公开(公告)号：WO2010114111A1

公开(公告)日：2010-10-07

申请号：PCT/JP2010/056047

申请日：2010-03-26

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  MITSUHASHI, Hisashi ,  SAITOU, Kenichi ,  ITAMI, Yasuo ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter Cheshire ,  KLEYER, Don Lee ,  SMITH, Janet M.

Inventor： MITSUHASHI, Hisashi ,  SAITOU, Kenichi ,  ITAMI, Yasuo ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter Cheshire ,  KLEYER, Don Lee ,  SMITH, Janet M.

IPC: C08G77/26 ,  C08G77/388 ,  C08L83/08 ,  A61K8/898

CPC classification number: C08G77/388 ,  A61K8/898 ,  A61Q1/12 ,  C08G77/26 ,  C08L83/08

Abstract: A fluorine-modified silicone polymer prepared by reacting (a) an epoxy-modified fluorocompound of the formula (I): wherein Rf is a fluoroalkyl group having 1 to 6 carbon atoms wherein at least one fluorine atom is optionally substituted by a hydrogen atom or a halogen atom, and R 1 is a bivalent organic group, with (b) an amino group-containing siloxane polymer of the formula (II): wherein R 2 , R 5 , R 6 , R 7 and R 8 are an unsubstituted or substituted monovalent organic group, R 4 and R 9 are an unsubstituted or substituted monovalent organic group or X, in which X is of the formula: NHR 11 -Y-[NH-Y] r - (III) R 3 and R 10 are an unsubstituted or substituted monovalent organic group or OR 12 , where R 12 is a hydrogen atom or unsubstituted or substituted alkyl group, and a and b are from 0 to 200, provided that when a=0, either or both R 4 and R 9 = X.

Abstract translation: 通过使（a）式（I）的环氧改性氟化合物反应制备的氟改性有机硅聚合物：其中Rf是具有1至6个碳原子的氟代烷基，其中至少一个氟原子任选被氢原子取代或 卤素原子，R 1为二价有机基团，（b）式（II）的含氨基的硅氧烷聚合物：其中R2，R5，R6，R7和R8为未取代或取代的一价有机基团，R4 并且R 9是未取代或取代的一价有机基团或X，其中X具有下式：NHR 11 -Y- [NH-Y] r - （III）R 3和R 10是未取代或取代的一价有机基团或OR 12，其中 R 12为氢原子或未取代或取代的烷基，a和b为0〜200，条件是当a = 0时，R 4和R 9均为X。

公开(公告)号：WO2010055932A2

公开(公告)日：2010-05-20

申请号：PCT/JP2009/069413

申请日：2009-11-10

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  UEDA, Akihiko ,  ITAMI, Yasuo ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter Cheshire ,  SMITH, Janet ,  LECOMTE, Jean-Paul

Inventor： UEDA, Akihiko ,  ITAMI, Yasuo ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter Cheshire ,  SMITH, Janet ,  LECOMTE, Jean-Paul

CPC classification number: C08F220/24 ,  C08F2/04 ,  C08F220/18 ,  C08F230/08 ,  Y10T428/31663 ,  Y10T428/31855 ,  Y10T428/31935

Abstract: The present invention provides a water- and oil-repellent soil-resistant composition comprising (A) a fluorine-containing polymer having repeating units derived from a monomer comprising a fluorine-containing monomer and (B) a silane compound. The water- and oil-repellent soil-resistant composition comprising the fluorine-containing acrylate polymer can impart the excellent water- and oil-repellency and soil resistance to the porous substrate and is free from an organic solvent.

