公开(公告)号：WO2011140018A1

公开(公告)日：2011-11-10

申请号：PCT/US2011/034897

申请日：2011-05-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  WALKER, Christopher B. Jr., ,  TEBOW, Christopher P., ,  PHAM, Tri D., ,  KONG, Steven H., ,  ARONSON, Joseph T., ,  LINDSTROM, Kyle J., ,  GERLACH, Michael K., ,  TOY, Michelle L., ,  MCKENZIE, Taun L., ,  RENSTROM, Anthony M., ,  YAPEL, Robert A., ,  JOHNSON, Mitchell A.F.,

Inventor： WALKER, Christopher B. Jr., ,  TEBOW, Christopher P., ,  PHAM, Tri D., ,  KONG, Steven H., ,  ARONSON, Joseph T., ,  LINDSTROM, Kyle J., ,  GERLACH, Michael K., ,  TOY, Michelle L., ,  MCKENZIE, Taun L., ,  RENSTROM, Anthony M., ,  YAPEL, Robert A., ,  JOHNSON, Mitchell A.F.,

IPC: G02B1/10 ,  G02F1/1335 ,  G02B1/11

CPC classification number: G02B1/118 ,  G02B5/0242

Abstract: The present invention concerns antireflective films comprising a high refractive index layer (60) and low refractive index layer (80) disposed on the high refractive index layer. The antireflective films have a microstructured surface (70) that can be derived from a microreplicated tool.

Abstract translation: 本发明涉及包括设置在高折射率层上的高折射率层（60）和低折射率层（80）的抗反射膜。 抗反射膜具有可由微复制工具衍生的微结构化表面（70）。

公开(公告)号：WO2010074862A1

公开(公告)日：2010-07-01

申请号：PCT/US2009/065352

申请日：2009-11-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JONES, Clinton, L., ,  KOLB, Brant, U., ,  MCKENZIE, Taun, L., ,  OLSON, David, B., ,  NAISMITH, Nathan, K.,

Inventor： JONES, Clinton, L., ,  KOLB, Brant, U., ,  MCKENZIE, Taun, L., ,  OLSON, David, B., ,  NAISMITH, Nathan, K.,

IPC: G02B6/00 ,  C08K5/101 ,  C08K9/04

CPC classification number: G02B1/04 ,  B82Y30/00 ,  C01P2004/64 ,  C08K5/11 ,  C09C1/00 ,  C09C1/3676 ,  C09C3/10 ,  G02B1/08 ,  G02B6/0053 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1064 ,  Y10T428/1077 ,  Y10T428/1082 ,  Y10T428/24355 ,  Y10T428/24405 ,  Y10T428/24413 ,  Y10T428/31855

Abstract: Microstructured films comprising surface modified inorganic oxide particles, surface modified inorganic nanoparticles having a high refractive index, and polymerizable resins are described.

Abstract translation: 描述了包含表面改性的无机氧化物颗粒，具有高折射率的表面改性的无机纳米颗粒和可聚合树脂的微结构膜。

公开(公告)号：WO2009086079A3

公开(公告)日：2009-10-08

申请号：PCT/US2008087641

申请日：2008-12-19

Applicant: 3M INNOVATIVE PROPERTIES CO ,  KUMAR RAMESH C ,  MCKENZIE TAUN L ,  LU YING-YUH

Inventor： KUMAR RAMESH C ,  MCKENZIE TAUN L ,  LU YING-YUH

IPC: C08F220/18 ,  C08F290/06 ,  C08F292/00 ,  C09D133/06

CPC classification number: C09D143/04 ,  B82Y30/00 ,  C08F230/08 ,  C08F283/126 ,  C08F290/068 ,  C09J7/401 ,  C09J7/405 ,  C09J151/085 ,  C09J2400/163 ,  C09J2400/226 ,  C09J2400/263 ,  C09J2400/283 ,  C09J2429/005 ,  C09J2433/005 ,  C09J2483/005 ,  Y10T428/2848 ,  Y10T428/31663 ,  Y10T442/20

Abstract: A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) silicone macromer. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.

