公开(公告)号：WO2016189333A1

公开(公告)日：2016-12-01

申请号：PCT/GB2016/051566

申请日：2016-05-27

Applicant: THE QUEEN'S UNIVERSITY OF BELFAST ,  GOODRICH, Peter ,  O'HARA, Eoghain ,  ATKINS, Martin Philip ,  HAMER, Christopher Klatt

Inventor： GOODRICH, Peter ,  O'HARA, Eoghain ,  ATKINS, Martin Philip ,  HAMER, Christopher Klatt

IPC: C11B3/06 ,  C11B3/10

CPC classification number: C11B3/06 ,  C11B3/10

Abstract: The present invention relates to an improved process for refining glyceride oil which incorporates a basic ionic liquid treatment. In particular, the basic ionic liquid treatment prevents or reduces the formation of chloropropanol fatty acid esters and glycidyl fatty acid esters during the overall refining process. The present invention also relates to glyceride oil compositions formed therefrom and uses of the basic ionic liquid.

Abstract translation: 本发明涉及一种改进含有碱性离子液体处理的甘油酯油的精制方法。 特别地，碱性离子液体处理在整个精制过程中防止或减少氯丙醇脂肪酸酯和缩水甘油基脂肪酸酯的形成。 本发明还涉及由其形成的甘油酯油组合物和碱性离子液体的用途。

公开(公告)号：WO2016189114A1

公开(公告)日：2016-12-01

申请号：PCT/EP2016/061964

申请日：2016-05-27

Applicant: EVONIK DEGUSSA GMBH ,  FEDOR, Gabriela ,  ATKINS, Martin Philip ,  GOODRICH, Peter ,  KLATT HAMER, Christopher ,  WITTHAUT, Daniel ,  BOES, Ulrich

Inventor： FEDOR, Gabriela ,  ATKINS, Martin Philip ,  GOODRICH, Peter ,  KLATT HAMER, Christopher ,  WITTHAUT, Daniel ,  BOES, Ulrich

IPC: C11B3/00 ,  C11B3/04 ,  C11B3/10 ,  C11B3/12

CPC classification number: C11B3/06 ,  C11B3/001 ,  C11B3/04 ,  C11B3/10 ,  C11B3/12 ,  C11B3/14

Abstract: The present invention relates to a process for refining glyceride oil comprising the steps of: (i) contacting glyceride oil with a liquid comprising a basic quaternary ammonium salt to form a treated glyceride oil; wherein the quaternary ammonium salt comprises a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a quaternary ammonium cation; (ii) separating the treated glyceride oil from a salt comprising the quaternary ammoniumcation; and (iii) subjecting the treated glyceride oil after the separation step to at least one further refining step; and to the use of contacting a glyceride oil with the basic quaternary ammonium salt for preventing or reducing the formation of fatty acid esters of chloropropanols and/or glycidol upon heating of the glyceride oil.

Abstract translation: 本发明涉及一种精制甘油酯油的方法，包括以下步骤：（i）使甘油酯油与包含碱性季铵盐的液体接触以形成经处理的甘油酯油; 其中季铵盐包括选自氢氧化物，醇盐，烷基碳酸盐，碳酸氢盐，碳酸盐，丝氨酸盐，脯氨酸盐，组氨酸盐，苏氨酸盐，缬氨酸盐，天冬酰胺酸盐，牛磺酸盐和赖氨酸盐的碱性阴离子; 和季铵阳离子; （ii）从包含季铵阳离子的盐分离经处理的甘油酯油; 和（iii）在分离步骤之后对经处理的甘油酯油进行至少一个进一步的精制步骤; 以及使用甘油酯油与碱性季铵盐接触以防止或减少加热甘油酯油时氯丙醇和/或缩水甘油的脂肪酸酯的形成。

公开(公告)号：WO2015079262A1

公开(公告)日：2015-06-04

申请号：PCT/GB2014/053553

申请日：2014-11-28

Applicant: THE QUEEN'S UNIVERSITY OF BELFAST ,  ATKINS, Martin ,  COLEMAN, Fergal ,  GOODRICH, Peter

Inventor： ATKINS, Martin ,  COLEMAN, Fergal ,  GOODRICH, Peter

IPC: C11B3/02 ,  C11B3/06

CPC classification number: C11B3/06 ,  A23D9/007 ,  A23L5/27 ,  A23V2002/00 ,  C11B3/02 ,  C11C3/003

