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    A NOVEL CATALYTIC FORMULATION AND ITS PREPARATION TECHNICAL FIELD
    81.
    发明申请
    A NOVEL CATALYTIC FORMULATION AND ITS PREPARATION TECHNICAL FIELD 审中-公开
    新型催化制剂及其制备技术领域

    公开(公告)号：WO2002078842A1

    公开(公告)日：2002-10-10

    申请号：PCT/IN2001/000083

    申请日：2001-03-30

    Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH ,  CHAUDHARI, Raghunath, Vitthal ,  MAHAJAN, Avinash, Narendra

    Inventor： CHAUDHARI, Raghunath, Vitthal ,  MAHAJAN, Avinash, Narendra

    IPC: B01J31/16

    CPC classification number: C07C45/50 ,  B01J27/188 ,  B01J31/1616 ,  B01J31/1805 ,  B01J31/183 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/321 ,  B01J2231/341 ,  B01J2231/4211 ,  B01J2231/4261 ,  B01J2231/52 ,  B01J2231/641 ,  B01J2531/025 ,  B01J2531/72 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/847 ,  C07C45/49 ,  C07C2601/14 ,  Y02P20/588 ,  C07C47/19 ,  C07C47/02 ,  C07C47/11 ,  C07C47/228 ,  C07C47/232

    Abstract: The present invention describes a generic methodology to formulate a composite solid useful for catalyzing variety of reactions, the present invention in particular relates to a heterogeneous catalyst as a formulation constituting a solid support having deposited thereon a catalytically active material, which is practically insoluble in variety of liquid media, the said insoluble material is constructed from secondary building blocks derived from suitable organometallic active components and the organometallic active component is molecularly modified so as to introduce two or more negatively charged functional groups, these molecularly modified organometallic components upon interaction with salts of Ca 2+ , Sr 2+ and Ba 2+ , provide practically insoluble solid material and the invention further ascertains various ways of formulating organometallic active material on as solid support as a solid catalyst, the methodology is suitable for preparation of wide variety of catalysts having applications in catalyzing diverse reactions in polar and nonpolar reaction media and the overall integrity of the formulation as a solid material in a liquid phase provides easy catalyst and product separation.

    Abstract translation: 本发明描述了一种用于制备可用于催化多种反应的复合固体的通用方法，本发明特别涉及一种作为构成固体载体的制剂的非均相催化剂，其上沉积有催化活性材料，其实际上不溶于多种 所述不溶性材料由衍生自合适的有机金属活性组分的二级结构单元构成，并且有机金属活性组分被分子修饰，以便引入两个或多个带负电荷的官能团，这些分子改性的有机金属组分与 Ca 2+，Sr 2+和Ba 2+提供几乎不溶的固体材料，本发明进一步确定了作为固体催化剂配制作为固体载体的有机金属活性材料的各种方式，该方法适用于制备 各种各样的催化剂具有a 在极性和非极性反应介质中催化多种反应的应用和作为液相中固体物质的配方的总体完整性提供了易于催化剂和产物分离。

    TWO-STEP PROCESS FOR SULPHIDING A CATALYST CONTAINING AN S-CONTAINING ADDITIVE
    86.
    发明申请
    TWO-STEP PROCESS FOR SULPHIDING A CATALYST CONTAINING AN S-CONTAINING ADDITIVE 审中-公开
    用于硫化包含含S添加剂的催化剂的两步法

    公开(公告)号：WO01076742A1

    公开(公告)日：2001-10-18

    申请号：PCT/EP2001/003895

    申请日：2001-04-03

    IPC: B01J23/85 ,  B01J23/88 ,  B01J27/188 ,  B01J31/02 ,  B01J31/04 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    CPC classification number: B01J31/04 ,  B01J23/85 ,  B01J23/88 ,  B01J27/188 ,  B01J31/0217 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    Abstract: The present invention pertains to a process for sulphiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or group VIII of the Periodic Table, and an S-containing organic additive wherein the catalyst composition is contacted in two steps with hydrogen and a sulphur-containing compound in the gaseous phase, with the first step being performed at a temperature which is lower than that of the second step. Catalysts sulphided by the process according to the invention show a higher activity than the same catalysts which have been sulphided in a one-step process. It is preferred to carry out the process according to the invention ex situ , where it solves the problem of difficult start-up and the formation of undesirable side products in the hydrotreating unit. The S-containing organic additive preferably is a mercapto-compound, more preferably a mercaptocarboxylic acid represented by the general formula HS-R1-COOR, wherein R1 stands for a divalent hydrocarbon group with 1-10 carbon atoms and R stands for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched alkyl group having 1 to 10 carbon atoms.