Abstract translation: 共聚物包含（a）（甲基）丙烯酸酯官能化纳米颗粒，（b）乙烯基单体和（c）硅氧烷大分子单体的反应产物。 （甲基）丙烯酸酯官能化的纳米粒子选自二氧化硅纳米粒子，氧化锆纳米粒子，二氧化钛纳米粒子及其组合。

公开(公告)号：WO2009085740A2

公开(公告)日：2009-07-09

申请号：PCT/US2008086951

申请日：2008-12-16

Applicant: 3M INNOVATIVE PROPERTIES CO ,  KUMAR RAMESH C ,  MCKENZIE TAUN L ,  LU YING-YUH

Inventor： KUMAR RAMESH C ,  MCKENZIE TAUN L ,  LU YING-YUH

IPC: C08F292/00 ,  C08J5/02 ,  C08L33/04 ,  C08L57/00

CPC classification number: C09D143/04 ,  B82Y30/00 ,  C08F2/38 ,  C08F283/122 ,  C08L83/08 ,  C09D151/085 ,  C09J7/401 ,  C09J151/085 ,  C09J2433/005 ,  C09J2483/005 ,  C08F230/08

Abstract: A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) mercapto-functional silicone. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.

Abstract translation: 共聚物包含（a）（甲基）丙烯酸酯官能化纳米颗粒，（b）乙烯基单体和（c）巯基官能化硅氧烷的反应产物。 （甲基）丙烯酸酯官能化纳米颗粒选自二氧化硅纳米颗粒，氧化锆纳米颗粒，二氧化钛纳米颗粒及其组合。

公开(公告)号：WO2008121465A1

公开(公告)日：2008-10-09

申请号：PCT/US2008/055058

申请日：2008-02-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KOLB, Brant U. ,  JONES, Clinton L. ,  OLSON, David B. ,  MCKENZIE, Taun L. ,  NAISMITH, Nathan K.

Inventor： KOLB, Brant U. ,  JONES, Clinton L. ,  OLSON, David B. ,  MCKENZIE, Taun L. ,  NAISMITH, Nathan K.

IPC: C08F2/44 ,  C08J5/18 ,  G02B1/04 ,  C09D133/00

CPC classification number: G02B1/04 ,  B82Y20/00 ,  B82Y30/00 ,  C08F2/44 ,  C08J5/18 ,  C08J2335/02 ,  C08L35/02 ,  G02F2001/133507 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/105 ,  Y10T428/1064 ,  Y10T428/1077 ,  Y10T428/24355 ,  Y10T428/24405 ,  Y10T428/24413 ,  Y10T428/2998

Abstract: Microstructured films such as brightness enhancing films, polymerizable resin compositions comprising an organic component and surface modified nanoparticles, and surface modified nanoparticles are described. The microstructured film has a polymerized structure comprising the reaction product of the polymerizable resin composition (e.g. having a refractive index of at least 1.58). The cured nanocomposite (e.g. structure) can exhibit improved crack resistance. In some embodiments, the flexibility is expressed in terms of a cylindrical mandrel bend test property (e.g. a mandrel size to failure of less than 6 mm or a mandrel size to failure according to the equation D = 1000(T/0.025-T) wherein T is the thickness in millimeters of a (e.g. preformed base layer). In other embodiments, the flexibility is expressed in terms of a tensile and elongation property (e.g. a tensile strength at break of at least 25 MPa and an elongation at break of at least 1.75%).

Abstract translation: 描述了诸如亮度增强膜，包含有机组分和表面改性纳米颗粒的可聚合树脂组合物和表面改性纳米颗粒的微结构膜。 微结构膜具有包含可聚合树脂组合物的反应产物（例如折射率至少为1.58）的聚合结构。 固化的纳米复合材料（例如结构）可以显示出改进的抗裂性。 在一些实施例中，柔性通过圆柱形心轴弯曲测试性质（例如，心轴尺寸小于6mm的故障或心轴尺寸根据等式D = 1000（T / 0.025-T）而失效）来表示，其中 T是以（以预制的基层为单位）的毫米数的厚度，在其它实施例中，柔软性以拉伸和拉伸性能表示（例如，断裂时的拉伸强度至少为25MPa，断裂伸长率为at 至少1.75％）。

公开(公告)号：WO2010141345A1

公开(公告)日：2010-12-09

申请号：PCT/US2010/036547

申请日：2010-05-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  WALKER, Christopher B., Jr. ,  TEBOW, Christopher P. ,  PHAM, Tri D. ,  KONG, Steven H. ,  ARONSON, Joseph T. ,  LINDSTROM, Kyle J. ,  GERLACH, Michael K. ,  TOY, Michelle L. ,  MCKENZIE, Taun L. ,  RENSTROM, Anthony M. ,  JENDOUBI, Slah ,  JOHNSON, Mitchell A. F. ,  KAYTOR, Scott R. ,  YAPEL, Robert A. ,  ZIGAL, Joseph A. ,  MCMAN, Steven J. ,  SOLOMONSON, Steven D. ,  LU, Fei ,  BOYD, Gary T.