Abstract: The present invention relates to deacidification of glyceride oils. The present invention provides a process for removing free fatty acids from glyceride oil, preferably palm oil, containing free fatty acids, said process comprising the steps of: (i) contacting the glyceride oil containing free fatty acids with the basic ionic liquid; wherein the basic ionic liquid has a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a cation selected from: [N(R a )(R b )(R c )(R d )] + , wherein: R a , R b , R c and R d are each independently selected from hydrogen, a C 1 to C 8 , straight chain or branched alkyl group or a C 3 to C 6 cycloalkyl group, wherein said alkyl or cycloalkyl groups are unsubstituted or may be substituted by one to three groups selected from: C 1 to C 4 alkoxy, C 2 to C 8 alkoxyalkoxy, C 3 to C 6 cycloalkyl, -OH, -SH, - CO 2 (C 1 to C 6 )alkyl, -OC(O)(C 1 to C 6 )alkyl, or any two of R a , R b , R c and R d combine to form an alkylene chain -(CH 2 ) q - wherein q is from 3 to 6; and (ii) obtaining a treated glyceride oil having a reduced content of free fatty acid compared to the glyceride oil feed of step (i).

Abstract translation: 本发明涉及甘油酯油的脱酸。 本发明提供了一种从含有游离脂肪酸的甘油酯油，优选棕榈油中除去游离脂肪酸的方法，所述方法包括以下步骤：（i）使含有游离脂肪酸的甘油酯油与碱性离子液体接触; 其中所述碱性离子液体具有选自氢氧化物，醇盐，烷基碳酸盐，碳酸氢盐，丝氨酸盐，脯氨酸盐，组氨酸盐，苏氨酸盐，缬氨酸盐，天冬酰胺酸盐，牛磺酸盐和赖氨酸盐的碱性阴离子; 和选自：[N（Ra）（Rb）（Rc）（Rd）] +的阳离子，其中：Ra，Rb，Rc和Rd各自独立地选自氢，C1至C8，直链或支链烷基 或C 3至C 6环烷基，其中所述烷基或环烷基是未取代的或可被一至三个选自以下的基团取代：C 1至C 4烷氧基，C 2至C 8烷氧基烷氧基，C 3至C 6环烷基，-OH，-SH， CO 2（C 1至C 6）烷基，-OC（O）（C 1至C 6）烷基或R a，R b，R c和R d中的任何两个结合形成亚烷基链 - （CH 2）q-，其中q为3至6 ; 和（ii）与步骤（i）的甘油酯油进料相比，获得游离脂肪酸含量降低的经处理的甘油酯油。

公开(公告)号：WO2012069832A3

公开(公告)日：2012-11-01

申请号：PCT/GB2011052304

申请日：2011-11-23

Applicant: UNIV BELFAST ,  HARDACRE CHRISTOPHER ,  GOODRICH PETER ,  HUSSAIN AZLAN ,  ROONEY DAVID

Inventor： HARDACRE CHRISTOPHER ,  GOODRICH PETER ,  HUSSAIN AZLAN ,  ROONEY DAVID

IPC: C10G21/16 ,  C10G21/27 ,  C10G21/28

CPC classification number: C10G21/16 ,  C07C51/48 ,  C07C211/63 ,  C10G19/02 ,  C10G21/27 ,  C10G21/28 ,  C10G2300/1033 ,  C10G2300/104 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/203 ,  Y02P20/582 ,  C07C63/36

Abstract: The present invention relates to a process for the removal of naphthenic acids from crude oils and crude oil distillates by use of supported basic ionic liquids.

Abstract translation: 本发明涉及一种通过使用负载的碱性离子液体从原油和原油馏出物中除去环烷酸的方法。

公开(公告)号：WO02094740A3

公开(公告)日：2003-03-13

申请号：PCT/GB0202333

申请日：2002-05-17

Applicant: UNIV BELFAST ,  ANDERSON KRIS ,  GOODRICH PETER ,  HARDACRE CHRISTOPHER ,  MCMATH SARAH ELIZABETH JANE

Inventor： ANDERSON KRIS ,  GOODRICH PETER ,  HARDACRE CHRISTOPHER ,  MCMATH SARAH ELIZABETH JANE

IPC: C07B35/02 ,  C07B41/02 ,  C07B61/00 ,  C07C5/08 ,  C07C15/46 ,  C07C29/141 ,  C07C29/17 ,  C07C33/32 ,  C07C45/62 ,  C07C47/21 ,  C07C67/303 ,  C07D473/00

