公开(公告)号：WO2010043011A8

公开(公告)日：2010-07-29

申请号：PCT/BR2009000321

申请日：2009-10-16

Applicant: RM MATERIAIS REFRATARIOS LTDA ,  GARCIA PINATTI DALTRO ,  OLIVEIRA ISAIAS ,  GUEDES SOARES ALVARO ,  ROMAO ERICA LEONOR ,  FERREIRA JOAO CARLOS

Inventor： GARCIA PINATTI DALTRO ,  OLIVEIRA ISAIAS ,  GUEDES SOARES ALVARO ,  ROMAO ERICA LEONOR ,  FERREIRA JOAO CARLOS

IPC: C10B53/00 ,  B09C1/06 ,  C09C1/48 ,  C10B47/16 ,  C10B53/07

CPC classification number: C10B47/16 ,  C01P2006/80 ,  C09C1/482 ,  C10B53/00 ,  C10B53/07 ,  F23G5/027 ,  Y02P20/143 ,  Y02P20/145

Abstract: The present invention refers to a Low Temperature Conversion apparatus composed of tri-tubes which simultaneously carries out the functions of vessel and heat exchanger. This apparatus is capable of thermally decomposing any kind of organic material to obtain coal, oil, water and non-condensable gases, and also decontaminating soils and residues contaminated with organochlorides and dioxins. The apparatus is used for thermal decomposition of any kind of organic material and comprises: an outer box (2) with a hermetic lid (19); a thermal insulation layer (5) disposed throughout the inner surface of the outer box (2) and lid, said apparatus also comprising at least a structure with three concentric tubes disposed internally, positioned substantially vertically and with a wall width suitable for heating by means of gases from an inner side and outer side of said structure. The invention also refers to a process for thermal decomposition of any kind of organic material using the apparatus of the present invention and comprises the steps of feeding the organic material into the apparatus; heating with gases on the inside and outside of an annular region located in the concentric tubes inside the apparatus; processing with extraction and condensation of oil; cooling with gases; and tilting of the apparatus.

Abstract translation: 本发明涉及由同时执行容器和热交换器功能的三管组成的低温转换设备。 该设备能够热分解任何有机材料以获得煤，油，水和不可冷凝的气体，并且还净化污染有机氯和二恶英的污垢和残留物。 该设备用于任何种类的有机材料的热分解，并包括：具有气密盖（19）的外箱（2）; 一个设置在外箱（2）和盖的整个内表面上的隔热层（5），所述设备还包括至少一个具有三个同心管的结构，所述同心管设置在内部，基本竖直定位并具有适于通过装置 的来自所述结构的内侧和外侧的气体。 本发明还涉及使用本发明的设备对任何种类的有机材料进行热分解的方法，并包括将有机材料进料到设备中的步骤; 用位于设备内同心管内的环形区域的内侧和外侧的气体加热; 用油萃取和冷凝加工; 用气体冷却; 并倾斜设备。

公开(公告)号：WO2010043011A3

公开(公告)日：2010-09-30

申请号：PCT/BR2009000321

申请日：2009-10-16

Applicant: RM MATERIAIS REFRATARIOS LTDA ,  GARCIA PINATTI DALTRO ,  OLIVEIRA ISAIAS ,  GUEDES SOARES ALVARO ,  ROMAO ERICA LEONOR ,  FERREIRA JOAO CARLOS

Inventor： GARCIA PINATTI DALTRO ,  OLIVEIRA ISAIAS ,  GUEDES SOARES ALVARO ,  ROMAO ERICA LEONOR ,  FERREIRA JOAO CARLOS

IPC: C10B53/00 ,  B09C1/06 ,  C09C1/48 ,  C10B47/16 ,  C10B53/07

CPC classification number: C10B47/16 ,  C01P2006/80 ,  C09C1/482 ,  C10B53/00 ,  C10B53/07 ,  F23G5/027 ,  Y02P20/143 ,  Y02P20/145

