公开(公告)号：WO2003027016A1

公开(公告)日：2003-04-03

申请号：PCT/US2002/016355

申请日：2002-05-22

Applicant: THE DOW CHEMICAL COMPANY ,  GARCES, Juan, M. ,  LAKSO, Steve, R. ,  SUN, Tao ,  JOVANOVIC, Zoran, R. ,  KUPERMAN, Alex ,  FIBIGER, Richard, F.

Inventor： GARCES, Juan, M. ,  LAKSO, Steve, R. ,  SUN, Tao ,  JOVANOVIC, Zoran, R. ,  KUPERMAN, Alex ,  FIBIGER, Richard, F.

IPC: C01B33/44

CPC classification number: C08K7/10 ,  C01B33/44 ,  C08K3/346 ,  C08K7/00 ,  C08K9/04 ,  C08L23/02

Abstract: A polyolefin nanocomposite composition having from one to twenty weight percent of a platy cation exchanging layered silicate material (such as magadiite), from one to twenty weight percent of a fibrous cation exchanging layered silicate material (such as sepiolite) and from ninety eight to sixty weight percent of a polyolefin polymer matrix (such as polypropylene), the platy cation exchanging layered silicate material and the fibrous cation exchanging layered silicate material being dispersed in the polyolefin polymer matrix. .The use ofboth the platy and the fibrous cation exchanging layered silicate material results in a synergistic improvement of the physical properties of the composition. The composition can be made by melt blending the polymer with the platy and fibrous material. Alternatively, the composition can be made by polymerizing the polymber with a metallocene polymerization catalyst treated dispersion of an acid treated platy and fibrous material in a solvent so that the olefin polymerizes to form the composition.

Abstract translation: 一种聚烯烃纳米复合材料组合物，其具有一至二十重量百分比的层状阳离子交换层状硅酸盐材料（例如magadiite），一至二十重量百分比的纤维阳离子交换层状硅酸盐材料（例如海泡石）和九十八至六十 聚烯烃聚合物基质（例如聚丙烯）的重量百分数，层状阳离子交换层状硅酸盐材料和纤维阳离子交换层状硅酸盐材料分散在聚烯烃聚合物基质中。 使用板状和纤维状阳离子交换层状硅酸盐材料可以使组合物的物理性能得到协同的改善。 该组合物可以通过将聚合物与片状和纤维材料熔融共混来制备。 或者，组合物可以通过将茂金属聚合催化剂处理的酸处理的片状和纤维材料的分散体在溶剂中聚合多伯而制成，使得烯烃聚合形成组合物。

公开(公告)号：WO0130864A3

公开(公告)日：2002-03-28

申请号：PCT/US0027840

申请日：2000-10-06

Applicant: DOW CHEMICAL CO ,  SUN TAO ,  GARCES JUAN M ,  JOVANOVIC ZORAN R

Inventor： SUN TAO ,  GARCES JUAN M ,  JOVANOVIC ZORAN R

IPC: B01J21/08 ,  B01J21/16 ,  B01J31/22 ,  C01B33/154 ,  C01B33/157 ,  C08F4/02 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08G77/02 ,  C08G77/04 ,  C08K7/00 ,  C08K9/08 ,  C08K3/34 ,  C01B33/44

CPC classification number: B01J31/2291 ,  B01J21/08 ,  B01J21/16 ,  B01J29/049 ,  B01J31/143 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/49 ,  C01B33/154 ,  C01B33/157 ,  C08F4/025 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08K7/00 ,  C08K9/08 ,  C08F2/44 ,  C08F4/65916 ,  C08L23/02

Abstract: A method for producing a nanocomposite polymer that includes the step of adding an olefin to a metallocene polymerization catalyst treated dispersion of an acid treated cation exchanging layered silicate material in a solvent so that the olefin polymerizes to form the nanocomposite polymer. An exfoliated acid treated cation exchanging layered silicate material dispersed in a polymer matrix, wherein more than about fifty percent of the acid treated cation exchanging layered silicate material is found by electron microscopy to have five or fewer layers. A metallocene polymerization catalyst treated, acid treated cation exchanging layered silicate material.

