POLYOLEFIN COMPOSITION COMPRISING CROSSLINKABLE POLYOLEFIN WITH SILANE GROUPS, SILANOL CONDENSATION CATALYST AND SILICON CONTAINING COMPOUND

    公开(公告)号:WO2009071265A3

    公开(公告)日:2009-06-11

    申请号:PCT/EP2008/010203

    申请日:2008-12-02

    Inventor: CARLSSON, Roger

    Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), (ii) a silanol condensation catalyst (B), and (iii) a silicon containing compound (C) according to the formula (R 1 ) x [Si(R 2 ) y R 3 ) z ] m (I) wherein R 1 , which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms and at least one heteroatom; R 2 , which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R 3 , is -R 4 SiR 1 p R 2 q , wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R 4 is -(CH 2 ) r Y s (CH 2 ) t - where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -O-(CO)-, -NH-, -NH 2 , -NH-(CO)-NH 2 , -NH-(CO)-OCH 3 , an epoxy group, a carbamate group, -S-, -SO-, -SO 2 -, -NR-, -PR-, where R is a hydrocarbon or a hydrogen and where R 1 and R 2 are as previously defined; and x is 0 to 3, y is 1 to 4, z is 0 or 1, with the proviso that x + y + z = 4; and m = 1 or 2; to an article, in particular a wire or cable, comprising such a composition, and to the use of such a composition for the production of an article. The present invention further relates to the use of silicon containing compound (C) according to the formula (I) given above as a processing aid in the compounding of polyolefin compositions and as a surface smoothening agent in polyolefin compositions. Finally, the present invention relates to the use of a silicon containing compound (C) according to the formula (I) given above as a drying agent for polyolefin compositions, as a corrosion inhibitor in polyolefin compositions comprising a Brönsted acid and as a pH controlling agent in polymer compositions comprising a Brönsted acid.

    POLYOLEFIN COMPOSITION COMPRISING CROSSLINKABLE POLYOLEFIN WITH SILANE GROUPS, SILANOL CONDENSATION CATALYST AND SILICON CONTAINING COMPOUND
    2.
    发明申请
    POLYOLEFIN COMPOSITION COMPRISING CROSSLINKABLE POLYOLEFIN WITH SILANE GROUPS, SILANOL CONDENSATION CATALYST AND SILICON CONTAINING COMPOUND 审中-公开
    包含可交联聚烯烃与硅烷基聚硅氧烷聚合催化剂和含硅化合物的聚烯烃组合物

    公开(公告)号:WO2007137757A1

    公开(公告)日:2007-12-06

    申请号:PCT/EP2007/004591

    申请日:2007-05-23

    Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefln with hydrolysable silane groups (A), (ii) a Bronsted acid (B) as a silanol condensation catalyst, and (iii) a silicon containing compound (C) according to the formula (I): (R 1 ) x [Si(R 2 ) y (R 3 ) z ] m wherein R 1 , which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms; R 2 , which may be the same or different if more than one such group is present, is a hydro carbyloxy residue comprising from 1 to 100 carbon atoms; R 3 , is -R 4 SiR 1 p R 2 q , wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R 4 is -(CH 2 ) r Y s (CH 2 ) t - where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -S-, -SO-, -SO 2 -, -NH-, -NR 1 - or -PR 1 - where R 1 and R 2 are as previously defined; and x is O to 3, y is 1 to 4, z is O or 1, with the proviso that x + y + z = 4; and m = 1 or 2, to an article, in particular a wire or cable, comprising such a composition, and to the use of such a composition for the production of an article.

    Abstract translation: 本发明涉及一种组合物,其包含(i)具有可水解硅烷基团的可交联聚烯烃(A),(ii)作为硅烷醇缩合催化剂的布朗斯台德酸(B),以及(iii)含硅化合物(C) 式(I):(R 1)X x(Si(R 2))Y(R SUP) 其中R 1,其可以相同或不同,如果存在多于一个这样的基团,则其可以是相同或不同的 是单官能的,或者如果m = 2,是包含1至100个碳原子的双功能烃基残基; R 2是如果存在多于一个这样的基团,可以相同或不同,是含有1至100个碳原子的氢化碳氧基; R 3是R 4,SiR 1,R 2,R 3,

    A SILICON CONTAINING COMPOUND AS DRYING AGENT FOR POLYOLEFIN COMPOSITIONS
    4.
    发明申请
    A SILICON CONTAINING COMPOUND AS DRYING AGENT FOR POLYOLEFIN COMPOSITIONS 审中-公开
    一种含硅化合物作为聚烯烃组合物的干燥剂

