公开(公告)号：WO2017010718A1

公开(公告)日：2017-01-19

申请号：PCT/KR2016/007201

申请日：2016-07-04

申请人： LG NANOH2O, INC. ,  LG CHEM, LTD.

发明人： JEON, Hyung Joon ,  KOEHLER, Jeff ,  CHOI, Hyungsam

IPC分类号： B01D71/00 ,  B01D71/02 ,  B01D71/06 ,  B01D69/12 ,  C02F1/44

CPC分类号： B01D69/125 ,  B01D61/025 ,  B01D69/02 ,  B01D71/022 ,  B01D71/56 ,  B01D71/60 ,  B01D2325/20 ,  C02F1/441 ,  C02F2103/08

摘要： Provided are flux enhancing inclusion complexes for preparing highly permeable thin film composite membranes, and processes that include adding the flux enhancing inclusion complexes to the organic phase or aqueous phase prior to interfacial polymerization of the thin film composite membrane. The thin film composite membranes are suitable for nanofiltration, and reverse and forward osmosis. The provided processes can include contacting a porous support membrane with an aqueous phase containing a polyamine to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide and a flux enhancing inclusion complex to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer to form thin film composite membranes.

摘要翻译： 提供了用于制备高渗透性薄膜复合膜的通量增强包合络合物，以及包括在薄膜复合膜的界面聚合之前将助熔剂增强包合配合物添加到有机相或水相中的方法。 薄膜复合膜适用于纳滤，反向和正向渗透。 所提供的方法可以包括使多孔支持膜与含有多胺的水相接触以形成涂覆的支撑膜，以及将包含多官能酰卤和助焊剂增强包合配合物的有机相施加到涂覆的支持膜上以使多胺界面聚合 和多官能酰卤形成鉴别层以形成薄膜复合膜。

公开(公告)号：WO2016196821A1

公开(公告)日：2016-12-08

申请号：PCT/US2016/035559

申请日：2016-06-02

申请人： LG NANOH2O, INC.

发明人： KOEHLER, Jeff ,  FOSTER, Alexis ,  SONG, Keunwon ,  LEE, Young, Ju ,  SHIN, Chongkyu

IPC分类号： C08J5/22 ,  C08K5/00 ,  C08L79/02 ,  C08K5/5353 ,  C08J3/03

CPC分类号： C02F1/441 ,  B01D61/025 ,  B01D63/10 ,  B01D69/125 ,  B01D69/148 ,  B01D71/56 ,  C02F2103/08 ,  Y02A20/131

摘要： Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, forward osmosis, or reverse osmosis, particularly for use with brackish water at low energy conditions. The process includes contacting a porous support membrane with an aqueous phase containing a polyamine and a flux enhancing combination of additives that includes a metal chelate additive containing a bidentate ligand and a metal atom or metal ion and a phosphoramide to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer of the thin film composite membrane. Also provided are the membranes prepared by the methods and reverse osmosis modules containing the membranes.

摘要翻译： 提供了用于制备高渗透性薄膜复合膜的界面聚合方法，其可用于纳滤，前向渗透或反渗透，特别是用于在低能量条件下的微咸水。 该方法包括使多孔支撑膜与含有多胺的水相和增强助焊剂的组合使得该添加剂包含含有二齿配体和金属原子或金属离子的金属螯合添加剂和磷酰胺形成涂覆的支撑膜，以及 将包含多官能酰卤的有机相施加到涂覆的支撑膜上以使多胺和多官能酰卤交联聚合以形成薄膜复合膜的鉴别层。 还提供了通过包含膜的方法和反渗透模块制备的膜。

公开(公告)号：WO2016196814A1

公开(公告)日：2016-12-08

申请号：PCT/US2016/035546

申请日：2016-06-02

申请人： LG NANOH2O, INC.

发明人： KOEHLER, Jeff ,  FOSTER, Alexis ,  SONG, Keunwon ,  LEE, Young, Ju ,  SHIN, Chongkyu

IPC分类号： B01D71/06 ,  B01D61/02 ,  B01D63/10 ,  B01D69/10 ,  B01D69/12

CPC分类号： C02F1/441 ,  B01D61/025 ,  B01D65/08 ,  B01D67/0006 ,  B01D67/0088 ,  B01D69/12 ,  B01D69/125 ,  B01D69/145 ,  B01D71/028 ,  B01D71/56 ,  B01D71/60 ,  B01D2323/40 ,  C02F2103/08 ,  Y02A20/131

摘要： Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, or forward or reverse osmosis, for use with tap water, seawater and brackish water, particularly for use with brackish water at low energy conditions. The process includes contacting a porous support membrane with an aqueous phase containing a polyamine and a flux enhancing combination, which includes a metal chelate additive containing a bidentate ligand and a metal atom or metal ion and a dialkyl sulfoxide, to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer of the thin film composite membrane. Also provided are the membranes prepared by the methods and reverse osmosis modules containing the membranes.

