CATALYST AND METHOD OF CATALYST MANUFACTURE
    1.
    发明申请
    CATALYST AND METHOD OF CATALYST MANUFACTURE 审中-公开
    催化剂制造的催化剂和方法

    公开(公告)号:WO2011080515A2

    公开(公告)日:2011-07-07

    申请号:PCT/GB2010052203

    申请日:2010-12-23

    Abstract: The catalyst of the invention is a particulate catalyst in the form of particles having a minimum dimension of at least 0.8 mm, comprising a transition metal or a compound thereof dispersed on a porous support material, characterised in that said catalyst particles comprise at least 35% w/w total transition metal; and the transition metal surface area of said catalyst is at least 110 m2 per gram of transition metal and the tapped bulk density of a bed of the catalyst particles is at least 0.7 g/ml. The method of making a catalyst includes multiple steps of impregnation of a porous support with a metal ammine solution followed by drying, calcination and reduction of the dried material. The catalyst is useful in hydrogenation reactions.

    Abstract translation: 本发明的催化剂是颗粒状催化剂,其颗粒形式为最小尺寸至少为0.8mm,包含分散在多孔载体材料上的过渡金属或其化合物,其特征在于所述催化剂颗粒包含至少35% w / w总过渡金属; 并且所述催化剂的过渡金属表面积为每克过渡金属至少110m 2,并且催化剂颗粒床的振实堆积密度为至少0.7g / ml。 制备催化剂的方法包括用金属氨溶液浸渍多孔载体然后干燥,煅烧和还原干燥材料的多个步骤。 该催化剂可用于氢化反应。

    POLYMERISATION REACTION AND CATALYST THEREFOR
    3.
    发明申请
    POLYMERISATION REACTION AND CATALYST THEREFOR 审中-公开
    聚合反应和催化剂

    公开(公告)号:WO2004052980A1

    公开(公告)日:2004-06-24

    申请号:PCT/GB2003/005386

    申请日:2003-12-10

    Abstract: The invention provides a compound suitable for use as a catalyst for ring opening polymerisation reactions for example for the polymerisation of lactones, lactides etc, the catalyst comprising the reaction product of (i) an alkoxide, halide, condensed alkoxide, amide, condensed amide, mixed halo-alkoxide or, mixed halo-amide, sulphonic acid derivative, sulphonamide, silanol or silylamide of titanium zirconium, hafnium or aluminium or a mixture thereof, and (ii) a complexing compound selected from the list comprising oximes, hydroxy-Schiff bases, 8-hydroxyquinoline derivatives, 10-hydroxybenzo-[h]-quinoline derivatives, hydrazones and substituted phenols.

    Abstract translation: 本发明提供了一种适于用作开环聚合反应的催化剂的化合物,例如用于内酯,丙交酯等的聚合,所述催化剂包含(i)醇盐,卤化物,稠合醇盐,酰胺,缩合酰胺, 混合的卤代醇盐或混合的卤代酰胺,磺酸衍生物,磺酰胺,钛锆,铪或铝或其混合物的硅烷醇或甲硅烷基酰胺,和(ii)选自肟,羟基 - 席夫碱 ,8-羟基喹啉衍生物,10-羟基苯并 - [h] - 喹啉衍生物,腙和取代酚。

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