Abstract translation: 一种制备纳米复合材料聚合物的方法，其包括将烯烃加入茂金属聚合催化剂处理的酸处理的阳离子交换层状硅酸盐材料在溶剂中的分散体，使得烯烃聚合形成纳米复合聚合物的步骤。 分散在聚合物基质中的经剥离的酸处理的阳离子交换层状硅酸盐材料，其中通过电子显微镜发现超过约百分之五十的经酸处理的阳离子交换层状硅酸盐材料具有五层或更少层。 茂金属聚合催化剂处理，酸处理阳离子交换层状硅酸盐材料。

公开(公告)号：WO0125149A3

公开(公告)日：2002-03-14

申请号：PCT/US0027839

申请日：2000-10-06

Applicant: DOW CHEMICAL CO ,  SUN TAO ,  GARCES JUAN M ,  JOVANOVIC ZORAN R ,  CARNAHAN EDMUND M

Inventor： SUN TAO ,  GARCES JUAN M ,  JOVANOVIC ZORAN R ,  CARNAHAN EDMUND M

IPC: B01J21/08 ,  B01J21/16 ,  B01J31/22 ,  C01B33/154 ,  C01B33/157 ,  C08F4/02 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08G77/02 ,  C08G77/04 ,  C08K7/00 ,  C08K9/08

CPC classification number: B01J31/2291 ,  B01J21/08 ,  B01J21/16 ,  B01J29/049 ,  B01J31/143 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/49 ,  C01B33/154 ,  C01B33/157 ,  C08F4/025 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08K7/00 ,  C08K9/08 ,  C08F2/44 ,  C08F4/65916 ,  C08L23/02

Abstract: The invention relates to silica gel compositions containing acidified cation exchanging layered silicate materials and methods for preparing such compositions. These silica gel compositions can be contacted with metallocene polymerization catalysts to produce a catalyst composition.

Abstract translation: 本发明涉及含有酸化的阳离子交换层状硅酸盐材料的硅胶组合物及其制备方法。 这些硅胶组合物可以与金属茂聚合催化剂接触以产生催化剂组合物。

公开(公告)号：WO2011155962A1

公开(公告)日：2011-12-15

申请号：PCT/US2010/059564

申请日：2010-12-08

Applicant: SUNDROP FUELS, INC. ,  SIMMONS, Wayne, W. ,  PERKINS, Christopher ,  JOVANOVIC, Zoran ,  HILTON, Courtland, M. ,  POPP, Peter ,  SCHRAMM, Bryan, J. ,  TURNER, John, T.

Inventor： SIMMONS, Wayne, W. ,  PERKINS, Christopher ,  JOVANOVIC, Zoran ,  HILTON, Courtland, M. ,  POPP, Peter ,  SCHRAMM, Bryan, J. ,  TURNER, John, T.

IPC: B21D53/02

CPC classification number: C07C29/152 ,  C01B3/24 ,  C01B3/34 ,  C01B2203/0216 ,  C01B2203/0222 ,  C01B2203/0272 ,  C01B2203/0485 ,  C01B2203/0495 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0877 ,  C01B2203/0894 ,  C01B2203/1241 ,  C10G2300/1011 ,  C10G2300/807 ,  C10G2400/02 ,  C10J3/485 ,  C10J3/506 ,  C10J3/84 ,  C10J2200/152 ,  C10J2300/0906 ,  C10J2300/0909 ,  C10J2300/0916 ,  C10J2300/0976 ,  C10J2300/0989 ,  C10J2300/1223 ,  C10J2300/1246 ,  C10J2300/1269 ,  C10J2300/1292 ,  C10J2300/1621 ,  C10J2300/1665 ,  C10J2300/1687 ,  C10J2300/1693 ,  C10J2300/1884 ,  C10J2300/1892 ,  F28D2021/0022 ,  Y02E50/18 ,  Y02P20/128 ,  Y02P20/129 ,  Y02P20/134 ,  Y02P20/145 ,  Y02P30/20 ,  C07C31/04

Abstract: Various processes and apparatus are discussed for an ultra-high heat flux chemical reactor. A thermal receiver and the reactor tubes are aligned to 1 ) absorb and re-emit radiant energy, 2) highly reflect radiant energy, and 3) any combination of these, to maintain an operational temperature of the enclosed ultra-high heat flux chemical reactor. Particles of biomass are gasified in the presence of a steam carrier gas and methane in a simultaneous steam reformation and steam biomass gasification reaction to produce reaction products that include hydrogen and carbon monoxide gas using the ultra-high heat flux thermal energy radiated from the inner wall and then into the multiple reactor tubes. The multiple reactor tubes and cavity walls of the receiver transfer energy primarily by radiation absorption and re-radiation, rather than by convection or conduction, to the reactants in the chemical reaction to drive the endothermic chemical reaction flowing in the reactor tubes.

Abstract translation: 讨论了超高热通量化学反应器的各种工艺和装置。 热接收器和反应器管对准1）吸收和再发射辐射能，2）高度反射辐射能，3）任何组合，以保持封闭的超高热通量化学反应器的工作温度 。 生物质颗粒在蒸汽载体气体和甲烷的存在下在同时蒸汽重整和蒸汽生物质气化反应中气化，以产生包含氢气和一氧化碳气体的反应产物，使用从内壁辐射的超高热通量热能 然后进入多个反应管。 接收器的多个反应器管和空腔壁主要通过辐射吸收和再辐射而不是通过对流或传导将能量转移到化学反应中的反应物以驱动在反应器管中流动的吸热化学反应。