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    PAINT COATING SYSTEM AND METHOD OF PRODUCING MULTILAYERED PAINT COATING
    1.
    发明申请
    PAINT COATING SYSTEM AND METHOD OF PRODUCING MULTILAYERED PAINT COATING 审中-公开
    涂料涂料体系和多层涂料涂料的制造方法

    公开(公告)号：WO2010149746A1

    公开(公告)日：2010-12-29

    申请号：PCT/EP2010/059009

    申请日：2010-06-24

    Applicant: BASF SE ,  OHRBOM, Walter H. ,  MENOVCIK, Gregory G. ,  MORMILE, Patrick J. ,  CAMPBELL, Donald H. ,  CRANFILL, David

    Inventor： OHRBOM, Walter H. ,  MENOVCIK, Gregory G. ,  MORMILE, Patrick J. ,  CAMPBELL, Donald H. ,  CRANFILL, David

    IPC: B05D1/36 ,  B05D7/00 ,  C09D4/00

    CPC classification number: B05D1/36 ,  B05D7/52 ,  C09D4/00 ,  Y10T428/31507 ,  Y10T428/31515 ,  Y10T428/31536

    Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

    Abstract translation: 涂料系统包括基材和设置在基材上的第一涂料层。 第一涂料层由包含第一解络剂或第一有机硼烷络合物的第一组合物形成。 涂料系统还包括设置在第一涂料层上的第二涂料层。 第二涂层由第二组合物形成，第二组合物包含第一解络剂和第一有机硼烷络合物中的另一种。 第一和第二组合物中的至少一种还包含自由基聚合性化合物。 制造多层涂料涂料的方法包括以下步骤：提供基材，在基材上施加第一涂料层，在第一涂料层上施加第二涂料层，并固化第一和第二涂料层中的至少一个。

    OLIGOMERS HAVING URETDIONE STRUCTURE, METHODS OF MAKING THEM, COATING COMPOSITIONS CONTAINING THEM, AND CURED COATINGS THEREOF
    2.
    发明申请
    OLIGOMERS HAVING URETDIONE STRUCTURE, METHODS OF MAKING THEM, COATING COMPOSITIONS CONTAINING THEM, AND CURED COATINGS THEREOF 审中-公开
    具有尿素结构的低聚物，其制备方法，包含它们的涂料组合物及其固化的涂料

    公开(公告)号：WO2010135093A1

    公开(公告)日：2010-11-25

    申请号：PCT/US2010/034041

    申请日：2010-05-07

    Applicant: BASF COATINGS GMBH ,  CAIOZZO, Nicholas ,  OHRBOM, Walter H. ,  CRANFILL, David C.

    Inventor： CAIOZZO, Nicholas ,  OHRBOM, Walter H. ,  CRANFILL, David C.

    IPC: C09D175/04 ,  C08G18/79 ,  C08G18/28 ,  C08G18/36 ,  C08G18/32 ,  C08G18/22 ,  C08G18/38

    CPC classification number: C08G18/3831 ,  C08G18/222 ,  C08G18/2815 ,  C08G18/3206 ,  C08G18/36 ,  C08G18/798 ,  C09D175/04 ,  C08L2666/16

    Abstract: An oligomer may be made by capping a uretdione compound of structure (I) wherein each R 1 is independently selected from alkylene groups having 1 to 12 carbon atoms, arylene groups having 5 to 12 carbon atoms, and arylalkylene and alkylarylene groups having 6 to 15 carbon atoms, wherein alkylene groups, alkylene portions of arylakylene groups, and alkyl portions of alkylarylene groups may be linear, branched, or cyclic with a compound having an active hydrogen and having a carbamate group or cyclic carbonate group the reaction being carried out under conditions in which the isocyanate groups but not the uretdione group of compound (I) react to form a compound (III), the compound (III) then being reacted with a reactant having at least two active hydrogens selected from polyols, polyamines having at least two amine groups selected from primary and secondary amine groups, and aminoalcohols having at least one amine group that is a primary or secondary amine group to form a product that is an oligomer. Any cyclic carbonate groups may be converted to carbamate groups. Also disclosed is an oligomer comprising repeating monomer units of structures in which n is an integer from 1 to 4 and R 1 is as previously defined. Also disclosed is a curable coating composition including at least one of the disclosed oligomers and at least one aminoplast resin crosslinker; a method of coating a substrate with the coating composition, a cured coating derived from the coating composition, and a coated substrate with the cured coating.

