanotubes, or nanofibers in various matrices. The invention provides methods of mixing that highly disperse and align the fullerenes, nanotubes, or nanofibers within the matrices of metals and polymers. The invention provides new compositions of matter and multifunctional materials based on processing, composition, and degree of in situ processing.

Abstract translation: 本发明涉及富勒烯，纳米管或纳米纤维填充的金属和聚合物。 本发明源于通过富勒烯或纳米纤维添加剂的材料的电磁和声学加工和性能增强的跨学科组合。 电磁场形式和/或声学混合形式的无容器加工（CP）导致富勒烯，纳米管或纳米纤维在各种基体中受控的分散。 本发明提供了将金属和聚合物基质中的富勒烯，纳米管或纳米纤维高度分散和排列的混合方法。 本发明提供了基于加工，成分和原位处理程度的物质和多功能材料的新组合物。

公开(公告)号：WO0116392A3

公开(公告)日：2001-06-21

申请号：PCT/DE0003036

申请日：2000-09-01

Applicant: DRESDEN EV INST FESTKOERPER ,  SCHWARZ WOLFGANG ,  ECKERT JUERGEN ,  SCHINNERLING SABINE

Inventor： SCHWARZ WOLFGANG ,  ECKERT JUERGEN ,  SCHINNERLING SABINE

IPC: C22B9/22 ,  C22C1/00 ,  C22C1/02 ,  C22C45/00 ,  C23C24/10 ,  C23C26/00 ,  C23C26/02

CPC classification number: C23C26/02 ,  C23C24/10

Abstract: The aim of the invention is to develop a method for producing massive-amorphous layers on massive metallic shaped bodies. According to said method, amorphous layers having a thickness of > 20 ñm can be produced in only one procedure step. To this end, alloys which can be used for producing massive metallic glasses under quick solidification conditions or alloy elements which can be used for producing massive metallic glasses together with the elements of the shaped body material and under quick solidification conditions are molten by means of high-energy radiation and are directly applied onto the massive metallic shaped body for producing an amorphous layer that is > 20 mu m up to several millimetre thick or are alloyed into the surface of the shaped bodies. The melt is quickly solidified by means of natural cooling and/or forced air cooling of the shaped body. The inventive method enables to coat metallic shaped bodies with massive metallic glasses which improve the surface characteristics. Such layers can be used for increasing the anticorrosion or wear and tear properties of shaped bodies for instance.

Abstract translation: 本发明具有的目的是开发用于上块状金属成型体生产固体无定形层的过程中，随着厚度的> 20亩非晶层可以在仅仅一个工艺步骤米来制造。 这个目的是在合金，其适合用于形成块状金属玻璃，或合金，其适合快速凝固条件下与所述成型体材料的元件一起的元件，通过高能辐射以形成块状金属玻璃，制成熔融并直接向快速凝固条件下创造性实现 块状金属成形体以产生> 20微米到几毫米厚的非晶形层被涂布或熔合到模具主体的表面上，熔融物的快速凝固是通过利用成型体的自冷却和/或由该成形体的外部冷却带来的。 利用该方法，有可能以涂覆金属模本体与块状金属玻璃，其构成的表面性能的改进。 这样的层可以，例如，用于增加腐蚀或磨损的模制品的电阻。

公开(公告)号：WO00068440A1

公开(公告)日：2000-11-16

申请号：PCT/JP2000/002866

申请日：2000-05-01

IPC: B09B3/00 ,  C21B13/12 ,  C22B5/02 ,  C22B7/00 ,  C22B7/02 ,  C22B9/00 ,  C22B9/02 ,  C22B9/22 ,  F27B14/14 ,  H05B6/10 ,  C21B15/00

CPC classification number: C21B13/12 ,  C22B5/02 ,  C22B7/003 ,  C22B9/003 ,  Y02P10/212 ,  Y02P10/253