CPC classification number: C07D473/00 ,  C07B35/02 ,  C07B41/02 ,  C07C5/08 ,  C07C29/141 ,  C07C29/17 ,  C07C29/175 ,  C07C45/62 ,  C07C67/303 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/18 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2527/053 ,  C07C2527/232 ,  C07C2601/16 ,  C07C49/213 ,  C07C47/32 ,  C07C47/228 ,  C07C49/203 ,  C07C69/24 ,  C07C33/32 ,  C07C33/20 ,  C07C31/125 ,  C07C31/10 ,  C07C33/14 ,  C07C33/38 ,  C07C33/02 ,  C07C33/025

Abstract: Disclosed are heterogeneous processes (i) for the hydrogenation of a compound containing at least one unsaturated carbon-carbon bond, and (ii) for the hydro-dehalogenation of a compound containing at least one C-Cl, C-Br or C-l bond. The processes comprise reacting said compound with a hydrogenating agent and a heterogeneous hydrogenation catalyst in the presence of an ionic liquid.

Abstract translation: 公开了用于氢化含有至少一个不饱和碳 - 碳键的化合物的非均相方法（i）和（ii）含有至少一个C-Cl，C-Br或C-l键的化合物的氢化脱卤。 所述方法包括在离子液体存在下使所述化合物与氢化剂和多相氢化催化剂反应。

公开(公告)号：WO2016189332A3

公开(公告)日：2017-03-02

申请号：PCT/GB2016051565

申请日：2016-05-27

Applicant: THE QUEEN'S UNIV OF BELFAST ,  GOODRICH PETER ,  O'HARA EOGHAIN ,  ATKINS MARTIN PHILIP

Inventor： GOODRICH PETER ,  O'HARA EOGHAIN ,  ATKINS MARTIN PHILIP

IPC: C11B3/06

CPC classification number: C11B3/06 ,  A23D9/04 ,  C11B3/10

Abstract: The present invention relates to a process for the removal of free fatty acids from glyceride oils, especially palm oil. In particular, the present invention is directed to a process wherein specific ionic liquids are utilised for removing free fatty acids contained in glyceride oils,preferably palm oil,such that a glyceride oil, having a reduced content of free fatty acids may be obtained. The invention also relates to treated glyceride oil compositions, preferably treated palm oil compositions, comprising certainionic liquids to prevent build-up of free fatty acids in stored oil.

Abstract translation: 本发明涉及从甘油酯油，特别是棕榈油中除去游离脂肪酸的方法。 特别地，本发明涉及一种方法，其中特定的离子液体用于除去甘油酯油，优选棕榈油中所含的游离脂肪酸，使得可以获得具有降低的游离脂肪酸含量的甘油酯油。 本发明还涉及经处理的甘油酯油组合物，优选处理的棕榈油组合物，其包含某些阴离子液体，以防止游离脂肪酸在储存的油中积累。

公开(公告)号：WO2016189330A1

公开(公告)日：2016-12-01

申请号：PCT/GB2016/051562

申请日：2016-05-27

Applicant: THE QUEEN'S UNIVERSITY OF BELFAST ,  GOODRICH, Peter ,  O'HARA, Eoghain ,  ATKINS, Martin Philip ,  HAMER, Christopher Klatt

Inventor： GOODRICH, Peter ,  O'HARA, Eoghain ,  ATKINS, Martin Philip ,  HAMER, Christopher Klatt

IPC: C11B3/06 ,  C11B3/10

CPC classification number: C11B3/06 ,  C11B3/10

Abstract: The present invention is directed to a process for removing metal contaminants from glyceride oil and a refining process incorporating the same. In particular, the present invention is directed to a process wherein certain basic ionic liquids are used for treating glyceride oil. The present invention also relates to uses of the basic ionic liquid and to glyceride oil compositions obtained from the ionic liquid treatment.

Abstract translation: 本发明涉及一种从甘油酯油中除去金属污染物的方法和包含该方法的精制方法。 特别地，本发明涉及某些碱性离子液体用于处理甘油酯油的方法。 本发明还涉及由离子液体处理获得的碱性离子液体和甘油酯油组合物的用途。

公开(公告)号：WO2013076509A1

公开(公告)日：2013-05-30

申请号：PCT/GB2012/052913

申请日：2012-11-23

Applicant: PETROLIAM NASIONAL BERHAD (PETRONAS) ,  ANDERSON, Kris ,  GOODRICH, Peter ,  HARDACRE, Christopher ,  HUSSAIN, Azlan ,  ROONEY, David

Inventor： ANDERSON, Kris ,  GOODRICH, Peter ,  HARDACRE, Christopher ,  HUSSAIN, Azlan ,  ROONEY, David

IPC: C10G75/02 ,  C10G21/27

CPC classification number: C10G75/02 ,  C10G7/10 ,  C10G21/27 ,  C10G2300/203

Abstract: The invention relates to a method of inhibiting corrosion by corrosive fluids, and more specifically to inhibiting corrosion of a metallic surface. The method comprising adding to the corrosive fluid a specifically selected ionic liquid which is added in an amount,based on the total weight of the corrosive fluid, effective to mitigate or alleviate corrosion.