    公开(公告)号:WO2007137758A1

    公开(公告)日:2007-12-06

    申请号:PCT/EP2007/004592

    申请日:2007-05-23

    CPC classification number: C08K5/42 C08K5/5419 C08L43/04 C08L23/08

    Abstract: The present invention relates to the use of a silicon containing compound as drying agent of a polyolefln composition comprising a crosslinkable polyolefin with hydrolysable silane groups, wherein the silicon containing compound has a structure according to the formula (R 1 ) X [Si(R 2 ) y (R 3 ) z ] m wherein R 1 , which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms; R 2 , which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R 3 , is -R 4 SiR 1 P R 2 q , wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R 4 is -(CH 2 ) r Y s (CH 2 ) t - where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -S-, -SO-, -SO 2 -, -NH-, -NR 1 - or -PR 1 -, where R 1 and R 2 are as previously defined; and x is 0 to 3, y is 1 to 4, z is 0 or 1, with the proviso that x + y + z = 4; and m = 1 or 2.

    Abstract translation: 本发明涉及含硅化合物作为聚烯烃组合物的干燥剂的用途,所述聚烯烃组合物包含具有可水解硅烷基团的可交联聚烯烃,其中含硅化合物具有下式的结构(R 1) ) X [硅(R 2 ý(R 3 ž] 其中R 1,其中如果存在多于一个这样的基团,其可以相同或不同,是单官能的,或者如果m = 2是双官能的, 包含1至100个碳原子的烃基残基; R 2,如果存在多于一个这样的基团,其可以相同或不同,是含有1至100个碳原子的烃氧基; R 3是R 4 SiR 1,R 2,R 3,R 3,

    A SILICON CONTAINING COMPOUND AS PROCESSING AID FOR POLYOLEFIN COMPOSITION
    5.
    发明申请
    A SILICON CONTAINING COMPOUND AS PROCESSING AID FOR POLYOLEFIN COMPOSITION 审中-公开
    一种含硅化合物作为聚烯烃组合物的加工助剂

    公开(公告)号:WO2007137756A1

    公开(公告)日:2007-12-06

    申请号:PCT/EP2007/004590

    申请日:2007-05-23

    Abstract: The present invention relates to the use of a silicon containing compound as processing aid in the compounding of polyolefin compositions, wherein the silicon containing compound has a structure according to the formula (I): (R 1 ) x [Si(R 2 ) y (R 3 ) z ] m wherein R 1 , which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms; R 2 , which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R 3 , is -R 4 SiR 1 p R 2 q , wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R 4 is -(CH 2 ) r Y s (CH 2 ) t - where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -S-, -SO-, -SO 2 -, -NH-, -NR 1 - or -PR 1 -, where R 1 and R 2 are as previously defined; and x is 0 to 3, y is 1 to 4, z is 0 or 1, with the proviso that x + y + z = 4; and m = 1 or 2, and to the use of such a compound in the production of an article, in particular a wire or cable, comprising such polyolefin compositions.

    Abstract translation: 本发明涉及含硅化合物在聚烯烃组合物配混中的加工助剂的用途,其中含硅化合物具有根据式(I)的结构:(R 1) SUB> X [硅(R 2 ý(R 3 ž] 其中R 1,如果存在多于一个这样的基团,其可以相同或不同,是单官能的,或者如果m = 2,是双官能的烃基残基 包含1至100个碳原子; R 2,如果存在多于一个这样的基团,其可以相同或不同,是含有1至100个碳原子的烃氧基; R 3是R 4,SiR 1,R 2,R 3,

    VEHICLE TELEMATICS SYSTEM
    6.
    发明申请
    VEHICLE TELEMATICS SYSTEM 审中-公开
    车辆电话系统

    公开(公告)号:WO2005107362A2

    公开(公告)日:2005-11-17

    申请号:PCT/IB2005002139

    申请日:2005-02-03

    CPC classification number: G08G1/20 G06F1/3203 G06F1/3228 G07C5/008

    Abstract: Disclosed is a system providing tracking and wireless communications for remote diagnostics of a vehicle which transmits data communicated over a vehicle system's CAN bus to a remote location, which is adapted to use data received from a vehicle in order to compare the performance of the vehicle and/or of the operator of the vehicle with the performance of other vehicles and/or operators of other vehicles, which incorporates advanced power management functionality for conserving power, particularly when the system is disconnected from a main power supply, and which facilitates the identification of vehicles that have not reported back to the system or that have not moved within a specified time period.

