公开(公告)号：WO2009035844A3

公开(公告)日：2009-03-19

申请号：PCT/US2008/074188

申请日：2008-08-25

Applicant: CATALYTIC DISTILLATION TECHNOLOGIES ,  BOYER, Christopher, C. ,  LOESCHER, Mitchell, E. ,  ROCK, Kerry, L. ,  GROTEN, Willibrord, A. ,  MARASCHINO, Mario, J.

Inventor： BOYER, Christopher, C. ,  LOESCHER, Mitchell, E. ,  ROCK, Kerry, L. ,  GROTEN, Willibrord, A. ,  MARASCHINO, Mario, J.

IPC: C07C41/05 ,  C07C43/03

Abstract: A process for the production of tertiary ethers, including: feeding a hydrocarbon stream comprising isoolefins and propionitrile to a distillation column reactor system containing at least one etherification reaction zone; feeding a C2 to C6 monoalcohol or mixture thereof to the distillation column reactor; concurrently in the distillation column reactor system: reacting a portion of the isoolefins with a portion of the alcohols to form a tertiary ether; and separating the tertiary ether from unreacted isoolefins; withdrawing the tertiary ether and propionitrile from the distillation column reactor system as a bottoms; withdrawing the unreacted isoolefins from the distillation column reactor system as an overheads; and operating the distillation column reactor system such that the etherification reaction zone is substantially free of propionitrile.

公开(公告)号：WO2010021771A1

公开(公告)日：2010-02-25

申请号：PCT/US2009/044418

申请日：2009-05-19

Applicant: CATALYTIC DISTILLATION TECHNOLOGIES ,  ROCK, Kerry, L. ,  BOYER, Christopher, C. ,  SMITH, Lawrence, A.

Inventor： ROCK, Kerry, L. ,  BOYER, Christopher, C. ,  SMITH, Lawrence, A.

IPC: C07C2/66 ,  C07B31/00 ,  B01J29/00 ,  C10L1/16

CPC classification number: C10G29/205 ,  C10G2300/1096 ,  C10G2300/4081 ,  C10G2400/02

Abstract: A process for reducing benzene content in a reformate stream, including: fractionating a full range reformate comprising benzene, C 7 to C 9 monoalkyl aromatics, and C 1O+ polyalkyl aromatics into at least three fractions including a light reformate fraction comprising the benzene; a medium reformate fraction comprising the C 7 to C 9 monoalkyl aromatics; and a heavy reformate fraction comprising the C 10+ polyalkyl aromatics; feeding the light reformate fraction, the heavy reformate fraction and a transalkylation catalyst to a transalkylation reaction zone; contacting the light fraction and the heavy fraction in presence of the transalkylation catalyst in the transalkylation reaction zone to react at least a portion of the benzene with C 1O+ polyalkyl aromatics to form monoalkyl aromatics; separating an effluent from the transalkylation reaction zone to form a catalyst fraction and a liquid fraction comprising the monoalkyl aromatics.

Abstract translation: 一种用于还原重整产物流中苯含量的方法，包括：将包含苯，C 7至C 9单烷基芳烃和C 10+多烷基芳族化合物的全范围重整产物分馏成至少三个馏分，包括包含苯的轻重油馏分; 包含C7-C9单烷基芳族化合物的中等重整油馏分; 和包含C10 +多烷基芳烃的重质重质馏分; 将轻重整油馏分，重质量重馏分和烷基转移催化剂加入烷基转移反应区; 在烷基转移反应区中在烷基转移催化剂存在下使轻馏分和重馏分接触，使至少一部分苯与C 1-10烷基芳族化合物反应形成单烷基芳族化合物; 分离来自烷基转移反应区的流出物以形成催化剂级分和包含单烷基芳族化合物的液体级分。

公开(公告)号：WO2009099848A2

公开(公告)日：2009-08-13

申请号：PCT/US2009/032310

申请日：2009-01-29

Applicant: CATALYTIC DISTILLATION TECHNOLOGIES ,  XIONG, Yi-Gang ,  ROCK, Kerry, L. ,  JUDZIS, Arvids ,  LOESCHER, Mitchell, E.

Inventor： XIONG, Yi-Gang ,  ROCK, Kerry, L. ,  JUDZIS, Arvids ,  LOESCHER, Mitchell, E.