    Abstract translation: 本发明涉及一种用于硫化催化剂组合物的方法，所述催化剂组合物包含至少一种元素周期表第Ⅵ族和/或Ⅷ族的氢化金属组分和含S的有机添加剂，其中催化剂组合物分两步与氢接触 和在气相中的含硫化合物，其中第一步在低于第二步的温度下进行。 通过根据本发明的方法硫化的催化剂显示出比在一步法中硫化的相同催化剂更高的活性。 优选地，根据本发明的非原位实施方法，其解决了在加氢处理单元中难以启动和形成不期望的副产物的问题。 含S的有机添加剂优选为巯基化合物，更优选由通式HS-R1-COOR表示的巯基羧酸，其中R1表示具有1-10个碳原子的二价烃基，R表示氢原子 碱金属，碱土金属，铵或碳原子数为1〜10的直链或支链烷基。

    PROCESS FOR <i>EX SITU</i> SULPHIDING A CATALYST CONTAINING AN S-CONTAINING ADDITIVE
    87.
    发明申请
    PROCESS FOR EX SITU SULPHIDING A CATALYST CONTAINING AN S-CONTAINING ADDITIVE 审中-公开
    用于硫化包含含S添加剂的催化剂的步骤

    公开(公告)号：WO01076739A1

    公开(公告)日：2001-10-18

    申请号：PCT/EP2001/003843

    申请日：2001-04-04

    IPC: B01J23/85 ,  B01J23/88 ,  B01J27/188 ,  B01J31/02 ,  B01J31/04 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    CPC classification number: B01J31/04 ,  B01J23/85 ,  B01J23/88 ,  B01J27/188 ,  B01J31/0217 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    Abstract: The present invention pertains to a process for sulphiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an S-containing organic additive wherein the catalyst composition is contacted with hydrogen and a sulphur-containing compound in the gaseous phase, characterised in that the process is carried out ex situ . By carrying out the process ex situ , the formation of undesirable side compounds in the hydrotreating unit is prevented. Additionally, the reactor suffers less downtime, and the start-up of the reactor may be simplified. The S-containing organic additive preferably is a mercapto-compound, more preferably a mercaptocarboxylic acid represented by the general formula HS-R1-COOR, wherein R1 stands for a divalent hydrocarbon group with 1-10 carbon atoms and R stands for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched alkyl group having 1 to 10 carbon atoms.

    Abstract translation: 本发明涉及一种用于硫化催化剂组合物的方法，所述催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族的氢化金属组分和含S的有机添加剂，其中催化剂组合物与氢和硫接触 在气相中的化合物，其特征在于该方法以非原位进行。 通过进行非原位处理，可以防止在加氢处理装置中形成不希望的侧面化合物。 此外，反应器的停机时间较短，反应器的起动可以简化。 含S的有机添加剂优选为巯基化合物，更优选由通式HS-R1-COOR表示的巯基羧酸，其中R1表示具有1-10个碳原子的二价烃基，R表示氢原子 碱金属，碱土金属，铵或具有1-10个碳原子的直链或支链烷基。

    HETEROPOLY ACID CATALYSTS SUPPORTED ON SILICA WITH LOW ALKALI METAL CONTENT
    88.
    发明申请
    HETEROPOLY ACID CATALYSTS SUPPORTED ON SILICA WITH LOW ALKALI METAL CONTENT 审中-公开
    支持低碱金属含量的二氧化硅的异戊酸催化剂