    Abstract translation: 低聚物可以通过将结构（I）的脲二酮化合物（其中每个R 1独立地选自具有1至12个碳原子的亚烷基，具有5至12个碳原子的亚芳基）和具有6至15个碳原子的芳基亚烷基和烷基亚芳基 原子，其中亚烷基，亚烷基的亚烷基部分和烷基亚芳基的烷基部分可以是具有活性氢的化合物，具有氨基甲酸酯基或环状碳酸酯基的直链，支链或环状的反应，其条件是 化合物（I）的异氰酸酯基团而不是脲二酮基团反应形成化合物（III），然后使化合物（III）与具有至少两个活性氢的反应物反应，所述活性氢选自多元醇，具有至少两个胺的多胺 选自伯胺基和仲胺基团的基团和具有至少一个胺基团的氨基醇，其是伯胺基或仲胺基团，以形成为 低聚物。 任何环状碳酸酯基团可以转化为氨基甲酸酯基团。 还公开了包含其中n为1至4的整数并且R 1如前所定义的结构的重复单体单元的低聚物。 还公开了包含至少一种所公开的低聚物和至少一种氨基塑料树脂交联剂的可固化涂料组合物; 用涂料组合物涂布基材的方法，衍生自涂料组合物的固化涂料和具有固化涂层的涂布基材。

    METHOD FOR OBTAINING COATING COMPOSITIONS HAVING REDUCED VOC
    5.
    发明申请
    METHOD FOR OBTAINING COATING COMPOSITIONS HAVING REDUCED VOC 审中-公开
    用于获得具有降低VOC的涂料组合物的方法

    公开(公告)号：WO2005123787A3

    公开(公告)日：2006-05-04

    申请号：PCT/US2005020611

    申请日：2005-06-10

    Applicant: BASF CORP ,  OHRBOM WALTER ,  GREEN MARVIN ,  MENOVCIK GREGORY

    Inventor： OHRBOM WALTER ,  GREEN MARVIN ,  MENOVCIK GREGORY

    IPC: C08F20/20 ,  C08F2/06 ,  C08F6/02 ,  C08F8/00 ,  C08F8/30 ,  C08G18/00 ,  C08G18/18 ,  C08G59/00 ,  C08G71/04 ,  C08L33/10 ,  C09D7/00 ,  C09D133/06 ,  C09D133/10 ,  C09D175/16 ,  C09D201/00

    CPC classification number: C08G71/04 ,  C08F2/06 ,  C08F6/02 ,  C08F8/00 ,  C08F2800/20 ,  C09D7/20 ,  C09D133/06 ,  C09D175/16 ,  C08L2666/16 ,  C08F220/20

    Abstract: Disclosed is a method of making reduced VOC polymers and coating compositions containing polymers. Provided is a mixture (I) comprising a reactant mixture (a) of polymerizable components and a nonvolatile solvent (bnv) that (i) is not a crystalline solid at 25°C, (ii) is nonvolatile, (iii) comprises at least one functional group (F1) and (iv) is a fluid solid. Reactant mixture (a) is polymerized to provide a polymer (a'). At least one functional group (F1) of nonvolatile solvent (bnv) is reacted with one or more reactants (e) to obtain a nonvolatile solvent (b'nv) comprising at least two functional groups (F2). Obtained is a mixture (II) comprising polymer (a') in nonvolatile solvent (b'nv) comprising at least two functional groups (F2). The at least one functional group (F1) is substantially nonreactive: (1) with the components of reactive mixture (a), (2) under the polymerization conditions which polymerize reactant mixture (a), and (3) with polymer (a').