Abstract: The present invention refers to a Low Temperature Conversion apparatus composed of tri-tubes which simultaneously carries out the functions of vessel and heat exchanger. This apparatus is capable of thermally decomposing any kind of organic material to obtain coal, oil, water and non-condensable gases, and also decontaminating soils and residues contaminated with organochlorides and dioxins. The apparatus is used for thermal decomposition of any kind of organic material and comprises: an outer box (2) with a hermetic lid (19); a thermal insulation layer (5) disposed throughout the inner surface of the outer box (2) and lid, said apparatus also comprising at least a structure with three concentric tubes disposed internally, positioned substantially vertically and with a wall width suitable for heating by means of gases from an inner side and outer side of said structure. The invention also refers to a process for thermal decomposition of any kind of organic material using the apparatus of the present invention and comprises the steps of feeding the organic material into the apparatus; heating with gases on the inside and outside of an annular region located in the concentric tubes inside the apparatus; processing with extraction and condensation of oil; cooling with gases; and tilting of the apparatus.

Abstract translation: 本发明涉及一种由同时实现容器和热交换器功能的三管组成的低温转化装置。 该设备能够热分解任何种类的有机材料，以获得煤，油，水和不可冷凝气体，以及净化有机氯和二恶英污染的污垢和残留物。 该装置用于任何种类的有机材料的热分解，并包括：具有密封盖（19）的外箱（2）; 设置在外箱（2）和盖子的整个内表面的隔热层（5），所述设备还至少包括一个内部布置的三个同心管的结构，该三个同心管基本垂直地设置，并具有适于通过装置加热的壁宽 的气体来自所述结构的内侧和外侧。 本发明还涉及使用本发明的装置对任何种类的有机材料进行热分解的方法，包括将有机材料进料到装置中的步骤; 在位于设备内的同心管内的环形区域的内部和外部加热气体; 用油提取和冷凝处理; 用气体冷却; 和倾斜的装置。

公开(公告)号：WO02051561A3

公开(公告)日：2003-04-03

申请号：PCT/IB0102356

申请日：2001-12-07

Applicant: RM MATERIAIS REFRATARIOS LTDA ,  ROMAO ERICA LEONOR ,  GARCIA PINATTI DALTRO ,  GUEDES SOARES ALVARO

Inventor： ROMAO ERICA LEONOR ,  GARCIA PINATTI DALTRO ,  GUEDES SOARES ALVARO

IPC: C13K1/02 ,  C13K13/00 ,  B09B3/00 ,  C10B53/00 ,  C10G1/00 ,  E01H15/00

CPC classification number: C13K13/002 ,  C13K1/02 ,  Y02E50/32

Abstract: The present invention relates to the average composition of urban waste, composed of plastics, paper, metal, glass, organic material of Municipal Solid Waste (OMMSW), ashes, batteries and humidity contents. OMMSW has been subjected to acidic prehydrolysis (2.5 % of H2SO4 on the dry matter), a prehydrolysate of 12 % of sugars and cellulignin with 12 % of ashes being obtained. Since the OMMSW contains only 30 % of dry matter, one has concluded that the economicity of the process defined as weight of solid matter by cubic meter of reactor improves with the mixture of 50 % of OMMSW and 50 % of biomass (wood, grass, agricultural residues, etc.). With this technique one has achieved 300kg of dry biomass/m3 (DB) of reactor. This requirement is not limiting, since the biomass may be supplied by planting trees in the urban perimeter or planting 1ha of grass for each 1000 inhabitants in the cities surroundings.