Abstract translation: 本发明提供一种拒水拒油防污组合物，其包含（A）含有衍生自含有含氟单体的单体的重复单元的含氟聚合物和（B） 硅烷化合物。 包含含氟丙烯酸酯聚合物的拒水拒油防污组合物可赋予多孔基材优异的防水和防油性和防污性，并且不含有机溶剂。

公开(公告)号：WO2010044479A1

公开(公告)日：2010-04-22

申请号：PCT/JP2009/067958

申请日：2009-10-09

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  FUKUDA, Teruyuki ,  MINAMI, Shinichi ,  HUPFIELD, Peter Cheshire ,  REED, Samantha ,  SMITH, Janet

Inventor： FUKUDA, Teruyuki ,  MINAMI, Shinichi ,  HUPFIELD, Peter Cheshire ,  REED, Samantha ,  SMITH, Janet

IPC: C08F283/12 ,  C08L51/08 ,  C04B41/48 ,  C04B41/49

CPC classification number: C04B41/63 ,  C04B41/4842 ,  C08F283/122 ,  C08L51/085 ,  Y10T428/31663 ,  C04B41/483 ,  C04B41/4961 ,  C08F220/24

Abstract: The present invention provides a surface treatment agent comprising a fluorine-containing polymer having repeating units derived from a monomer comprising a fluorine-containing monomer, wherein the fluorine-containing polymer has a silicone moiety possessed by a mercapto group-containing silicone. When a porous substrate is treated under drying at normal temperature, the surface treatment agent comprising the fluorine-containing acrylate polymer can impart the excellent water- and oil-repellency and soil resistance to the porous substrate.

Abstract translation: 本发明提供一种表面处理剂，其含有含有含有含氟单体的单体的重复单元的含氟聚合物，其中含氟聚合物具有含有巯基的硅酮所具有的硅氧烷部分。 当在常温下干燥处理多孔基材时，包含含氟丙烯酸酯聚合物的表面处理剂可赋予多孔基材优异的拒水拒油性和耐污性。

公开(公告)号：WO2009084705A1

公开(公告)日：2009-07-09

申请号：PCT/JP2008/073907

申请日：2008-12-22

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  MORITA, Masamichi ,  FUKUDA, Teruyuki ,  MINAMI, Shinichi ,  MAEDA, Masahiko ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter Cheshire

Inventor： MORITA, Masamichi ,  FUKUDA, Teruyuki ,  MINAMI, Shinichi ,  MAEDA, Masahiko ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter Cheshire

IPC: A61K8/897 ,  A61Q1/00 ,  A61Q19/00

CPC classification number: A61K8/897 ,  A61K8/19 ,  A61Q1/02 ,  A61Q1/12

Abstract: A cosmetic having excellent properties can be obtained from a fluorine-containing polymer for cosmetic comprising a fluorine-containing polymer comprising repeating units derived from: (A) a monomer which comprises; (a) a fluorine-containing monomer of the formula: CH 2 =C(X)COOYRf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 6 carbon atoms, and (B) a mercapto functional organopolysiloxane.

Abstract translation: 具有优异性能的化妆品可以由包含由以下衍生的重复单元的含氟聚合物构成的化妆品用含氟聚合物得到：（A）包含以下物质的单体： （a）下式的含氟单体：CH2 = C（X）COOYRf其中X是氢原子，一价有机基团或卤素原子，Y是直接键或二价有机基团，Rf是 具有1至6个碳原子的氟烷基，和（B）巯基官能的有机聚硅氧烷。

公开(公告)号：WO2002094937A1

公开(公告)日：2002-11-28

申请号：PCT/EP2002/006447

申请日：2002-05-14

Applicant: DOW CORNING CORPORATION ,  HUPFIELD, Peter, Cheshire

Inventor： HUPFIELD, Peter, Cheshire

IPC: C08L83/04

CPC classification number: A61K8/897 ,  A61K8/042 ,  A61K8/67 ,  A61Q19/00 ,  C08G77/50 ,  C08J3/09 ,  C08J2383/04

Abstract: A crosslinked polysiloxane comprises polysiloxane chains substituted by an ester-containing organic moiety joined by crosslinks derived from the reaction of an alpha, omega-diunsaturated hydrocarbon or fluorohydrocarbon with Si-H groups on the polysiloxane chains. The ester-containing organic moiety has the formula -A-COOR where A is an alkylene linkage having 1-18 carbon atoms which is optionally fluoro-substituted and R is an alkyl or fluoroalkyl group. The crosslinked polysiloxane can form an elastomeric gel in a liquid organic or silicone material, which is useful in preparing cosmetics.