    公开(公告)号：WO00045952A1

    公开(公告)日：2000-08-10

    申请号：PCT/GB1999/004322

    申请日：1999-12-17

    IPC: B01J21/08 ,  B01J27/188 ,  B01J37/02 ,  C07C29/04 ,  C07C67/04

    CPC classification number: C07C29/04 ,  B01J21/08 ,  B01J27/188 ,  B01J37/0207 ,  C07C67/04 ,  C07C69/14 ,  C07C31/08 ,  C07C31/10

    Abstract: This invention relates to a catalyst composition comprising a heteropoly acid or a partial acid salt thereof on a silica support, characterised in that the alkali metal content of the silica support is no more than 150 ppm. The alkali metal content of the silica can be reduced by pretreating the support by acid washing. The catalyst can be used in olefin hydration and the preparation of esters from reaction of olefins and carboxylic acids.

    Abstract translation: 本发明涉及在二氧化硅载体上含有杂多酸或其部分酸盐的催化剂组合物，其特征在于二氧化硅载体的碱金属含量不超过150ppm。 二氧化硅的碱金属含量可以通过用酸洗来预处理载体来降低。 该催化剂可用于烯烃水合和烯烃与羧酸反应制备酯。

    OXIDATION CATALYSTS
    90.
    发明申请
    OXIDATION CATALYSTS 审中-公开
    氧化催化剂

    公开(公告)号：WO1997044129A1

    公开(公告)日：1997-11-27

    申请号：PCT/GB1997001305

    申请日：1997-05-14

    Applicant: SOLVAY INTEROX LIMITED ,  JOHNSTONE, Robert, Alexander, Walker ,  DE JESUS DA COSTA PIRES, Preciosa

    Inventor： SOLVAY INTEROX LIMITED

    IPC: B01J23/00

    CPC classification number: B01J23/007 ,  B01J27/16 ,  B01J27/18 ,  B01J27/1813 ,  B01J27/188 ,  C07D301/12

    Abstract: Heterogeneous catalysts of mixed-metal compounds of oxygenated acids, the metal comprising Ce, the vanadyl group, and groups (4 and 14) of the periodic table of the elements and the oxygenated acids being selected from acids of groups (6 and 15) and the vanadyl group. Said catalysts may include free acid -OH groups, or groups wherein the H atom is replaced by organic groups conferring to the catalysts a pillared structure. Said catalysts may be crystalline, amorphous or pellicular. Method of preparation of the catalysts is whereby the halide or oxyhalide of one or more metals from Ce, the vanadyl group, and groups (4 and 14) is brought together in a solution with a sodium salt of the oxyanion of one or more elements of groups (6 and 15), until a gel (G) or precipitate (P) has completely formed. The gel or precipitate is then separated, washed and dried to give an amorphous catalyst. Alternatively, the gel may be further treated by refluxing in an acid solution to obtain the crystalline form of the catalyst. Also described is a process for the oxidation of an olefin into an epoxide or diol, or a ketone to an ester or a lactone by reaction with hydrogen peroxide in the presence of one of the above-mentioned catalysts.

    Abstract translation: 含氧化酸的混合金属化合物的非均相催化剂，包含Ce的金属，氧钒基和元素周期表的基团（4和14）和氧化的酸选自基团（6和15）的酸和 氧钒基。 所述催化剂可以包括游离酸-OH基团，或其中H原子被赋予催化剂的柱状结构的有机基团代替的基团。 所述催化剂可以是结晶的，无定形的或带状的。 催化剂的制备方法是将来自Ce，氧钒基和（4和14）基团的一种或多种金属的卤化物或卤氧化物与一种或多种元素的氧阴离子的钠盐 （6和15），直到凝胶（G）或沉淀（P）完全形成。 然后将凝胶或沉淀物分离，洗涤并干燥，得到无定形催化剂。 或者，可以通过在酸性溶液中回流进一步处理凝胶以获得催化剂的结晶形式。 还描述了通过在上述催化剂之一中与过氧化氢反应，将烯烃氧化成环氧化物或二醇或酮到酯或内酯的方法。

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