Abstract translation: 本发明涉及由塑料，纸，金属，玻璃，城市固体废物（OMMSW）的有机材料，灰烬，电池和湿度成分组成的城市垃圾的平均组成。 OMMSW已经进行酸性预水解（干物质上的2.5％的H 2 SO 4），得到12％的糖和纤维素的预水解酯和12％的灰分。 由于OMMSW仅含有30％的干物质，因此得出结论，定义为立方米反应堆固体物质重量的过程的经济性随着OMMSW的50％和生物量的50％（木材，草坪， 农业残留物等）。 通过这种技术，已经实现了300kg的干生物量/ m3（DB）的反应器。 这个要求不是限制性的，因为生物量可以通过在城市周边种植树木或在城市周围的每1000个居民种植1公顷的草来提供。

公开(公告)号：WO0078446A3

公开(公告)日：2001-11-08

申请号：PCT/BR0000065

申请日：2000-06-23

Applicant: RM MATERIAIS REFRATARIOS LTDA ,  GARCIA PINATTI DALTRO ,  GUEDES SOARES ALVARO

Inventor： GARCIA PINATTI DALTRO ,  GUEDES SOARES ALVARO

IPC: B09B3/00 ,  B01J3/00 ,  B01J3/02 ,  B01J3/04 ,  B01J19/02 ,  B01J19/28 ,  C08H8/00 ,  C13K1/02 ,  C13K13/00

CPC classification number: B01J19/02 ,  B01J19/0073 ,  B01J19/285 ,  B01J2219/00256 ,  B01J2219/0236 ,  B01J2219/0286 ,  C13K1/02 ,  C13K13/002 ,  Y02E50/16 ,  Y02E50/30

Abstract: This invention refers to an apparatus for the processing of pre-hydrolysis of biomass, particularly a reactor of the failsafe type, either mobile or not, which may be manufactured of microbonded carbon steel and coated with special materials (refractory metals, superalloys, stainless materials, plastics, etc.). The insertion of vacuum between the shell of the reactor and its coating prevents its implosion and permits the detection of leakage with helium gas. The resistance to corrosion of the refractory metals enables carrying out of pre-hydrolysis and mineral digestion. In the process of this invention, biomass is compacted at 300 kg/m by a helical feeder, degased, flooded, heated, stirred, pre-hydrolyzed, the sugar being recovered at a first washing within the reactor with values higher than 90 %. The low liquid/solid ratio = 2 enables one to achieve sugar content of 10 bricks in the pre-hydrolysate and a consumption of 6 % of the energy contained in the processed biomass. The pre-hydrolysate is constituted by solutions of xylose and others and is intended for the production of furfural, alcohol and xylitol. The control of the process enables one to produce cellulignin with a high specific surface, 2 m /g (measured by BET), compared with the value of 0.4 m /g of non-hydrolyzed biomass, maintain crystallinity of the cellulose fibers, aiming at grinding it into fine particles (f

Abstract translation: 本发明涉及一种用于处理生物质的预水解的设备，特别是可移动或不可移动的故障安全型反应器，其可以由微结构碳钢制成并涂覆有特殊材料（难熔金属，超合金，不锈钢材料 ，塑料等）。 在反应器的壳体和其涂层之间插入真空防止其内爆，并允许用氦气检测泄漏。 难熔金属的耐腐蚀性能够进行预水解和矿物质消解。 在本发明的方法中，生物质通过螺旋进料器，脱气，淹没，加热，搅拌，预水解，以300kg / m 3压实，反应器中第一次洗涤回收糖，值高于 90％。 低液/固比= 2使得能够在预水解产物中实现10砖的糖含量和消耗处理过的生物质中所含能量的6％。 预水解产物由木糖等构成，用于生产糠醛，醇和木糖醇。 该方法的控制使得能够产生具有高比表面积（2m 2 / g（通过BET测量））的蛋白质，与0.4m 2 / g非水解生物质的值相比，保持结晶度 纤维素纤维，旨在将其研磨成细颗粒（f <）250mm），使木质素球化，将纤维素暴露于微生物或酶发酵中的反刍动物，真菌，细菌或酶的微生物侵袭。 由于大的比表面积的催化燃烧导致用于锅炉，一般的燃烧器和用过滤水生产的MHD的新燃料，以及当用去离子水生产时用于燃气轮机。