公开(公告)号：WO2012087704A2

公开(公告)日：2012-06-28

申请号：PCT/US2011/064873

申请日：2011-12-14

申请人： BASF CORPORATION ,  RUETINGER, Wolfgang ,  MOINI, Ahmad ,  RAMACHANDRAN, Bala ,  CHOI, Sukwon

发明人： RUETINGER, Wolfgang ,  MOINI, Ahmad ,  RAMACHANDRAN, Bala ,  CHOI, Sukwon

IPC分类号： B01J21/10 ,  B01J21/06 ,  C01F5/02 ,  C07C11/09

CPC分类号： B01J37/0009 ,  B01J21/066 ,  B01J21/10 ,  B01J21/16 ,  B01J23/10 ,  B01J35/002 ,  C07C5/2512 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2521/16 ,  C07C2523/10 ,  C07C11/08

摘要： Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt% to about 20 wt%. Exemplaiy stabilizers include one or more of Zr02, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 \vt%. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.

摘要翻译： 公开了包含MgO，金属硅酸盐粘土粘合剂和稳定剂的挤出异构化催化剂以及形成这种异构化催化剂的方法。 还公开了异构化催化剂，其表现出新鲜异构化速率和老化异构化速率，其为新鲜异构化速率的至少50％。 本文公开的异构化催化剂的实施方案包括包含层状结构和金属硅酸盐的金属硅酸盐粘土粘合剂。 金属硅酸盐粘土粘合剂可以以约5重量％至约20重量％的量存在。 示例性稳定剂包括ZrO 2，四价稀土金属和三价稀土金属中的一种或多种。 稳定剂可以以高达约40％vt％的量存在。 催化剂制品表现出一种或多种改进的性能，如碎片强度和异构化性能。

公开(公告)号：WO2012018719A3

公开(公告)日：2012-05-24

申请号：PCT/US2011046108

申请日：2011-08-01

申请人： BASF CORP ,  LOEWENSTEIN MICHAEL A ,  MOINI AHMAD ,  PETROVIC IVAN

发明人： LOEWENSTEIN MICHAEL A ,  MOINI AHMAD ,  PETROVIC IVAN

IPC分类号： B01J29/04 ,  B01J23/42 ,  B01J37/08 ,  C10G3/00 ,  C10L1/02

CPC分类号： B01J29/7461 ,  B01J23/40 ,  B01J23/755 ,  B01J23/892 ,  B01J29/7469 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/85 ,  B01J37/0201 ,  B01J37/088 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G45/02 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  C10G2400/10 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20

摘要： Provided are hydiOisomerization catalysts for processing a bio-based feedstock into biodiesel fuels. These catalysts comprise a catalytic material and a matrix component. The catalytic material is made up of a molecular sieve that has a pre-loaded platinum group metal. The catalytic material and the matrix component are processed together to form the hydroisomerization catalyst. Methods of malting these hydroisomerization catalysts include synthesizing a molecular sieve; purifying the molecular sieve; associating the molecular sieve with a platinum group metal in the absence of the matrix component to form the pre-loaded molecular sieve before formation of a catalyst body; mixing the pre-loaded molecular sieve with the matrix component to form a mixture; processing the mixture to form a catalyst body; and drying and calcining the catalyst body to form the hydroisomerization catalyst. These hydroisomerization catalysts can be used to process hydrodeoxygenated plant- or animal- derived feeds to yield a biofuel.

摘要翻译： 提供用于将生物基原料加工成生物柴油燃料的高温异构化催化剂。 这些催化剂包含催化材料和基质组分。 催化材料由具有预载铂族金属的分子筛组成。 催化材料和基质组分一起加工形成加氢异构化催化剂。 使这些加氢异构化催化剂发麦的方法包括合成分子筛; 纯化分子筛; 在不存在基体组分的情况下将分子筛与铂族金属缔合以在形成催化剂体之前形成预加载分子筛; 将预加载的分子筛与基质组分混合以形成混合物; 处理该混合物以形成催化剂体; 干燥并煅烧催化剂体以形成加氢异构化催化剂。 这些加氢异构化催化剂可用于处理加氢脱氧的植物或动物衍生的饲料以产生生物燃料。

