Abstract:
The invention relates to a crosslinkable polymer composition comprising (a) a polyolefin bearing hydrolysable silane groups and a silanol condensation catalyst compound, as well as to an article, preferably a cable, thereof. Also the use of the silanol condensation catalyst compound for crosslinking an article, preferably a layer of a cable is provided.
Abstract:
The present invention relates to the use of a silicon containing compound as processing aid in the compounding of polyolefin compositions, wherein the silicon containing compound has a structure according to the formula (I): (R1)x[Si(R2)y(R3)z]m wherein R1, which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms; R2, which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R3, is -R4SiR1 pR2 q, wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R4 is -(CH2)rYs(CH2)t- where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -S-, -SO-, -SO2-, -NH-, -NR1- or -PR1-, where R1 and R2 are as previously defined; and x is 0 to 3, y is 1 to 4, z is 0 or 1, with the proviso that x + y + z = 4; and m = 1 or 2, and to the use of such a compound in the production of an article, in particular a wire or cable, comprising such polyolefin compositions.
Abstract translation:本发明涉及含硅化合物在聚烯烃组合物配混中的加工助剂的用途,其中含硅化合物具有根据式(I)的结构:(R1)x [Si(R2)y(R3 )z] m其中如果存在多于一个这样的基团,则可以相同或不同的R 1是单官能的,或者如果m = 2,则是包含1至100个碳原子的双官能的烃基; 如果存在多于一个这样的基团,其可以相同或不同,是含有1至100个碳原子的烃氧基; R3为-R4SiR1 pR2 q,其中p为0至3,q为0至3,条件是p + q为3,R4为 - (CH2)rYs(CH2)t-,其中r和t独立地为 1至3,s为0或1,Y为选自-O - , - S - , - SO - , - SO 2 - , - NH - , - NR 1 - 或-PR 1 - 的双官能杂原子基团,其中R 1和R 2 如前所述; x为0至3,y为1至4,z为0或1,条件是x + y + z = 4; 和m = 1或2,以及在制备包含这种聚烯烃组合物的制品,特别是电线或电缆的情况下使用这种化合物。
Abstract:
The present invention relates to a coaxial cable comprising a dielectric layer which comprises as a component (A) a propylene homo- or copolymer having strain hardening behaviour and to the use of propylene homo- or copolymer having strain hardening behaviour for the production of a dielectric layer of a coaxial or triaxial cable.
Abstract:
The present invention relates to a composition for cross-linking and stabilization of a polymer containing hydrolysable silane groups comprising a sulphonic acid as a silanol condensation catalyst characterized in that it comprises a stabilizer which is neutral or acidic, does not contain ester groups and is a compound according to formula (I): wherein R is an unsubstituted or substituted aliphatic or aromatic hydrocarbyl radical which may comprise heteroatoms, R' is a hydrocarbyl radical, R" is a hydrocarbyl radical and R' and/or R" being a bulky radical, X1, X2 or X3 is the same or different H or OH, whereby at least X1, X2 or X3 is OH, and n is 1 to 4; or a compound according to formula (II): wherein R"' is an aliphatic hydrocarbyl radical and p is 1 to 6; or a mixture of any of such compounds, to a stabilized polymer comprising the above stabilizers and to a process for cross-linking and stabilization of silane group containing polymers in the presence of the above mentioned stabilizers.
Abstract:
The present invention relates to a composition for cross-linking and stabilization of a polymer containing hydrolysable silane groups comprising a sulphonic acid as a silanol condensation catalyst characterized in that it comprises a stabilizer which is neutral or acidic, does not contain ester groups and is a compound according to formula (I): wherein R is an unsubstituted or substituted aliphatic or aromatic hydrocarbyl radical which may comprise heteroatoms, R' is a hydrocarbyl radical, R" is a hydrocarbyl radical and R' and/or R" being a bulky radical, X 1 , X 2 or X 3 is the same or different H or OH, whereby at least X 1 , X 2 or X 3 is OH, and n is 1 to 4; or a compound according to formula (II): wherein R"' is an aliphatic hydrocarbyl radical and p is 1 to 6; or a mixture of any of such compounds, to a stabilized polymer comprising the above stabilizers and to a process for cross-linking and stabilization of silane group containing polymers in the presence of the above mentioned stabilizers.
Abstract:
The invention relates to an article, preferably a cable, comprising a conductor surrounded by at least one crosslinkable layer comprising a polymer composition which comprises (a) a polyolefin bearing hydrolysable silane groups and a silanol condensation catalyst compound, as well as to a production process of such article which is preferably a cable.
Abstract:
The invention relates to silane-functionalised polyolefin compositions, to silane- crosslinkable polyolefin compositions and to silane-crosslinked polyolefin compositions, to a preparation process thereof, to their use for producing products and to the obtained products, to their use for W&C applications, preferably for producing one or more layers of a cable comprising said silane-functionalised polyolefin composition, as well as to silane-crosslinked cables comprising polyolefin compositions.
Abstract:
The present invention relates to a semiconductive polyolefin composition comprising: (i) up to 80 wt.% of a polyolefin (I), (ii) carbon black, and (iii) optionally up to 60 wt.% of a polymer (II) having a melting point of not less than 100 °C, wherein the polyolefin (I) has a co-monomer content of equal to or less than 4.3 mol%, to the use of that composition for the production of a power cable and to a power cable comprising that composition.
Abstract:
The present invention relates to a composition comprising (i) a crosslinkable polyolefln with hydrolysable silane groups (A), (ii) a Bronsted acid (B) as a silanol condensation catalyst, and (iii) a silicon containing compound (C) according to the formula (I): (R 1 ) x [Si(R 2 ) y (R 3 ) z ] m wherein R 1 , which may be the same or different if more than one such group is present, is a monofunctional, or, if m = 2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms; R 2 , which may be the same or different if more than one such group is present, is a hydro carbyloxy residue comprising from 1 to 100 carbon atoms; R 3 , is -R 4 SiR 1 p R 2 q , wherein p is 0 to 3, q is 0 to 3, with the proviso that p + q is 3, and R 4 is -(CH 2 ) r Y s (CH 2 ) t - where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from -O-, -S-, -SO-, -SO 2 -, -NH-, -NR 1 - or -PR 1 - where R 1 and R 2 are as previously defined; and x is O to 3, y is 1 to 4, z is O or 1, with the proviso that x + y + z = 4; and m = 1 or 2, to an article, in particular a wire or cable, comprising such a composition, and to the use of such a composition for the production of an article.
Abstract translation:本发明涉及一种组合物,其包含(i)具有可水解硅烷基团的可交联聚烯烃(A),(ii)作为硅烷醇缩合催化剂的布朗斯台德酸(B),以及(iii)含硅化合物(C) 式(I):(R 1)X x(Si(R 2))Y(R SUP) 其中R 1,其可以相同或不同,如果存在多于一个这样的基团,则其可以是相同或不同的 是单官能的,或者如果m = 2,是包含1至100个碳原子的双功能烃基残基; R 2是如果存在多于一个这样的基团,可以相同或不同,是含有1至100个碳原子的氢化碳氧基; R 3是R 4,SiR 1,R 2,R 3,
Abstract:
The invention relates to a cable comprising a conductor surrounded by at least one crosslinkable layer comprising a polymer composition which comprises (a) a polyolefin bearing hydrolysable silane groups and a silanol condensation catalyst compound, as well as to a production process of such cable.