Abstract translation: 交联聚硅氧烷包括由含酯的有机部分取代的聚硅氧烷链，所述有机部分通过衍生自α，ω-二不饱和烃或氟代烃与聚硅氧烷链上的Si-H基团的反应的交联连接。 含酯的有机部分具有式-A-COOR，其中A是具有1-18个碳原子的亚烷基键，其任选被氟取代，R是烷基或氟代烷基。 交联聚硅氧烷可以在液体有机或有机硅材料中形成弹性体凝胶，其可用于制备化妆品。

公开(公告)号：WO2011062292A1

公开(公告)日：2011-05-26

申请号：PCT/JP2010/071068

申请日：2010-11-18

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  UESUGI, Norimasa ,  KUBOTA, Kouji ,  YAMAMOTO, Ikuo ,  HUPFIELD, Peter Cheshire

Inventor： UESUGI, Norimasa ,  KUBOTA, Kouji ,  YAMAMOTO, Ikuo ,  HUPFIELD, Peter Cheshire

IPC: D06M23/10 ,  D06M15/277 ,  D06M15/356 ,  C09K3/18 ,  C08K5/16 ,  C08L33/16 ,  C08F220/24

CPC classification number: D06M15/657 ,  C08F220/24 ,  C08G77/442 ,  C08K5/16 ,  C09K3/18 ,  C09K2003/1081 ,  D06M15/277 ,  D06M15/576 ,  Y10T442/2172 ,  C08L33/16 ,  C08F220/18 ,  C08F2220/1891 ,  C08F2220/281 ,  C08F220/58

Abstract: Disclosed is a fluorine-containing polymer prepared by polymerizing (I) a polyfluoroalkyl group-containing (meth)acrylate which is substituted at alpha-position, in the presence of (II) a blocked isocyanate compound. A water- and oil-repellent composition containing the fluorine-containing polymer can impart the excellent water- and oil-repellency, and excellent durability thereof to substrates.

Abstract translation: 公开了在（II）封端异氰酸酯化合物存在下，通过聚合（I）在α位被取代的含有多氟烷基的（甲基）丙烯酸酯而制备的含氟聚合物。 含有含氟聚合物的拒水拒油剂可赋予基材优异的拒水拒油性和优异的耐久性。

公开(公告)号：WO2009122919A2

公开(公告)日：2009-10-08

申请号：PCT/JP2009/055381

申请日：2009-03-12

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  YAMAMOTO, Ikuo ,  MASUTANI, Tetsuya ,  MIYAHARA, Masahiro ,  ENOMOTO, Takashi ,  MINAMI, Shinichi ,  HUPFIELD, Peter, Cheshire ,  REED, Samantha ,  SURGENOR, Avril, E.

Inventor： YAMAMOTO, Ikuo ,  MASUTANI, Tetsuya ,  MIYAHARA, Masahiro ,  ENOMOTO, Takashi ,  MINAMI, Shinichi ,  HUPFIELD, Peter, Cheshire ,  REED, Samantha ,  SURGENOR, Avril, E.

CPC classification number: C08F283/122 ,  C08F14/18 ,  C08F14/22 ,  C08F214/186 ,  C08F283/124 ,  C08J3/03 ,  C08J2383/10 ,  D06M15/277 ,  D06M15/3568 ,  D06M15/643 ,  D06M15/6436 ,  D06M15/657 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50 ,  C08F2/30

Abstract: A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH 2 =C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.

Abstract translation: 公开了巯基或乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟化硅反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）巯基或乙烯基官能的有机聚硅氧烷制备。

公开(公告)号：WO2009119423A1

公开(公告)日：2009-10-01

申请号：PCT/JP2009/055382

申请日：2009-03-12

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING CORPORATION ,  UEDA, Akihiko ,  MINAMI, Shinichi ,  MAEDA, Masahiko ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter, Cheshire ,  REED, Samantha ,  SURGENOR, Avril, E.

Inventor： UEDA, Akihiko ,  MINAMI, Shinichi ,  MAEDA, Masahiko ,  MASUTANI, Tetsuya ,  HUPFIELD, Peter, Cheshire ,  REED, Samantha ,  SURGENOR, Avril, E.