公开(公告)号：WO2012018719A2

公开(公告)日：2012-02-09

申请号：PCT/US2011/046108

申请日：2011-08-01

申请人： BASF CORPORATION ,  LOEWENSTEIN, Michael, A. ,  MOINI, Ahmad ,  PETROVIC, Ivan

发明人： LOEWENSTEIN, Michael, A. ,  MOINI, Ahmad ,  PETROVIC, Ivan

IPC分类号： B01J29/04 ,  B01J23/42 ,  C10G3/00 ,  C10L1/02 ,  B01J37/08

CPC分类号： B01J29/7461 ,  B01J23/40 ,  B01J23/755 ,  B01J23/892 ,  B01J29/7469 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/85 ,  B01J37/0201 ,  B01J37/088 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G45/02 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  C10G2400/10 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20

摘要： Provided are hydiOisomerization catalysts for processing a bio-based feedstock into biodiesel fuels. These catalysts comprise a catalytic material and a matrix component. The catalytic material is made up of a molecular sieve that has a pre-loaded platinum group metal. The catalytic material and the matrix component are processed together to form the hydroisomerization catalyst. Methods of malting these hydroisomerization catalysts include synthesizing a molecular sieve; purifying the molecular sieve; associating the molecular sieve with a platinum group metal in the absence of the matrix component to form the pre-loaded molecular sieve before formation of a catalyst body; mixing the pre-loaded molecular sieve with the matrix component to form a mixture; processing the mixture to form a catalyst body; and drying and calcining the catalyst body to form the hydroisomerization catalyst. These hydroisomerization catalysts can be used to process hydrodeoxygenated plant- or animal- derived feeds to yield a biofuel.

摘要翻译： 提供用于将生物基原料加工成生物柴油燃料的水解异构化催化剂。 这些催化剂包括催化材料和基质组分。 催化材料由具有预加载的铂族金属的分子筛组成。 将催化材料和基体组分一起加工以形成加氢异构化催化剂。 这些加氢异构化催化剂的发酵方法包括合成分子筛; 净化分子筛; 在不存在基质组分的情况下使分子筛与铂族金属缔合，在形成催化剂体之前形成预加载的分子筛; 将预加载的分子筛与基质组分混合以形成混合物; 处理混合物以形成催化剂体; 并干燥和煅烧催化剂体以形成加氢异构化催化剂。 这些加氢异构化催化剂可用于处理加氢脱氧植物或动物来源的饲料以产生生物燃料。

公开(公告)号：WO2010054034A3

公开(公告)日：2010-05-14

申请号：PCT/US2009/063331

申请日：2009-11-05

申请人： BASF CATALYSTS LLC ,  BULL, Ivor ,  MOINI, Ahmad ,  RAI, Mukta

发明人： BULL, Ivor ,  MOINI, Ahmad ,  RAI, Mukta

IPC分类号： B01J29/70 ,  B01J29/76 ,  B01J29/74 ,  B01J37/30 ,  B01D53/56

摘要： Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.

公开(公告)号：WO2008036813A2

公开(公告)日：2008-03-27

申请号：PCT/US2007079024

申请日：2007-09-20

申请人： BASF CATALYSTS LLC ,  KOERMER GERALD STEPHEN ,  MOINI AHMAD ,  FURBECK HOWARD ,  CASTELLANO CHRISTOPHER R

发明人： KOERMER GERALD STEPHEN ,  MOINI AHMAD ,  FURBECK HOWARD ,  CASTELLANO CHRISTOPHER R

IPC分类号： B01D53/94 ,  B01J23/40 ,  B01J23/50 ,  F01N3/08

CPC分类号： B01D53/9418 ,  B01D2251/208 ,  B01D2255/102 ,  B01D2255/104 ,  B01D2255/9155 ,  B01D2258/012 ,  B01J21/04 ,  B01J23/50 ,  B01J35/006 ,  Y02T10/24 ,  Y10T428/24149

摘要： Catalysts, systems and methods are described to reduce NOx emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver on a particulate alumina support, the silver having a diameter of less than about 20 nm. Methods of manufacturing catalysts are described in which ionic silver is impregnated on particulate hydroxylated alumina particles.

