CATALYST PROPERTY CONTROL WITH INTERMIXED INORGANICS
    3.
    发明申请
    CATALYST PROPERTY CONTROL WITH INTERMIXED INORGANICS 审中-公开
    催化剂物理控制与无机无机

    公开(公告)号:WO2010124196A3

    公开(公告)日:2011-03-03

    申请号:PCT/US2010032217

    申请日:2010-04-23

    CPC classification number: H01M4/921 H01M4/925 H01M2008/1095

    Abstract: Nanostructured thin film catalysts which may be useful as fuel cell catalysts are provided, the catalyst materials including intermixed inorganic materials. In some embodiments the nanostructured thin film catalysts may include catalyst materials according to the formula PtxMn(1-x)where x is between 0.3 and 0.9 and M is Nb, Bi, Re, Hf, Cu or Zr. The nanostructured thin film catalysts may include catalyst materials according to the formula PtaCobMc where a+b+c=1, a is between 0.3 and 0.9, b is greater than 0.05, c is greater than 0.05, and M is Au, Zr, or Ir. The nanostructured thin film catalysts may include catalyst materials according to the formula PtaTibQc where a+b+c=l, a is between 0.3 and 0.9, b is greater than 0.05, c is greater than 0.05, and Q is C or B.

    Abstract translation: 提供可用作燃料电池催化剂的纳米结构薄膜催化剂,催化剂材料包括混合的无机材料。 在一些实施方案中,纳米结构薄膜催化剂可以包括根据式PtxMn(1-x)的催化剂材料,其中x在0.3和0.9之间,M是Nb,Bi,Re,Hf,Cu或Zr。 纳米结构薄膜催化剂可以包括根据式PtaCobMc的催化剂材料,其中a + b + c = 1,a在0.3和0.9之间,b大于0.05,c大于0.05,M是Au,Zr或 铱。 纳米结构薄膜催化剂可以包括根据式PtaTibQc的催化剂材料,其中a + b + c = 1,a在0.3和0.9之间,b大于0.05,c大于0.05,Q是C或B.

    CATHODE COMPOSITIONS FOR LITHIUM-ION ELECTROCHEMICAL CELLS
    5.
    发明申请
    CATHODE COMPOSITIONS FOR LITHIUM-ION ELECTROCHEMICAL CELLS 审中-公开
    锂离子电化学电池的阴极组合物

    公开(公告)号:WO2011025751A3

    公开(公告)日:2011-06-30

    申请号:PCT/US2010046404

    申请日:2010-08-24

    CPC classification number: H01M4/582 H01M4/58 H01M10/0525

    Abstract: Compositions useful for cathodes in lithium-ion batteries are described. In some examples, an electrochemical cell includes an electrode, the electrode comprising a composition including the elements of Li, Fe, and F, where the composition includes a first phase including a disordered trirutile structure. Cathodes including such a composition may exhibit reversible reactivity with lithium. In some examples, this reaction takes place via an intercalation mechanism.

    Abstract translation: 描述了用于锂离子电池阴极的组合物。 在一些实例中,电化学电池包括电极,所述电极包含含有Li,Fe和F的元素的组合物,其中所述组合物包含含有无序三分结构的第一相。 包含这种组合物的阴极可以表现出与锂的可逆反应性。 在一些实例中,该反应通过嵌入机制发生。

    REDOX SHUTTLE FOR OVERDISCHARGE PROTECTION IN RECHARGEABLE LITHIUM-ION BATTERIES
    9.
    发明申请
    REDOX SHUTTLE FOR OVERDISCHARGE PROTECTION IN RECHARGEABLE LITHIUM-ION BATTERIES 审中-公开
    可充电锂离子电池中的超重保护用氧化锌

    公开(公告)号:WO2005099025A3

    公开(公告)日:2006-07-20

    申请号:PCT/US2005010903

    申请日:2005-03-31

    Abstract: A battery of series-connected rechargeable lithium ion cells each of which contains a negative electrode; a negative electrode current collector; a positive electrode; a positive electrode current collector; and an electrolyte comprising charge carrying medium, lithium salt and cyclable redox chemical shuttle. The negative electrode has a larger irreversible first cycle capacity loss than that of the positive electrode, and is driven to a potential above that of the positive electrode if the cell is discharged to a state of cell reversal. The shuttle has an electrochemical potential above the positive electrode maximum normal operating potential, and prevents the negative electrode potential from reaching even higher and more destructive positive values during overdischarge. The current collector has a lithium alloying potential below the negative electrode minimum normal operating potential. The battery chemically limits or eliminates cell damage due to repeated overdischarge, and may operate without electronic overdischarge protection circuitry.

    Abstract translation: 一组串联的可再充电锂离子电池,每个锂离子电池含有负极; 负极集电体; 正极; 正极集电体; 以及包含电荷载体,锂盐和可循环氧化还原化学穿梭的电解质。 负极具有比正极更大的不可逆的第一循环容量损失,并且如果电池被放电到电池反转的状态,则被驱动到比正极的电位高的电位。 梭子具有高于正电极最大正常工作电位的电化学电位,并且防止负极电极在过放电期间达到甚至更高和更具破坏性的正值。 集电器的锂合金电位低于负极最小正常工作电位。 电池由于重复的过度放电而化学地限制或消除电池损坏,并且可以在没有电子过放电保护电路的情况下工作。

    RECHARGEABLE LITHIUM-ION CELL WITH TRIPHENYLAMINE REDOX SHUTTLE
    10.
    发明申请
    RECHARGEABLE LITHIUM-ION CELL WITH TRIPHENYLAMINE REDOX SHUTTLE 审中-公开
    可再充电的锂离子电池与三苯胺氧化还原梭

    公开(公告)号:WO2007097912A2

    公开(公告)日:2007-08-30

    申请号:PCT/US2007003174

    申请日:2007-02-05

    Abstract: Provided is a rechargeable lithium-ion cell that contains a positive electrode, a negative electrode, a charge-carrying electrolyte containing a charge carrying medium and a lithium salt, and a triphenylamine compound dissolved in or dissolvable in the electrolyte. The triphenylamine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection. Also provided are methods for manufacturing a rechargeable lithium-ion cell.

    Abstract translation: 本发明提供一种可再充电锂离子电池,其包含正极,负极,含有电荷传输介质和锂盐的带电荷电解质以及溶解于或溶解于电解质中的三苯胺化合物。 三苯胺化合物具有高于正极再充电电位的氧化电势,并用作提供电池过充电保护的可循环氧化还原化学梭。 还提供了用于制造可再充电锂离子电池的方法。

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