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1.发明申请CATALYST FOR METATHESIS OF ETHYLENE AND 2-BUTENE AND/OR DOUBLE BOND ISOMERIZATION 审中-公开用于乙烯和2-丁烯和/或双键异构化的催化剂
公开(公告)号：WO2011011173A2
公开(公告)日：2011-01-27
申请号：PCT/US2010040528
申请日：2010-06-30
CPC分类号： C07C5/2512 , B01J21/08 , B01J21/10 , C07C6/04 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/16 , C07C2523/02 , C07C2523/04 , C07C2523/30 , Y02P20/52 , C07C11/08 , C07C11/06
摘要： A process for the double-bond isomerization of olefins is disclosed. The process may include contacting a fluid stream comprising olefins with a fixed bed comprising an activated basic metal oxide isomerization catalyst to convert at least a portion of the olefin to its isomer. The isomerization catalysts disclosed herein may have a reduced cycle to cycle deactivation as compared to conventional catalysts, thus maintaining higher activity over the complete catalyst life cycle.
摘要翻译： 公开了烯烃双键异构化的方法。 该方法可以包括使包含烯烃的流体流与包含活化的碱性金属氧化物异构化催化剂的固定床接触以将至少一部分烯烃转化为其异构体。 与常规催化剂相比，本文公开的异构化催化剂可以具有降低的循环失活循环，因此在整个催化剂寿命周期内保持较高的活性。
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公开(公告)号：WO2010019595A3
公开(公告)日：2010-05-27
申请号：PCT/US2009053432
申请日：2009-08-11
CPC分类号： C07C11/06 , C07C4/06 , C07C6/04 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/30 , C07C2529/00 , C07C2529/40 , Y02P20/52
摘要： A process for the production of propylene, the process including: fractionating a hydrocarbon stream comprising n-butenes, isobutylene, and paraffins into at least two fractions including a light C4 fraction comprising isobutylene and a heavy C4 fraction comprising n-butenes and paraffins; contacting at least a portion of the heavy C4 fraction with a metathesis catalyst to form a metathesis product comprising ethylene, propylene, C4+ olefins, and paraffins; fractionating the metathesis product into at least four fractions including an ethylene fraction, a propylene fraction, a C4 fraction comprising C4 olefins and paraffins, and a C5+ fraction; cracking the light C4 fraction and the C5+ fraction to produce a cracking product comprising ethylene, propylene, and heavier hydrocarbons; and fractionating the cracking product into at least two fractions including a light fraction comprising propylene and a fraction comprising C5 to C6 hydrocarbons.
摘要翻译： 一种生产丙烯的方法，该方法包括：将包含正丁烯，异丁烯和链烷烃的烃流分馏成至少两个馏分，包括含有异丁烯的轻馏分C4馏分和包含正丁烯和链烷烃的重C4馏分; 使至少一部分重C4馏分与复分解催化剂接触以形成包含乙烯，丙烯，C 4 +烯烃和链烷烃的复分解产物; 将复分解产物分馏成至少四个馏分，包括乙烯馏分，丙烯馏分，包含C4烯烃和石蜡的C4馏分和C5 +馏分; 裂解光C4馏分和C5 +级分以产生包含乙烯，丙烯和较重烃的裂化产物; 并将裂化产物分馏成至少两个馏分，包括包含丙烯的轻馏分和包含C5至C6烃的馏分。
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公开(公告)号：WO2012087704A2
公开(公告)日：2012-06-28
申请号：PCT/US2011/064873
申请日：2011-12-14
CPC分类号： B01J37/0009 , B01J21/066 , B01J21/10 , B01J21/16 , B01J23/10 , B01J35/002 , C07C5/2512 , C07C2521/06 , C07C2521/10 , C07C2521/14 , C07C2521/16 , C07C2523/10 , C07C11/08
摘要： Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt% to about 20 wt%. Exemplaiy stabilizers include one or more of Zr02, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 \vt%. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.