摘要翻译： 描述了催化剂，系统和方法以减少内燃机的NOx排放。 在一个实施方案中，提供了一种用于排气流的排放物处理系统，其具有在颗粒状氧化铝载体上含有银的催化剂，银的直径小于约20nm。 描述了制造催化剂的方法，其中离子银浸渍在颗粒羟基化氧化铝颗粒上。

公开(公告)号：WO2008036803A2

公开(公告)日：2008-03-27

申请号：PCT/US2007079004

申请日：2007-09-20

申请人： BASF CATALYSTS LLC ,  GEN MOTORS CORP ,  CASTELLANO CHRISTOPHER R ,  MOINI AHMAD ,  KOERMER GERALD STEPHEN ,  FURBECK HOWARD ,  SCHMIEG STEVEN J ,  BLINT RICHARD J

发明人： CASTELLANO CHRISTOPHER R ,  MOINI AHMAD ,  KOERMER GERALD STEPHEN ,  FURBECK HOWARD ,  SCHMIEG STEVEN J ,  BLINT RICHARD J

IPC分类号： B01D53/94 ,  B01J23/40 ,  B01J23/50 ,  F01N3/08

CPC分类号： B01D53/9418 ,  B01D2251/208 ,  B01D2255/1021 ,  B01D2255/104 ,  B01D2255/9155 ,  B01D2258/012 ,  B01J23/50 ,  B01J37/0201 ,  B01J37/0242 ,  B01J37/10 ,  Y02T10/24

摘要： Catalysts, systems and methods are described to reduce NO x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.

摘要翻译： 描述了催化剂，系统和方法以减少内燃机的NO x排放。 在一个实施方案中，提供了一种用于排气流的排放物处理系统，其具有包含在颗粒状氧化铝载体上的银和铂族金属的催化剂，铂族金属的原子分数小于或等于约0.25。 描述了制造催化剂的方法，其中银被浸渍在氧化铝颗粒上。

公开(公告)号：WO2012047649A3

公开(公告)日：2012-04-12

申请号：PCT/US2011/053458

申请日：2011-09-27

申请人： BASF CORPORATION ,  FURBECK, Howard ,  MOINI, Ahmad

发明人： FURBECK, Howard ,  MOINI, Ahmad

IPC分类号： B01J23/68 ,  B01D53/94 ,  B01D53/56

摘要： The present disclosure provides an AgBi catalyst over alumina suitable for performing hydrocarbon selective catalytic reduction (HC-SCR).

公开(公告)号：WO2011073390A3

公开(公告)日：2011-09-22

申请号：PCT/EP2010070077

申请日：2010-12-17

申请人： BASF CORP ,  BEUTEL TILMAN ,  DIETERLE MARTIN ,  BULL IVOR ,  MUELLER ULRICH ,  MOINI AHMAD ,  BREEN MICHAEL ,  SLAWSKI BARBARA ,  ALERASOOL SAEED

发明人： BEUTEL TILMAN ,  DIETERLE MARTIN ,  BULL IVOR ,  MUELLER ULRICH ,  MOINI AHMAD ,  BREEN MICHAEL ,  SLAWSKI BARBARA ,  ALERASOOL SAEED

IPC分类号： B01J29/76 ,  B01D53/86 ,  B01D53/94 ,  B01J37/02 ,  B01J37/30 ,  C10G11/18

CPC分类号： B01J29/763 ,  B01D53/8628 ,  B01D53/8634 ,  B01D53/9418 ,  B01D53/944 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2257/402 ,  B01D2258/012 ,  B01J37/0036 ,  B01J37/0228 ,  B01J37/0246 ,  B01J37/30 ,  C10G11/18 ,  C10G11/187 ,  C10G2300/70 ,  Y02C20/10

摘要： Disclosed are processes for the preparation of copper containing molecular sieves with the CHA structure having a silica to alumina mole ratio greater than about 10, wherein the copper exchange step is conducted via wet state exchanged and prior to the coating step and wherein in the copper exchange step a liquid copper solution is used wherein the concentration of copper is in the range of about 0.001 to about 0.25 molar using copper acetate and/or an ammoniacal solution of copper ions as copper source. Catalysts made by the processes, catalyst systems and methods of treating exhaust gas with the molecular sieves and catalysts are also disclosed.