Abstract translation: 本发明涉及一种抑制腐蚀性液体腐蚀的方法，更具体地涉及抑制金属表面的腐蚀。 该方法包括向腐蚀性流体中加入特定选择的离子液体，该离子液体以基于腐蚀性流体总重量的量加入，有效减轻或减轻腐蚀。

公开(公告)号：WO2016189115A1

公开(公告)日：2016-12-01

申请号：PCT/EP2016/061965

申请日：2016-05-27

Applicant: EVONIK DEGUSSA GMBH ,  FEDOR, Gabriela ,  ATKINS, Martin Philip ,  GOODRICH, Peter ,  KLATT HAMER, Christopher ,  WITTHAUT, Daniel ,  BOES, Ulrich

Inventor： FEDOR, Gabriela ,  ATKINS, Martin Philip ,  GOODRICH, Peter ,  KLATT HAMER, Christopher ,  WITTHAUT, Daniel ,  BOES, Ulrich

IPC: C11B3/06 ,  C11B3/14 ,  C11B3/00 ,  C11B3/12 ,  C11B3/02

CPC classification number: C11B3/06 ,  C11B3/001 ,  C11B3/006 ,  C11B3/02 ,  C11B3/04 ,  C11B3/14

Abstract: The present invention relates to a process for removing metal from metal-containing glyceride oil comprising the steps of: (i) contacting a glyceride oil, comprising chromium, manganese, iron, cobalt, nickel and/or copper in a total amount of from 10 mg/kg to 10,000 mg/kg, with a liquid comprising a basic quaternary ammonium salt to form a treated glyceride oil; wherein the basic quaternary ammonium salt comprises a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and (ii) separating the treated glyceride oil from a salt comprising the quaternary ammonium cation, providing a treated glyceride oil containing a reduced amount of metals.

Abstract translation: 本发明涉及一种从含金属的甘油酯油中除去金属的方法，包括以下步骤：（i）将总量为10重量％的铬，锰，铁，钴，镍和/或铜的甘油酯油 mg / kg至10,000mg / kg，其中包含碱性季铵盐的液体以形成经处理的甘油酯油; 其中碱性季铵盐包括选自氢氧化物，醇盐，烷基碳酸盐，碳酸氢盐，碳酸盐，丝氨酸盐，脯氨酸盐，组氨酸盐，苏氨酸盐，缬氨酸盐，天冬酰胺酸盐，牛磺酸盐和赖氨酸盐的碱性阴离子; 和（ii）从包含季铵阳离子的盐分离经处理的甘油酯油，提供含有减少金属量的经处理的甘油酯油。

公开(公告)号：WO2010136783A1

公开(公告)日：2010-12-02

申请号：PCT/GB2010/050548

申请日：2010-03-30

Applicant: THE QUEEN'S UNIVERSITY OF BELFAST ,  HARDACRE, Chris ,  GOODRICH, Peter ,  ANDERSON, Kris

Inventor： HARDACRE, Chris ,  GOODRICH, Peter ,  ANDERSON, Kris

IPC: C10G21/27 ,  C10G25/00 ,  C07C211/00 ,  C07D233/00 ,  C10G21/28

CPC classification number: C10G21/27 ,  C10G21/28 ,  C10G25/003 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1062 ,  C10G2300/203 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/10 ,  Y02P20/582

Abstract: The present invention relates to a process for the removal of organic acids, particularly naphthenic acids, from crude oils and crude oil distillates by use of a supported basic ionic liquid in a mass ratio of crude oil and/or crude oil distillate and ionic liquid of from greater than 40:1, the basic ionic liquid comprises a basic anion selected from serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate.

Abstract translation: 本发明涉及从原油和原油馏出物中除去有机酸，特别是环烷酸的方法，其中使用负载的碱性离子液体以原油和/或原油馏出物的质量比和离子液体的离子液体 从大于40:1，碱性离子液体包含选自丝氨酸，脯氨酸，组氨酸，苏氨酸，缬氨酸，天冬酰胺酸，牛磺酸和赖氨酸的碱性阴离子。