Abstract: A device (1) for induction-heating and melting metal oxides-containing powder and granular material, which can suitably remove metals in burned ash and flying ash to render them harmless, recover metals with high purities and recovery rates and is high in equipment productivity and low in running costs, the device comprising an enclosed hopper (2), a heat-resistant pipeline (3) for supplying powder and granular material to an induction-heating pipe (5) therefrom, the dielectric induction-heating pipe (5) vertically slidably in contact with the lower end of the heat-resistant pipeline and its vertically driving mechanism (5A), a receiver (6) for receiving molten liquid of the powder and granular material melted in the induction-heating pipe (or a filler (60) for receiving the liquid of powder and granular material melted in the same pipe), a cylindrical upper vacuum chamber (8) for enclosing them, induction-heating coils (10) for surrounding the lower portion of the cylindrical upper vacuum chamber, an electric dust collector (4) located at the upper portion in the vacuum chamber, an inclined pan (11) for relaying molten liquid overflowing the receiver (6) to flow down (flowing down from the filler (6)) and its inclining mechanism (11), a molten liquid storing tank (12) for receiving and storing molten liquid flowing down from the inclined pan, and a lower vacuum chamber (16) for enclosing the inclined pan and the molten liquid storing tank and communicating with the lower end of the upper vacuum chamber.

Abstract translation: 用于感应加热和熔化含金属氧化物的粉末和颗粒材料的装置（1），其可以适当地去除烧灰和飞灰中的金属使其无害，回收高纯度和回收率的金属，并且设备生产率高 所述装置包括封闭的料斗（2），用于将粉末和颗粒材料供应到感应加热管（5）的耐热管道（3），介电感应加热管（5） 可垂直滑动地与耐热管道的下端及其垂直驱动机构（5A）接触;接收器（6），用于接收熔化在感应加热管（或填料（ 60），用于接收在同一管道中熔化的粉末和颗粒材料的液体），用于封闭它们的圆柱形上部真空室（8），用于围绕圆柱形上部va的下部的感应加热线圈（10） 位于真空室上部的电动集尘器（4），用于将溢出接收器（6）的熔融液体向下流动（从填料（6）向下流））的倾斜盘（11）和 其倾斜机构（11），用于接收和储存从倾斜盘向下流动的熔融液体的熔融液体储存罐（12），以及用于封闭倾斜盘和熔融液体储存罐的下部真空室（16），并与 上真空室的下端。

公开(公告)号：WO99061672A1

公开(公告)日：1999-12-02

申请号：PCT/US1999/011169

申请日：1999-05-20

IPC: C22B9/20 ,  C22B5/04 ,  C22B9/22 ,  C22B34/24 ,  C22C1/02 ,  C22C1/04 ,  C22C27/02 ,  C22F1/00 ,  C22F1/18

CPC classification number: C22B5/04 ,  C22B34/24 ,  C22C1/045 ,  C22C27/02 ,  C22F1/18

Abstract: An alloy comprising tantalum and silicon is described. The tantalum is the predominant metal present. The alloy also has a uniformity of tensile strength when formed into a wire, such that the maximum population standard deviation of tensile strength for the wire is about 3 KSI for an unannealed wire at finish diameter and about 2 KSI for an annealed wire at finish diameter. Also described is a process of making a Ta-Si alloy which includes reducing a silicon-containing solid and a tantalum-containing solid into a liquid state and mixing the liquids to form a liquid blend and forming a solid alloy from the liquid blend. Another process of making a Ta-Si alloy is described which involves blending powders containing tantalum or an oxide thereof with powders containing silicon or a silicon-containing compound to form a blend and then reducing the blend to a liquid state and forming a solid alloy from the liquid state. Also, a method of increasing the uniformity of tensile strength in tantalum metal, a method of reducing embrittlement of tantalum metal, and a method of imparting a controlled mechanical tensile strength in tantalum metal are described which involve adding silicon to tantalum metal so as to form a Ta-Si alloy.