IPC: C08F283/12 ,  D06M15/19 ,  C08G77/28 ,  D06M15/643

CPC classification number: C08F283/12 ,  C08L51/085 ,  C09D151/085 ,  C08L2666/02

Abstract: A polymer for leather treatment and a leather treatment agent having excellent properties can be obtained from a fluorine-containing polymer comprising repeating units derived from: (A) a monomer which comprises; (a) a fluorine-containing monomer of the formula: CH 2 =C(X)COOYRf, wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 21 carbon atoms, wherein the monomer is polymerized in the presence of: (B) a mercapto functional organopolysiloxane.

Abstract translation: 具有优异特性的用于皮革处理的聚合物和具有优异性能的皮革处理剂可以由包含衍生自以下的重复单元的含氟聚合物获得：（A）包含的单体; （a）下式的含氟单体：CH2 = C（X）COOYRf，其中X是氢原子，一价有机基团或卤素原子，Y是直接键或二价有机基团，Rf 是具有1至21个碳原子的氟代烷基，其中单体在下列存在下聚合：（B）巯基官能的有机聚硅氧烷。

公开(公告)号：WO2008072716A1

公开(公告)日：2008-06-19

申请号：PCT/JP2007/074066

申请日：2007-12-06

Applicant: DAIKIN INDUSTRIES, LTD. ,  DOW CORNING TORAY CO., LTD. ,  DOW CORNING CORPORATION ,  IMOTO, Katsuhiko ,  SHIMIZU, Tetsuo ,  HAYASHI, Masayuki ,  IIMURA, Tomohiro ,  KITAURA, Eiji ,  HUPFIELD, Peter, Cheshire

Inventor： IMOTO, Katsuhiko ,  SHIMIZU, Tetsuo ,  HAYASHI, Masayuki ,  IIMURA, Tomohiro ,  KITAURA, Eiji ,  HUPFIELD, Peter, Cheshire

IPC: C08L33/04 ,  C08L27/14

CPC classification number: C08L27/16 ,  C08L27/14 ,  C08L33/04 ,  C08L2666/04

Abstract: There is provided a curable polymer composition being curable quickly to form a cured article having excellent adhesion and followability to a substrate and at least comprising (A) an acrylic copolymer having a hydrogen atom bonded to a silicon atom, (B) a compound having at least two aliphatic unsaturated bonds in one molecule thereof, (C) a fluoroolefin copolymer comprising vinylidene fluoride as main component, and (D) a catalyst for hydrosilylation reaction.

Abstract translation: 提供了可固化的聚合物组合物，其可快速固化以形成具有优异的粘合性和对基材的追随性的固化制品，并且至少包含（A）具有与硅原子键合的氢原子的丙烯酸共聚物，（B） 其一分子中含有至少两个脂族不饱和键，（C）以偏氟乙烯为主要成分的氟代烯烃共聚物，（D）氢化硅烷化反应催化剂。

公开(公告)号：WO2007077982A2

公开(公告)日：2007-07-12

申请号：PCT/JP2006326419

申请日：2006-12-28

Applicant: DOW CORNING TORAY CO LTD ,  DOW CORNING ,  HAYASHI MASAYUKI ,  HUPFIELD PETER CHESHIRE ,  OKAWA TADASHI ,  IIMURA TOMOHIRO

Inventor： HAYASHI MASAYUKI ,  HUPFIELD PETER CHESHIRE ,  OKAWA TADASHI ,  IIMURA TOMOHIRO

IPC: C08G77/385 ,  C08G77/442

CPC classification number: C08G77/385 ,  C08G77/442

Abstract: A novel fluorine-containing organopolysiloxane represented by the following general formula: {where all R 1 's are univalent hydrocarbon groups that may or may not contain fluorine atoms, at least one R 1 is an organic group that contains a fluorine atom; Z designates a group selected from the same groups as those designated by R 1 , a group represented by the following general formula (I): - [R 2 - (SiR 1 2 )

Abstract translation: 一种由以下通式表示的新颖的含氟有机聚硅氧烷：其中所有的R 1是可以含有或不含有氟原子的一价烃基，至少一个R 1， SUP>是含有氟原子的有机基团; Z表示选自与由R 1表示的基团相同的基团，由以下通式（I）表示的基团： - [R 2 - （SiR） SUP> 1 2 ）