    Abstract translation: 公开了一种制备含有聚合物的VOC聚合物和涂料组合物的方法。 提供了包含可聚合组分的反应物混合物（a）和不挥发性溶剂（bnv）的混合物（I），（i）在25℃下不是结晶固体，（ii）是非挥发性的，（iii）至少包含 一个官能团（F1）和（iv）是流体固体。 将反应物混合物（a）聚合以提供聚合物（a'）。 将不挥发性溶剂（bnv）的至少一个官能团（F1）与一种或多种反应物（e）反应，得到包含至少两个官能团（F2）的非挥发性溶剂（b'nv）。 获得的是包含至少两个官能团（F2）的非挥发性溶剂（b'nv）中的聚合物（a'）的混合物（II）。 至少一个官能团（F1）基本上是非反应性的：（1）在反应混合物（a）和（3）与聚合物（a'）聚合的聚合条件下，反应混合物（a），（2） ）。

    CARBAMATE FUNCTIONAL ADDITION POLYMERS AND A METHOD FOR THEIR PREPARATION
    7.
    发明申请
    CARBAMATE FUNCTIONAL ADDITION POLYMERS AND A METHOD FOR THEIR PREPARATION 审中-公开
    碳酸酯官能添加聚合物及其制备方法

    公开(公告)号：WO2006039013A1

    公开(公告)日：2006-04-13

    申请号：PCT/US2005/030248

    申请日：2005-08-26

    Applicant: BASF CORPORATION ,  OHRBOM, Walter ,  CAMPBELL, Donald ,  ST. AUBIN, Donald ,  RAMESH, Swaminathan ,  HARRIS, Paul ,  RÖCKRATH, Ulrike

    Inventor： OHRBOM, Walter ,  CAMPBELL, Donald ,  ST. AUBIN, Donald ,  RAMESH, Swaminathan ,  HARRIS, Paul ,  RÖCKRATH, Ulrike

    IPC: C08F20/00

    CPC classification number: C08F220/06 ,  C08F8/00 ,  C08F8/14 ,  C08F220/08 ,  C08F222/20 ,  C08F222/22 ,  C08L2312/00 ,  C09D133/14 ,  C09D201/025 ,  C08F265/06

    Abstract: Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C=C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C=C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.

    Abstract translation: 公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。 该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C = C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C = C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。 还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

    METHOD FOR IMPROVING ENVIRONMENTAL DURABILITY OF MATERIALS
    8.
    发明申请
    METHOD FOR IMPROVING ENVIRONMENTAL DURABILITY OF MATERIALS 审中-公开
    改善材料的环境耐久性的方法

    公开(公告)号：WO2005123782A2

    公开(公告)日：2005-12-29

    申请号：PCT/US2005/020610

    申请日：2005-06-10

    Applicant: BASF CORPORATION ,  OHRBOM, Walter ,  GREEN, Marvin ,  MENOVCIK, Gregory

    Inventor： OHRBOM, Walter ,  GREEN, Marvin ,  MENOVCIK, Gregory

    IPC: C08F

    CPC classification number: C08F4/28 ,  C08F2/06 ,  C08F2/52 ,  C08F2/56 ,  C08F4/04 ,  C09D175/04 ,  C09D201/02 ,  C09D201/025 ,  C08L2666/16

    Abstract: Disclosed is a method of making an environmentally durable material, the method requiring providing a material comprising at least one functional group Fc, and subjecting the material to a free radical source such that substantially all functional groups Fc are eliminated but the material is not polymerized. In one embodiment, the functional group Fc is at least one of a nonaromatic carbon-carbon double bond, a hydrogen atom alpha to an aromatic ring, a hydrogen atom alpha to a carbon-carbon double bond, or a hydrogen atom attached to a tertiary substituted carbon. In another embodiment, functional group Fc is present in the material as a contaminant. In one exemplary embodiment, the material comprises from 0.05 to less than 15 % by weight of functional group Fc, based on the total weight of the material.

