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    SUBSTITUTED TERRYLENE AND QUATERRYLENE DERIVATIVES AND THE USE AS SEMICONDUCTORS
    1.
    发明申请
    SUBSTITUTED TERRYLENE AND QUATERRYLENE DERIVATIVES AND THE USE AS SEMICONDUCTORS 审中-公开
    取代的叔丁基和季戊四醇衍生物和作为半导体的用途

    公开(公告)号：WO2014002061A2

    公开(公告)日：2014-01-03

    申请号：PCT/IB2013/055309

    申请日：2013-06-28

    申请人： BASF SE ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E. V. ,  BASF (CHINA) COMPANY LIMITED ,  GEßNER, Thomas ,  REICHELT, Helmut ,  BATTAGLIARIN, Glauco ,  LI, Chen ,  MÜLLEN, Klaus

    发明人： GEßNER, Thomas ,  REICHELT, Helmut ,  BATTAGLIARIN, Glauco ,  LI, Chen ,  MÜLLEN, Klaus

    CPC分类号： H01L51/0072 ,  C07D471/06 ,  C07D487/06 ,  C07F5/04 ,  C09B5/62 ,  H01L27/283 ,  H01L51/0053 ,  H01L51/0545 ,  H01L51/0558 ,  H01L51/105 ,  H01L51/5012 ,  H01L51/5088 ,  H01L51/5234 ,  Y02E10/549

    摘要： The present invention relates to terrylene and quaterrylene derivates of the general formula I (formula I) (I) wherein n is 0 or 1, R a and R b are independently of one another selected from hydrogen and in each case unsubstituted or substituted alkyl, alkenyl, alkadienyl, alkynyl, cycloalkyl, bicyclo- alkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl, X 1 , X 2 , X 3 and X 4 are independently of one another selected from F, CI, Br, I, CN and B(OR c ) 2 , wherein R c is selected from in each case unsubstituted or substituted alkyl, cycloalkyl or aryl, or wherein two radicals R c may together form a divalent bridging group selected from in each case unsubstituted or substituted C 2 - C 10 -alkylene, C 3 -C 6 -cycloalkylene and C 6 -C 14 -arylene, wherein C 2 -C 10 - alkylene, C 3 -C 6 -cycloalkylene and C 6 -C 14 -arylene may carry one or more identical or different C 2 -C 12 -alkyl radicals, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 11 and R 12 and, if present, R 7 , R 8 , R 9 and R 10 are independently of one another selected from hydrogen, F, CI, Br, I, CN, hydroxy, mercapto, nitro, cyanato, thiocyanato, formyl, acyl, carboxy, carboxylate, alkylcarbonyloxy, car¬ bamoyl, alkylaminocarbonyl, dialkylaminocarbonyl, sulfo, sulfonate, sulfoamino, sulfamoyl, alkylsulfonyl, arylsulfonyl, amidino, NE 1 E 2 , where E 1 and E 2 are each independently selected from hydrogen, alkyl, cycloalkyi, heterocycloalkyl, aryl or hetaryl, in each case unsubstituted or substituted alkyl, alkoxy, alkylthio, (monoal- kyl)amino, (dialkyl)amino, cycloalkyi, cycloalkoxy, cycloalkylthio, (monocycloal- kyl)amino, (dicycloalkyl)amino, heterocycloalkyi, heterocycloalkoxy, heterocyclo- alkylthio, (monoheterocycloalkyl)amino, (diheterocycloalkyl)amino, aryl, aryloxy, arylthio, (monoaryl)amino, (diaryl)amino, hetaryl, hetaryloxy, hetarylthio, (mono- hetaryl)amino, (dihetaryl)amino, and the use thereof as organic semiconductor materials.

    摘要翻译： 本发明涉及通式I（式I）（I）的二亚烷基和四亚甲基衍生物，其中n为0或1，Ra和Rb彼此独立地选自氢，并且在每种情况下均为未取代或取代的烷基，烯基， 链烯基，炔基，环烷基，双环烷基，环烯基，杂环烷基，芳基或杂芳基，X1，X2，X3和X4彼此独立地选自F，Cl，Br，I，CN和B（ORc）2，其中Rc 在每种情况下选自未取代或取代的烷基，环烷基或芳基，或其中两个基团Rc可以一起形成二价桥基，其选自在每种情况下未取代或取代的C 2 -C 10 - 亚烷基，C 3 -C 6 - 亚环烷基和C 6 -C 14 亚芳基，其中C 2 -C 10 - 亚烷基，C 3 -C 6 - 亚环烷基和C 6 -C 14亚芳基可以携带一个或多个相同或不同的C 2 -C 12 - 烷基，R 1，R 2，R 3，R 4，R 5，R 6，R 11和 R 12，如果存在，R 7，R 8，R 9和R 10彼此独立地选自氢， F，Cl，Br，I，CN，羟基，巯基，硝基，氰基，硫氰酸酯，甲酰基，酰基，羧基，羧酸酯，烷基羰氧基，羧酰基，烷基氨基羰基，二烷基氨基羰基，磺基，磺酸酯基，磺氨基，氨磺酰基，烷基磺酰基，芳基磺酰基， 脒基，NE1E2，其中E1和E2各自独立地选自氢，烷基，环烷基，杂环烷基，芳基或杂芳基，在每种情况下为未取代或取代的烷基，烷氧基，烷硫基，（单烷基）氨基，（二烷基）氨基， ，环烷氧基，环烷硫基，（单环烷基）氨基，（二环烷基）氨基，杂环烷基，杂环烷氧基，杂环烷硫基，（单杂环烷基）氨基，（二杂环烷基）氨基，芳基，芳氧基，芳硫基，（单芳基）氨基，（二芳基）氨基 ，杂芳基，杂芳氧基，杂芳硫基，（单杂芳基）氨基，（二杂芳基）氨基及其作为有机半导体材料的用途。