摘要翻译： 公开了包含MgO，金属硅酸盐粘土粘合剂和稳定剂的挤出异构化催化剂以及形成这种异构化催化剂的方法。 还公开了异构化催化剂，其表现出新鲜异构化速率和老化异构化速率，其为新鲜异构化速率的至少50％。 本文公开的异构化催化剂的实施方案包括包含层状结构和金属硅酸盐的金属硅酸盐粘土粘合剂。 金属硅酸盐粘土粘合剂可以以约5重量％至约20重量％的量存在。 示例性稳定剂包括ZrO 2，四价稀土金属和三价稀土金属中的一种或多种。 稳定剂可以以高达约40％vt％的量存在。 催化剂制品表现出一种或多种改进的性能，如碎片强度和异构化性能。
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公开(公告)号：WO2011011173A3
公开(公告)日：2011-01-27
申请号：PCT/US2010/040528
申请日：2010-06-30
申请人： LUMMUS TECHNOLOGY INC. , RAMACHANDRAN, Bala , CHOI, Sukwon , GARTSIDE, Robert, J. , GREENE, Marvin, I.
摘要： A process for the double-bond isomerization of olefins is disclosed. The process may include contacting a fluid stream comprising olefins with a fixed bed comprising an activated basic metal oxide isomerization catalyst to convert at least a portion of the olefin to its isomer. The isomerization catalysts disclosed herein may have a reduced cycle to cycle deactivation as compared to conventional catalysts, thus maintaining higher activity over the complete catalyst life cycle.
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公开(公告)号：WO2005101649A3
公开(公告)日：2007-02-22
申请号：PCT/US2005012334
申请日：2005-04-12
发明人： RAMACHANDRAN BALA , VASA JOHN E
CPC分类号： H03F1/30 , H03F2200/294 , H03F2200/331 , H03F2200/372 , H04B1/30
摘要： A system and method for direct current offset correction are disclosed. One embodiment of the system includes a direct current offset correction circuitry (240a, 240b) having an adjustable bandwidth and control logic (119) configured to effect a bandwidth change of the direct current offset correction circuitry to speed up warm-up and settling time of the direct current offset correction circuitry.
摘要翻译： 公开了用于直流偏移校正的系统和方法。 该系统的一个实施例包括具有可调节带宽的控制逻辑（119）的直流偏移校正电路（240a，240b）和用于实现直流偏移校正电路的带宽变化的控制逻辑（119），以加速预热和稳定时间 直流偏移校正电路。
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公开(公告)号：WO2005046098A1
公开(公告)日：2005-05-19
申请号：PCT/US2004/033050
申请日：2004-10-07
发明人： RAMACHANDRAN, Bala , LOKE, Aravind
IPC分类号： H04H1/00
CPC分类号： H03D3/00 , H04B1/707 , H04L27/0008
摘要： A multi-mode receiver system (200a-200c) for processing signals based on a plurality of systems is disclosed. Embodiments of the invention provide for a shared architecture (212a-212c) for processing baseband signals (209, 221, 239, 241, 261, 265, 273, 275) corresponding to a plurality of systems (201, 233, 253, 267).
摘要翻译： 公开了一种用于处理基于多个系统的信号的多模式接收机系统（200a-200c）。 本发明的实施例提供了一种用于处理对应于多个系统（201,233,253,267）的基带信号（209,221,239,241,261,265,273,275）的共享架构（212a-212c） 。
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公开(公告)号：WO2012087704A3
公开(公告)日：2012-08-16
申请号：PCT/US2011064873
申请日：2011-12-14
申请人： BASF CORP , RUETINGER WOLFGANG , MOINI AHMAD , RAMACHANDRAN BALA , CHOI SUKWON
CPC分类号： B01J37/0009 , B01J21/066 , B01J21/10 , B01J21/16 , B01J23/10 , B01J35/002 , C07C5/2512 , C07C2521/06 , C07C2521/10 , C07C2521/14 , C07C2521/16 , C07C2523/10 , C07C11/08
摘要： Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt% to about 20 wt%. Exemplaiy stabilizers include one or more of Zr02, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 \vt%. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.