Inventor： WALKER, Christopher B., Jr. ,  TEBOW, Christopher P. ,  PHAM, Tri D. ,  KONG, Steven H. ,  ARONSON, Joseph T. ,  LINDSTROM, Kyle J. ,  GERLACH, Michael K. ,  TOY, Michelle L. ,  MCKENZIE, Taun L. ,  RENSTROM, Anthony M. ,  JENDOUBI, Slah ,  JOHNSON, Mitchell A. F. ,  KAYTOR, Scott R. ,  YAPEL, Robert A. ,  ZIGAL, Joseph A. ,  MCMAN, Steven J. ,  SOLOMONSON, Steven D. ,  LU, Fei ,  BOYD, Gary T.

IPC: G02B1/10 ,  G02F1/1335

CPC classification number: G02B5/02 ,  G02F1/133502 ,  G02F2202/36 ,  Y10T428/24355 ,  Y10T428/24372

Abstract: The present invention concerns antiglare films having a microstructured surface.

Abstract translation: 本发明涉及具有微结构化表面的防眩膜。

公开(公告)号：WO2009086079A2

公开(公告)日：2009-07-09

申请号：PCT/US2008/087641

申请日：2008-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KUMAR, Ramesh C. ,  MCKENZIE, Taun L. ,  LU, Ying-Yuh

Inventor： KUMAR, Ramesh C. ,  MCKENZIE, Taun L. ,  LU, Ying-Yuh

IPC: C08F220/18

CPC classification number: C09D143/04 ,  B82Y30/00 ,  C08F230/08 ,  C08F283/126 ,  C08F290/068 ,  C09J7/401 ,  C09J7/405 ,  C09J151/085 ,  C09J2400/163 ,  C09J2400/226 ,  C09J2400/263 ,  C09J2400/283 ,  C09J2429/005 ,  C09J2433/005 ,  C09J2483/005 ,  Y10T428/2848 ,  Y10T428/31663 ,  Y10T442/20

Abstract: A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) silicone macromer. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.

Abstract translation: 共聚物包含（a）（甲基）丙烯酸酯官能化纳米颗粒，（b）乙烯基单体和（c）硅氧烷大分子单体的反应产物。 （甲基）丙烯酸酯官能化纳米颗粒选自二氧化硅纳米颗粒，氧化锆纳米颗粒，二氧化钛纳米颗粒及其组合。

公开(公告)号：WO2009085926A2

公开(公告)日：2009-07-09

申请号：PCT/US2008/087385

申请日：2008-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KOLB, Brant U., ,  ANDERSON, Danny B., ,  DAVIDSON, Robert S., ,  HENDRICKSON, Mark J., ,  LEACH, James J., ,  MCKENZIE, Taun L.,

Inventor： KOLB, Brant U., ,  ANDERSON, Danny B., ,  DAVIDSON, Robert S., ,  HENDRICKSON, Mark J., ,  LEACH, James J., ,  MCKENZIE, Taun L.,

IPC: C01G25/02

CPC classification number: B01J19/0053 ,  B82Y30/00 ,  C01G25/02 ,  C04B35/486 ,  C04B35/6263 ,  C04B2235/3225 ,  C04B2235/449 ,  C04B2235/5454 ,  C04B2235/72

Abstract: A method of preparing zirconia-containing nanoparticles and a method of preparing a composite material that includes the zirconia-containing nanoparticles are provided. A method of treating a zirconium carboxylate salt solution to remove alkali metal ions and alkaline earth ions is provided. The treated solution can be used as a feedstock to prepare the zirconia-containing nanoparticles. Additionally, a continuous hydrothermal reactor system is provided that can be used, for example, to prepare the zirconia-containing nanoparticles.