摘要翻译： 公开了具有二氧化硅/氧化铝摩尔比大于约10的CHA结构的含铜分子筛的方法，其中铜交换步骤通过湿态交换并在涂布步骤之前进行，并且其中在铜交换 使用其中使用乙酸铜和/或作为铜源的铜离子的氨溶液，铜的浓度在约0.001至约0.25摩尔范围内的液体铜溶液。 还公开了通过方法制备的催化剂，催化剂体系和用分子筛和催化剂处理废气的方法。

公开(公告)号：WO2012087704A3

公开(公告)日：2012-08-16

申请号：PCT/US2011064873

申请日：2011-12-14

申请人： BASF CORP ,  RUETINGER WOLFGANG ,  MOINI AHMAD ,  RAMACHANDRAN BALA ,  CHOI SUKWON

发明人： RUETINGER WOLFGANG ,  MOINI AHMAD ,  RAMACHANDRAN BALA ,  CHOI SUKWON

IPC分类号： B01J21/10 ,  B01J21/06 ,  C01F5/02 ,  C07C11/09

CPC分类号： B01J37/0009 ,  B01J21/066 ,  B01J21/10 ,  B01J21/16 ,  B01J23/10 ,  B01J35/002 ,  C07C5/2512 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2521/16 ,  C07C2523/10 ,  C07C11/08

摘要： Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt% to about 20 wt%. Exemplaiy stabilizers include one or more of Zr02, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 \vt%. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.

摘要翻译： 公开了包含MgO，金属硅酸盐粘土粘合剂和稳定剂的挤出异构化催化剂和形成这种异构化催化剂的方法。 还公开了异构化催化剂，其表现出新异构化速率和至少为新异构化速率的50％的陈化异构化速率。 本文公开的异构化催化剂的实施方式包括包含层状结构和金属硅酸盐的金属硅酸盐粘土粘合剂。 金属硅酸盐粘土粘合剂可以以约5重量％至约20重量％的量存在。 示例性稳定剂包括ZrO 2，四价稀土金属和三价稀土金属中的一种或多种。 稳定剂可以以高达约40％的量存在。 该催化剂制品表现出一种或多种改进的性能，例如片压碎强度和异构化性能。

公开(公告)号：WO2008106519A1

公开(公告)日：2008-09-04

申请号：PCT/US2008/055140

申请日：2008-02-27

申请人： BASF CATALYSTS LLC ,  BULL, Ivor ,  BOORSE, R. Samuel ,  JAGLOWSKI, William M. ,  KOERMER, Gerald Stephen ,  MOINI, Ahmad ,  PATCHETT, Joseph A. ,  XUE, Wen-mei ,  BURK, Patrick ,  DETTLING, Joseph Charles ,  CAUDLE, Matthew Tyler

发明人： BULL, Ivor ,  BOORSE, R. Samuel ,  JAGLOWSKI, William M. ,  KOERMER, Gerald Stephen ,  MOINI, Ahmad ,  PATCHETT, Joseph A. ,  XUE, Wen-mei ,  BURK, Patrick ,  DETTLING, Joseph Charles ,  CAUDLE, Matthew Tyler

IPC分类号： B01J29/072 ,  B01J29/76 ,  B01D53/00

CPC分类号： B01D53/9418 ,  B01D2251/206 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9155 ,  B01D2258/012 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/072 ,  B01J29/723 ,  B01J29/763 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0246 ,  Y02T10/24 ,  Y10T428/24149

摘要： Zeolite catalysts, systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15 : 1 to about 256 : 1 and a copper to alumina ratio from about 0.25 : 1 to about 1 : 1.

摘要翻译： 公开了用于制备和使用具有CHA晶体结构的沸石催化剂的沸石催化剂，体系和方法。 催化剂可用于在宽温度范围内从气态介质中除去氮氧化物，并在高反应温度下表现出水热稳定性。 沸石催化剂包括具有约15:1至约256:1的二氧化硅与氧化铝的沸石载体，铜与氧化铝的比例为约0.25:1至约1:1。