IPC: C10L1/18 ,  C10G11/00 ,  C10G7/00

CPC classification number: C10L1/1852 ,  C10G2300/30 ,  C10G2300/305 ,  C10L1/023

Abstract: A fuel or fuel blendstock comprising ethanol, ethyl ethers, olefins, and alkanes. In some embodiments, the fuel or fuel blendstock of claim 1, wherein the fuel or fuel blendstock may have an octane number greater than 92 (RON + M0N)/2). In other embodiments, the fuel or fuel blendstock may have a Reid vapor pressure less than 7.2 psi. Also disclosed is a process for the production of a fuel, the process including: contacting ethanol and at least one gasoline fraction including alkanes and olefins in the presence of a catalyst to form a fuel mixture including ethyl ethers, alkanes, unreacted olefins, and unreacted ethanol; and recovering the fuel mixture for use as a gasoline or gasoline blendstock without separation of the ethanol from the fuel mixture.

Abstract translation: 包含乙醇，乙醚，烯烃和烷烃的燃料或燃料混合料。 在一些实施方案中，权利要求1的燃料或燃料混合原料，其中所述燃料或燃料混合原料可具有大于92（RON + M0N）/ 2的辛烷值。 在其它实施方案中，燃料或燃料混合原料可具有小于7.2psi的Reid蒸气压。 还公开了一种生产燃料的方法，该方法包括：在催化剂存在下使乙醇和至少一种包含烷烃和烯烃的汽油馏分接触，形成包括乙醚，烷烃，未反应烯烃和未反应的燃料混合物 乙醇; 以及回收燃料混合物以用作汽油或汽油混合料，而不将乙醇与燃料混合物分离。

公开(公告)号：WO2006049673A2

公开(公告)日：2006-05-11

申请号：PCT/US2005/029395

申请日：2005-08-18

Applicant: CATALYTIC DISTILLATION TECHNOLOGIES

Inventor： ROCK, Kerry, L. ,  XOING, Yi-Gang ,  JUDZIS, Arvids, Jr.

IPC: C10G31/00 ,  C10G67/16

CPC classification number: C10G45/00 ,  C10G2400/02

Abstract: A process for the production of low sulfur, low olefin gasoline wherein a cracked naphtha, such as a full boiling range cracked naphtha, is first separated by fractional distillation into at least two fractions while simultaneously selectively hydrogenating the polyunsaturated compounds contained therein. The mono olefins in the light fraction are then subjected to etherification with alcohol to produce ethers or hydration with water to produce alcohols. The heavy fraction is subjected to sulfur removal by hydrodesulfurization or chemisorption. The two fractions are then combined to produce a low sulfur, low olefin gasoline.

Abstract translation: 一种生产低硫低烯烃汽油的方法，其中裂解石脑油，例如全沸点裂化石脑油首先通过分馏分离成至少两个馏分，同时选择性地氢化其中所含的多不饱和化合物。 然后将轻馏分中的单烯烃与醇进行醚化，以产生醚或与水合成以产生醇。 重馏分通过加氢脱硫或化学吸附进行除硫。 然后将两个级分组合以产生低硫，低烯烃汽油。

公开(公告)号：WO2004069775A2

公开(公告)日：2004-08-19

申请号：PCT/US2003/041473

申请日：2003-12-30

Applicant: CATALYTIC DISTILLATION TECHNOLOGIES

Inventor： GROTEN, Willibrord, A. ,  ROCK, Kerry, L.

IPC: C07C

CPC classification number: C10G49/002 ,  C10G2400/02

Abstract: A process for the production of low benzene content gasoline is disclosed wherein a full boiling range naphtha is fractionated to produce a light naphtha, a medium naphtha and a heavy naphtha. The benzene is contained in the medium naphtha and this stream is subjected to hydrogenation to convert the benzene to cyclohexane which may be isomerized to improve the octane. The valuable olefins are removed in the light naphtha and the valuable heavier aromatics (toluene and xylenes) are removed in the heavy naphtha. In a preferred embodiment all of the reactions are carried out in distillation column reactors.

Abstract translation: 公开了一种生产低苯含量汽油的方法，其中将全沸程石脑油分馏以产生轻石脑油，中等石脑油和重石脑油。 苯被包含在中等石脑油中，该物流进行氢化，将苯转化为可被异构化以改善辛烷值的环己烷。 在轻石脑油中除去有价值的烯烃，并在重质石脑油中除去有价值的较重芳族化合物（甲苯和二甲苯）。 在优选的实施方案中，所有反应都在蒸馏塔反应器中进行。