Abstract translation: 描述了包含钽和硅的合金。 钽是主要的金属存在。 该合金在形成线时也具有拉伸强度的均匀性，使得线材的拉伸强度的最大总体标准偏差对于完成直径处的未退火丝线的约3KSI，对于精加工直径处的退火丝线的约2KSI 。 还描述了一种制备Ta-Si合金的方法，其包括将含硅固体和含钽固体还原成液态，并将液体混合以形成液体共混物并从液体共混物形成固体合金。 描述了制造Ta-Si合金的另一种方法，其涉及将含有钽或其氧化物的粉末与含硅或含硅化合物的粉末混合以形成共混物，然后将共混物还原成液态并从 液态。 另外，提出了提高钽金属中拉伸强度的均匀性的方法，减少钽金属的脆化的方法，以及赋予钽金属受控的机械拉伸强度的方法，其涉及向钽金属添加硅以形成 Ta-Si合金。

公开(公告)号：WO99006604A1

公开(公告)日：1999-02-11

申请号：PCT/US1998/011277

申请日：1998-06-03

IPC: B22D1/00 ,  B01F13/08 ,  C21C5/52 ,  C22B9/00 ,  C22B9/02 ,  C22B9/22 ,  F27D27/00 ,  C22B9/187

CPC classification number: C22B9/003 ,  B01F13/0809 ,  B01F2215/0075 ,  C21C5/5241 ,  Y02P10/253

Abstract: Method and apparatus (40) for controlling stirring of molten metal (24) during processing in a metallurgical vessel (20), free of mechanical-contact with the molten metal (24). Efficiencies of metal processing and improvements in metallurgical properties are achieved by selecting configurations and placement of interacting apparatus (40), and by controlling electromagnetic field characteristics. Apparatus (40) can be retrofitted to an existing vessel and a reduction in vessel maintenance results from a decreased rate of slag buildup during usage.

Abstract translation: 用于在冶金容器（20）中处理期间控制熔融金属（24）的搅拌的方法和装置（40），与熔融金属（24）没有机械接触。 金属加工的效率和冶金性能的提高通过选择配置和布置相互作用的设备（40）以及通过控制电磁场特性来实现。 可以将装置（40）改装到现有的容器中，并且由于使用期间炉渣积聚速率降低而导致容器维护的减少。

公开(公告)号：WO99005330A1

公开(公告)日：1999-02-04

申请号：PCT/FR1998/001630

申请日：1998-07-23

IPC: B22D11/10 ,  B22D11/04 ,  B22D11/041 ,  B22D11/11 ,  B22D11/115 ,  B22D23/06 ,  B22D27/04 ,  B22D41/60 ,  C22B5/04 ,  C22B9/00 ,  C22B9/187 ,  C22B9/22 ,  C22B60/02 ,  F27B14/06 ,  H05B6/34

CPC classification number: B22D11/115 ,  B22D11/0401 ,  B22D11/041 ,  B22D23/06 ,  B22D27/04 ,  B22D41/60 ,  C22B5/04 ,  C22B9/003 ,  C22B60/0213 ,  F27B14/063 ,  H05B6/34 ,  Y02P10/253

Abstract: The invention concerns metallothermal process and continuous drawing of a metal product consisting of at least one metal, comprising: a step for melting the metal in a first cold crucible (1) heated by induction where the reduction of said metal oxide or salt is brought about in a reduction medium (8) and where the formed metal decants in a solvent medium (7) for the scoria resulting from reduction to be absorbed; a step for gathering and melting the decanting metal, carried out in a second cold crucible (3) heated by induction and located under the first cold crucible (1), for obtaining a continuous drawing of the metal product. The invention also concerns a device for implementing the method consisting of a first induction crucible with cold furnaces communicating with a second induction crucible with cold furnaces for continuously drawing off the molten metal. The invention is particularly useful for obtaining uranium or an alloy containing uranium.

Abstract translation: 本发明涉及金属热处理和由至少一种金属组成的金属产品的连续拉伸，包括：在通过诱导加热的第一冷坩埚（1）中熔化金属的步骤，其中所述金属氧化物或盐的还原引起 在还原介质（8）中并且其中所形成的金属在溶剂介质（7）中倾析用于由还原而被吸收的污垢; 在通过感应加热并位于第一冷坩埚（1）下方的第二冷坩埚（3）中进行的用于收集和熔化倾析金属的步骤，以获得金属产品的连续拉伸。 本发明还涉及一种用于实施该方法的装置，该装置包括：第一感应坩埚，其具有与第二感应坩埚连通的冷却炉，其具有用于连续抽出熔融金属的冷却炉。 本发明对于获得铀或含铀合金特别有用。