    Abstract translation: 公开了一种制备环境耐久材料的方法，该方法需要提供包含至少一个官能团Fc的材料，并使材料经受自由基源，使得基本上所有的官能团Fc都被去除，但是材料没有聚合。 在一个实施方案中，官能团Fc是非芳族碳 - 碳双键，芳族环中的α，氢原子，碳 - 碳双键的氢原子或与叔碳原子连接的氢原子中的至少一种 取代碳。 在另一个实施方案中，官能团Fc作为污染物存在于材料中。 在一个示例性实施方案中，基于材料的总重量，该材料包含0.05至小于15重量％的官能团Fc。

    CURABLE COATING COMPOSITIONS CONTAINING REACTIVE COMPOUNDS HAVING A SECONDARY OR TERTIARY HYDROXY OR HALIDE GROUP SEPARATED FROM A PRIMARY CARBAMATE GROUP BY THREE OR MORE CARBON ATOMS
    9.
    发明申请
    CURABLE COATING COMPOSITIONS CONTAINING REACTIVE COMPOUNDS HAVING A SECONDARY OR TERTIARY HYDROXY OR HALIDE GROUP SEPARATED FROM A PRIMARY CARBAMATE GROUP BY THREE OR MORE CARBON ATOMS 审中-公开
    含有三级或更多碳原子从主要碳酸酯基分离的二级或更多羟基或卤化物的反应性化合物的可固化涂料组合物

    公开(公告)号：WO2004041949A8

    公开(公告)日：2005-03-24

    申请号：PCT/US0330294

    申请日：2003-09-24

    Applicant: BASF CORP GENERAL APPOINTMENT ,  OHRBOM WALTER ,  SCHANG CRAIG

    Inventor： OHRBOM WALTER ,  SCHANG CRAIG

    IPC: C08G18/28 ,  C08G18/38 ,  C09D175/04 ,  C09D201/02 ,  C09D7/12

    CPC classification number: C09D175/04 ,  C08G18/285 ,  C08G18/3831 ,  C09D201/025 ,  Y10T428/31529 ,  Y10T428/31663 ,  C08L2666/16 ,  C08L2666/02 ,  C08L2666/28

    Abstract: Provided is a curable coating composition comprising a reactive compound having one or more structures of the formula: X-Cn(R1)(R2)-C(R0)(Y)-Cn'(R3)(R4)(R5) wherein X is a primary carbamate group, Y is a hydroxy or halide group, n is an integer of 2 or more, n' is an integer of 1 or more, and R0, R1, R2, R3, R4 and R5 may be H or a group selected from alkyl groups, aliphatic groups, cycloaliphatic groups, aromatic groups and mixtures thereof, with the provisos that at least one R1 or R2 group is selected from the group consisting of aliphatic groups, cycloaliphatic groups, aromatic groups, and mixtures thereof, and in substantially all structures primary carbamate group X is attached to a carbon atom having a lower degree of substitution than a carbon atom to which functional group Y is attached.

    Abstract translation: 提供一种可固化涂料组合物，其包含具有一个或多个下式的结构的反应性化合物：X-Cn（R1）（R2）-C（R0）（Y）-Cn'（R3）（R4）（R5）其中X 是主要的氨基甲酸酯基团，Y是羟基或卤化物基团，n是2以上的整数，n'是1以上的整数，R 0，R 1，R 2，R 3，R 4和R 5可以是H或 选自烷基，脂族基团，脂环族基团，芳族基团及其混合物的基团，条件是至少一个R 1或R 2基团选自脂族基团，脂环族基团，芳族基团及其混合物，以及 在基本上所有结构中，主要氨基甲酸酯基团X连接到具有低于官能团Y所连接的碳原子的取代度低的碳原子。

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