公开(公告)号：WO2005051880A3

公开(公告)日：2005-07-21

申请号：PCT/US2004038869

申请日：2004-11-19

Applicant: HONEYWELL INT INC ,  BELL ROBERT L ,  NALEWAJEK DAVID ,  BRADLEY DAVID E ,  DEMMIN TIMOTHY R

Inventor： BELL ROBERT L ,  NALEWAJEK DAVID ,  BRADLEY DAVID E ,  DEMMIN TIMOTHY R

IPC: C07C51/21 ,  C07C51/58 ,  C07C53/40

CPC classification number: C07C51/58 ,  C07C53/48

Abstract: The invention pertains to a process for preparing chlorodifluoroacetyl fluoride (CDAF) by oxidation of chlorotrifluoroethylene (CTFE) in a solvent using a continuously stirred tank reactor. It provides a process for the production of chlorodifluoroacetyl fluoride by comprises reacting a solvent solution of chlorotrifluoroethylene with oxygen in a reactor to form a product which comprises chlorodifluoroacetyl fluoride. The reacting may be conducted in a continuous or batch mode.

Abstract translation: 本发明涉及通过使用连续搅拌釜式反应器在溶剂中氧化三氟氯乙烯（CTFE）来制备氯二氟乙酰氟（CDAF）的方法。 它提供了一种生产氯二氟乙酰氟的方法，包括在反应器中使氯三氟乙烯的溶剂溶液与氧反应形成包含氯二氟乙酰氟的产物。 反应可以以连续或间歇的方式进行。

公开(公告)号：WO2005051880A2

公开(公告)日：2005-06-09

申请号：PCT/US2004/038869

申请日：2004-11-19

Applicant: HONEYWELL INTERNATIONAL, INC. ,  BELL, Robert, L. ,  NALEWAJEK, David ,  BRADLEY, David, E. ,  DEMMIN, Timothy, R.

Inventor： BELL, Robert, L. ,  NALEWAJEK, David ,  BRADLEY, David, E. ,  DEMMIN, Timothy, R.

IPC: C07C51/00

CPC classification number: C07C51/58 ,  C07C53/48

Abstract: The invention pertains to a process for preparing chlorodifluoroacetyl fluoride (CDAF) by oxidation of chlorotrifluoroethylene (CTFE) in a solvent using a continuously stirred tank reactor. It provides a process for the production of chlorodifluoroacetyl fluoride by comprises reacting a solvent solution of chlorotrifluoroethylene with oxygen in a reactor to form a product which comprises chlorodifluoroacetyl fluoride. The reacting may be conducted in a continuous or batch mode.

Abstract translation: 本发明涉及一种通过使用连续搅拌罐式反应器在溶剂中氧化三氟氯乙烯（CTFE）来制备氯二氟乙酰氟（CDAF）的方法。 它提供了一种生产氯二氟乙酰氟的方法，包括使三氟氯乙烯的溶剂溶液与氧在反应器中反应，形成包含氯二氟乙酰氟的产物。 反应可以以连续或分批模式进行。

公开(公告)号：WO02053518A3

公开(公告)日：2003-09-12

申请号：PCT/US0149924

申请日：2001-12-31

Applicant: HONEYWELL INT INC ,  DEMMIN TIMOTHY R ,  POSS ANDREW JOSEPH ,  BELL ROBERT LOUIS ,  MALEC RONALD THEODOR

Inventor： DEMMIN TIMOTHY R ,  POSS ANDREW JOSEPH ,  BELL ROBERT LOUIS ,  MALEC RONALD THEODOR

IPC: C07C45/51 ,  C07C47/14 ,  C07C47/24 ,  C07C227/08 ,  C07C229/30 ,  C07C253/14 ,  C07C255/23 ,  C07C303/02 ,  C07C309/08 ,  C07D231/12 ,  C07D317/16 ,  A01N37/06 ,  C07C69/76

CPC classification number: C07D231/12 ,  C07C45/515 ,  C07C47/14 ,  C07C47/24 ,  C07C227/08 ,  C07C253/14 ,  C07C303/02 ,  C07C309/08 ,  C07D317/16 ,  C07C229/30 ,  C07C255/23

Abstract: A process for preparing a halogenated aliphatic- alpha , beta -unsaturated- beta -nucleophile-functionalized carboxylate ester having the formula: R -C(-Nu)=CH-COOR by reacting a nucleophile with a halogenated aliphatic- alpha , beta -unsaturated- beta halocarboxylate ester having the formula: R -CX =CH-COOR , wherein R is selected from the group consisting of straight chain and branched halogenated C1-C12 aliphatic groups; Nu is a nucleophile moiety different from X ; X is F, Cl or Br; and R is selected from the group consisting of straight chain and branched C1-C6 alkyl groups. Halogenated aliphatic- alpha , beta -unsaturated- beta -nucleophile-functionalized carboxylate esters, halogenated aliphatic- alpha , beta -unsaturated- beta -halocarboxylate esters, and intermediate compounds and processes in the preparation thereof are also disclosed.

Abstract translation: 通过将亲核试剂与卤代脂族醇反应制备具有下式的卤代脂族-α，β-不饱和的β-亲核试剂官能化羧酸酯的方法：R 1 -C（-Nu）= CH-COOR 8 α，β-不饱和-β卤代羧酸酯，其具有下式：R 1 -CX 1 = CH-COOR 8，其中R 1选自直链和支链卤代C1- C12脂族基团; Nu是不同于X 1的亲核部分; X 1是F，Cl或Br; 并且R 8选自直链和支链C 1 -C 6烷基。 还公开了卤化脂族-α，β-不饱和-β-亲核试剂官能化的羧酸酯，卤代脂族-α，β-不饱和-β-卤代羧酸酯以及其制备中的中间体化合物和方法。

公开(公告)号：WO2005049535A1

公开(公告)日：2005-06-02

申请号：PCT/US2004/037501

申请日：2004-11-09

Applicant: HONEYWELL INTERNATIONAL INC. ,  STUCK, Jason, T. ,  LULY, Matthew, H. ,  POSS, Andrew, J. ,  WONG, Franklin, S. ,  DEMMIN, Timothy, R. ,  VAN DER PUY, Michael ,  TUNG, Hsueh Sung

Inventor： STUCK, Jason, T. ,  LULY, Matthew, H. ,  POSS, Andrew, J. ,  WONG, Franklin, S. ,  DEMMIN, Timothy, R. ,  VAN DER PUY, Michael ,  TUNG, Hsueh Sung

IPC: C07C17/38

CPC classification number: C07B39/00 ,  Y02P20/582

Abstract: Disclosed are improved fluorination processes and fluorine-containing compositions which involve introducing to one or more fluorination process compositions a water reactive agent in an amount and under conditions effective to decrease the amount of water in that composition. The water reactive agent is preferably introduced to the fluorination reaction process at a location proximate to the site of the fluorination reaction, or upstream of the fluorination reaction, in amounts and under conditions effective to produce a relatively lower concentration of water in the composition, and preferably throughout the fluorination process.

Abstract translation: 公开了改进的氟化方法和含氟组合物，其涉及在有效降低该组合物中的水量的量和条件下向一种或多种氟化方法组合物引入水反应剂。 水反应剂优选在有效产生组合物中相对较低浓度的水的量和在有效产生组合物中较低浓度的水的条件下，在氟化反应的位置或氟化反应的上游附近的位置处引入氟化反应过程，以及 优选在整个氟化过程中。