Abstract translation: 提供了制备含氧化锆的纳米颗粒的方法和制备包含含氧化锆的纳米颗粒的复合材料的方法。 提供了一种处理羧酸锆盐溶液以除去碱金属离子和碱土离子的方法。 经处理的溶液可用作制备含氧化锆的纳米颗粒的原料。 另外，提供连续的水热反应器系统，其可以用于例如制备含氧化锆的纳米颗粒。

公开(公告)号：WO2009045752A3

公开(公告)日：2011-02-10

申请号：PCT/US2008076959

申请日：2008-09-19

Applicant: 3M INNOVATIVE PROPERTIES CO ,  KALGUTKAR RAJDEEP S ,  AMOS DAVID T ,  MCKENZIE TAUN L

Inventor： KALGUTKAR RAJDEEP S ,  AMOS DAVID T ,  MCKENZIE TAUN L

IPC: A61K6/083 ,  A61C7/12 ,  C08L33/00

CPC classification number: A61K6/0023 ,  A61C7/16 ,  A61K6/0008 ,  A61K6/0052 ,  A61K6/083 ,  C08L33/12 ,  C08L25/06 ,  C08L25/14 ,  C08L33/10

Abstract: Orthodontic adhesives are claimed which use polymeric filler particles with defined particle size characteristics. The particle size characteristics are controlled such that these adhesives provide comparable mechanical retention and cohesive strength of conventional orthodontic adhesives when used to bond orthodontic appliances to teeth. Because polymeric fillers are generally softer than inorganic fillers, these adhesives are easier to remove from the tooth than conventional adhesives after debonding an orthodontic appliance. Embodiments of the invention include both self-curing and two-part adhesives, packaged adhesive-coated orthodontic appliances, and methods for removing a cured adhesive from a tooth surface.

Abstract translation: 要求使用具有确定的粒度特性的聚合物填料颗粒的正畸粘合剂。 控制粒度特征，使得这些粘合剂当用于将正畸器具粘合到牙齿上时，提供了常规正畸粘合剂相当的机械保持性和内聚强度。 因为聚合物填料通常比无机填料柔软，因此在脱粘矫正器具之后，这些粘合剂比常规粘合剂更容易从牙齿上除去。 本发明的实施例包括自固化和两部分粘合剂，包装的粘合剂涂覆的正畸矫治器，以及从牙齿表面去除固化的粘合剂的方法。

公开(公告)号：WO2009085926A3

公开(公告)日：2010-08-26

申请号：PCT/US2008087385

申请日：2008-12-18

Applicant: 3M INNOVATIVE PROPERTIES CO ,  KOLB BRANT U ,  ANDERSON DANNY B ,  DAVIDSON ROBERT S ,  HENDRICKSON MARK J ,  LEACH JAMES J ,  MCKENZIE TAUN L

Inventor： KOLB BRANT U ,  ANDERSON DANNY B ,  DAVIDSON ROBERT S ,  HENDRICKSON MARK J ,  LEACH JAMES J ,  MCKENZIE TAUN L

IPC: C01G25/02 ,  C04B35/119

CPC classification number: B01J19/0053 ,  B82Y30/00 ,  C01G25/02 ,  C04B35/486 ,  C04B35/6263 ,  C04B2235/3225 ,  C04B2235/449 ,  C04B2235/5454 ,  C04B2235/72

Abstract: A method of preparing zirconia-containing nanoparticles and a method of preparing a composite material that includes the zirconia-containing nanoparticles are provided. A method of treating a zirconium carboxylate salt solution to remove alkali metal ions and alkaline earth ions is provided. The treated solution can be used as a feedstock to prepare the zirconia-containing nanoparticles. Additionally, a continuous hydrothermal reactor system is provided that can be used, for example, to prepare the zirconia-containing nanoparticles.

Abstract translation: 提供了制备含氧化锆的纳米粒子的方法和制备包含含氧化锆的纳米粒子的复合材料的方法。 提供了一种处理羧酸锆盐溶液以除去碱金属离子和碱土离子的方法。 经处理的溶液可用作制备含氧化锆的纳米颗粒的原料。 另外，提供连续的水热反应器系统，其可以用于例如制备含氧化锆的纳米颗粒。