摘要翻译： 公开了包含MgO，金属硅酸盐粘土粘合剂和稳定剂的挤出异构化催化剂和形成这种异构化催化剂的方法。 还公开了异构化催化剂，其表现出新异构化速率和至少为新异构化速率的50％的陈化异构化速率。 本文公开的异构化催化剂的实施方式包括包含层状结构和金属硅酸盐的金属硅酸盐粘土粘合剂。 金属硅酸盐粘土粘合剂可以以约5重量％至约20重量％的量存在。 示例性稳定剂包括ZrO 2，四价稀土金属和三价稀土金属中的一种或多种。 稳定剂可以以高达约40％的量存在。 该催化剂制品表现出一种或多种改进的性能，例如片压碎强度和异构化性能。
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公开(公告)号：WO2006016967A1
公开(公告)日：2006-02-16
申请号：PCT/US2005/021152
申请日：2005-06-15
申请人： ABB LUMMUS GLOBAL INC. , RAMACHANDRAN, Bala , KRAUS, Martin , SHAN, Zhiping , ANGEVINE, Philip, J.
IPC分类号： C10G49/02
CPC分类号： C10G65/12 , B01J29/0308 , B01J29/041 , B01J35/002 , B01J35/0066 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , C10G45/36 , C10G45/40 , C10G45/48 , C10G45/52 , C10G45/54 , C10G47/00
摘要： A process for the hydrogenation of a hydrocarbon feed containing unsaturated components includes providing a catalyst including at least one noble metal on a noncrystalline, mesoporous inorganic oxide support having at least 97 volume percent interconnected mesopores based upon mesopores and micropores, a BET surface area of at least 300 m 2 /g and a pore volume of at least 0.3 cm 3 /g; and, contacting the hydrocarbon feed with hydrogen in the presence of said catalyst under hydrogenation reaction conditions.
摘要翻译： 含有不饱和组分的烃进料的氢化方法包括在非结晶的中孔无机氧化物载体上提供包含至少一种贵金属的催化剂，其具有基于介孔和微孔的至少97体积％的相互连接的介孔，BET表面积 至少300m 2 / g，孔体积至少为0.3cm 3 / g; 并且在氢化反应条件下，在所述催化剂存在下，使烃进料与氢气接触。
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公开(公告)号：WO2010028267A3
公开(公告)日：2010-03-11
申请号：PCT/US2009/056076
申请日：2009-09-04
申请人： LUMMUS TECHNOLOGY INC. , BASF CATALYSTS LLC , RAMACHANDRAN, Bala , CHOI, Sukwon , GARTSIDE, Robert, J. , KLEINDIENST, Shane , RUETTINGER, Wolfgang , ALERASOOL, Saeed
发明人： RAMACHANDRAN, Bala , CHOI, Sukwon , GARTSIDE, Robert, J. , KLEINDIENST, Shane , RUETTINGER, Wolfgang , ALERASOOL, Saeed
摘要： A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization- metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, HA, HB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1 -butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
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公开(公告)号：WO2010028267A2
公开(公告)日：2010-03-11
申请号：PCT/US2009056076
申请日：2009-09-04
申请人： LUMMUS TECHNOLOGY INC , BASF CATALYSTS LLC , RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
发明人： RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
CPC分类号： B01J27/236 , B01J23/007 , B01J23/30 , B01J35/0006 , B01J37/0201 , B01J37/04 , C07C5/2512 , C07C6/04 , C07C2521/04 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/24 , Y02P20/52 , C07C11/08 , C07C11/06
摘要： A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization- metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, HA, HB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1 -butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
摘要翻译： 一种生产丙烯的方法，所述方法包括：使乙烯和包含1-丁烯和2-丁烯的烃流与双功能异构化复分解催化剂接触以同时异构化1-丁烯成2-丁烯并形成复分解产物，所述复分解产物包含 丙烯; 其中所述双功能异构化复分解催化剂包含：催化剂化合物可包括选自钨，钽，铌，钼，镍，钯，锇，铱，铑，钒，钌和铼中的至少一种元素， 包含至少一种元素周期表IA，IIA，IIB和IIIA族元素的载体; 其中载体的暴露表面积为1-丁烯异构化为2-丁烯提供了异构化活性; 和用于吸附催化剂化合物毒物的反应位点。 在其他实施方案中，催化剂化合物可以包括选自铝，镓，铱，铁，钼，镍，铌，锇，钯，磷，铼，铑，钌，钽，钛，钨和钒中的至少一种元素。
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