摘要翻译： 提供了一种用于制备可渗透的高渗透性薄膜复合膜的界面聚合方法，其可用于纳滤，或向前或反向渗透，用于自来水，海水和咸水，特别是用于低能量的咸水 条件。 该方法包括使多孔支撑膜与含有多胺和助熔剂增强组合的水相接触，其包含含有二齿配体和金属原子或金属离子和二烷基亚砜的金属螯合添加剂，以形成涂覆的支撑膜， 以及将包含多官能酰卤的有机相施加到所述涂覆的支撑膜上以使所述多胺和所述多官能酰卤交联聚合以形成所述薄膜复合膜的鉴别层。 还提供了通过包含膜的方法和反渗透模块制备的膜。

公开(公告)号：WO2017150885A1

公开(公告)日：2017-09-08

申请号：PCT/KR2017/002197

申请日：2017-02-28

申请人： LG NANOH2O, INC. ,  LG CHEM, LTD.

发明人： SONG, Keunwon ,  KO, Young Hoon ,  ROZENBAOUM, Evgueni ,  SHIN, Chongkyu

IPC分类号： B01D69/12 ,  C02F1/44

摘要： Provided is a post-formation process for preparation of a highly permeable thin film composite membranes for reverse osmosis, particularly for use with brackish water at low energy conditions. The process includes contacting a polyamide discrimination layer of a TFC membrane with a solution containing an oxidizing agent to form a treated membrane, followed by contacting the treated membrane with a solution containing a reducing agent. The resulting membrane exhibits enhanced water flux while maintaining salt rejection. Also provided are reverse osmosis membranes prepared in accord with the method, and modules containing the highly permeable thin film composite membranes, and methods of purifying water using the membranes or modules.

摘要翻译： 提供了用于制备用于反渗透的高渗透性薄膜复合膜的后成型工艺，特别用于在低能量条件下使用含盐水。 该方法包括使TFC膜的聚酰胺分辨层与含有氧化剂的溶液接触以形成经处理的膜，随后使经处理的膜与含有还原剂的溶液接触。 得到的膜表现出增强的水通量，同时保持脱盐。 还提供了根据该方法制备的反渗透膜，以及包含高渗透性薄膜复合膜的模块，以及使用膜或模块净化水的方法。

公开(公告)号：WO2017123507A1

公开(公告)日：2017-07-20

申请号：PCT/US2017/012768

申请日：2017-01-09

申请人： LG NANOH2O, INC. ,  LG CHEM, LTD.

发明人： HOLMBERG, Brett, Anderson ,  KOEHLER, Jeff ,  JEON, Hyung Joon

IPC分类号： B01D67/00 ,  B01D61/02

CPC分类号： B01D67/0088 ,  B01D67/0095 ,  B01D69/02 ,  B01D69/10 ,  B01D69/125 ,  B01D71/56 ,  C02F1/441 ,  C02F2103/08 ,  Y02A20/131

摘要： Provided is a process for preparation of a highly permeable thin film composite membranes for nanofiltration, reverse osmosis, and forward osmosis, particularly for reverse osmosis of brackish water. The process includes treating a prepared TFC membrane containing a discrimination layer on a frontside, a support layer, and a felt layer on the backside by contacting the backside of TFC membrane with a solution containing a pore protection agent that includes a tertiary amine salt of camphorsulfonic acid prior to or at the same time as contacting the frontside of the membrane with a solution containing a coating agent and drying the membrane. Also provided are reverse osmosis membranes prepared in accord with the method, and modules containing the highly permeable thin film composite membranes.

摘要翻译： 本发明提供了一种用于纳米过滤，反渗透和正渗透，特别是用于微咸水反渗透的高渗透性薄膜复合膜的制备方法。 该方法包括通过使TFC膜的背面与含有包含樟脑磺酸的叔胺盐的孔隙保护剂的溶液接触来处理在背面上的前侧，支撑层和毡层上包含歧视层的制备的TFC膜 在将膜的前侧与含有涂层剂的溶液接触并干燥膜之前或同时进行。 还提供了根据该方法制备的反渗透膜和含有高渗透性薄膜复合膜的模块。