    Abstract translation: 公开了一种提供用于远程诊断车辆的跟踪和无线通信的系统,其将通过车辆系统的CAN总线传送的数据发送到远程位置,该远程位置适于使用从车辆接收的数据,以便比较车辆的性能和 具有其他车辆和/或其他车辆的操作者的车辆的操作者,其具有用于节省电力的先进的电源管理功能,特别是当系统与主电源断开连接时,便于识别 尚未报告回系统或未在指定时间内移动的车辆。

    A SILICON CONTAINING COMPOUND AS PROCESSING AID FOR POLYOLEFIN COMPOSITION
    8.
    发明申请
    A SILICON CONTAINING COMPOUND AS PROCESSING AID FOR POLYOLEFIN COMPOSITION 审中-公开
    一种含硅化合物作为聚烯烃组合物的加工助剂

    公开(公告)号:WO2007137756A8

    公开(公告)日:2009-03-05

    申请号:PCT/EP2007004590

    申请日:2007-05-23

    Abstract: The present invention relates to the use of a silicon containing compound as processing aid in the compounding of polyolefin compositions, wherein the silicon containing compound has a structure according to the formula (I): (R1)x[Si(R2)y(R3)z]m wherein R1, which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms; R2, which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R3, is -R4SiR1 pR2 q, wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R4 is -(CH2)rYs(CH2)t- where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -S-, -SO-, -SO2-, -NH-, -NR1- or -PR1-, where R1 and R2 are as previously defined; and x is 0 to 3, y is 1 to 4, z is 0 or 1, with the proviso that x + y + z = 4; and m = 1 or 2, and to the use of such a compound in the production of an article, in particular a wire or cable, comprising such polyolefin compositions.

    Abstract translation: 本发明涉及含硅化合物在聚烯烃组合物配混中的加工助剂的用途,其中含硅化合物具有根据式(I)的结构:(R1)x [Si(R2)y(R3 )z] m其中如果存在多于一个这样的基团,则可以相同或不同的R 1是单官能的,或者如果m = 2,则是包含1至100个碳原子的双官能的烃基; 如果存在多于一个这样的基团,其可以相同或不同,是含有1至100个碳原子的烃氧基; R3为-R4SiR1 pR2 q,其中p为0至3,q为0至3,条件是p + q为3,R4为 - (CH2)rYs(CH2)t-,其中r和t独立地为 1至3,s为0或1,Y为选自-O - , - S - , - SO - , - SO 2 - , - NH - , - NR 1 - 或-PR 1 - 的双官能杂原子基团,其中R 1和R 2 如前所述; x为0至3,y为1至4,z为0或1,条件是x + y + z = 4; 和m = 1或2,以及在制备包含这种聚烯烃组合物的制品,特别是电线或电缆的情况下使用这种化合物。

    CROSSLINKABLE POLYOLEFIN COMPOSITION COMPRISING SILANE GROUPS FORMING AN ACID OR A BASE UPON HYDROLYSATION
    10.
    发明申请
    CROSSLINKABLE POLYOLEFIN COMPOSITION COMPRISING SILANE GROUPS FORMING AN ACID OR A BASE UPON HYDROLYSATION 审中-公开
    可交联的聚烯烃组合物,包含形成酸或基于水解的硅烷基团

    公开(公告)号:WO2010130458A1

    公开(公告)日:2010-11-18

    申请号:PCT/EP2010/002972

    申请日:2010-05-14

    Abstract: The present invention relates to a polyolefin composition comprising (A) a crosslinkable polyolefin with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90°C cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR 2 = 2 g/10min, a density of 923 g/cm 3 , and 2 wt.% of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90°C, and to a polyolefin composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups, and (ii) a non-polymeric compound with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90°C cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR 2 = 2 g/10min, a density of 923 g/cm 3 , and 2 wt.% of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90°C.

    Abstract translation: 本发明涉及一种聚烯烃组合物,其包含(A)具有可水解硅烷基团的可交联聚烯烃,其在水解形成酸或碱时,​​其特征在于所述酸或碱在40小时后产生至少40%的凝胶含量 90℃交联试验,其中将酸或碱以4.5mmol / kg的量加入到MFR 2 = 2g / 10min,密度为923g / cm 3和2wt。%的乙烯/乙烯基三甲氧基硅烷共聚物中。 %的乙烯基三甲氧基硅烷,然后在90℃的水浴中交联,以及包含(i)具有可水解硅烷基团的可交联聚烯烃的聚烯烃组合物,和(ii)在水解时可水解硅烷基团的非聚合化合物 形成酸或碱,其特征在于酸或碱在90℃交联试验中40小时后产生至少40%的凝胶含量,其中酸或碱的加入量为4.5mmol / kg至乙烯/乙烯基三甲氧基硅烷 共聚物,MFR 2 = 2g / 10min,密度为923g / cm 3,和2重量%的乙烯基三甲氧基硅烷,然后在90℃的水浴中交联。

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