公开(公告)号：WO2005039765A1

公开(公告)日：2005-05-06

申请号：PCT/EP2004/010958

申请日：2004-10-01

Applicant: DEGUSSA AG ,  MAYER, Ralf ,  WOLF, Dorit ,  DINGERDISSEN, Uwe

Inventor： MAYER, Ralf ,  WOLF, Dorit ,  DINGERDISSEN, Uwe

IPC: B01J37/08

CPC classification number: F27B7/04 ,  F27B7/34 ,  F27B7/42 ,  F27B2007/041

Abstract: A rotary kiln in which several tubes which can be heated independently are arranged in a drum. The rotary kiln can be used for the parallel thermal treatment of materials.

Abstract translation: 一个回转窑，其中可以独立加热的多个管子被布置在滚筒中。 回转窑可用于材料的平行热处理。

公开(公告)号：WO2005058499A1

公开(公告)日：2005-06-30

申请号：PCT/EP2004/013145

申请日：2004-11-19

Applicant: DEGUSSA AG ,  MAYER, Ralf ,  FISCHER, Achim ,  WOLF, Dorit ,  KOHLE, Norbert ,  DINGERDISSEN, Uwe

Inventor： MAYER, Ralf ,  FISCHER, Achim ,  WOLF, Dorit ,  KOHLE, Norbert ,  DINGERDISSEN, Uwe

IPC: B01J37/32

CPC classification number: B01J37/32 ,  B01J19/0046 ,  B01J37/031 ,  B01J2219/00283 ,  B01J2219/00306 ,  B01J2219/00416 ,  B01J2219/00488 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/00691 ,  B01J2219/00745 ,  B01J2219/00747 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14

Abstract: Process and device for the preparation of inorganic materials, in which salt solutions and solids are mixed with one another and a solid is precipitated out by addition of a further salt solution, the suspension is frozen and the solvent is removed. The solid can be investigated for its catalytic properties.

Abstract translation: 制备无机材料的方法和装置，其中盐溶液和固体彼此混合，固体通过加入另外的盐溶液沉淀出来，将悬浮液冷冻并除去溶剂。 可以研究固体的催化性能。

公开(公告)号：WO2005040705A2

公开(公告)日：2005-05-06

申请号：PCT/EP2004/010959

申请日：2004-10-01

Applicant: DEGUSSA AG ,  MAYER, Ralf ,  WOLF, Dorit ,  DINGERDISSEN, Uwe

Inventor： MAYER, Ralf ,  WOLF, Dorit ,  DINGERDISSEN, Uwe

IPC: F27B5/02

CPC classification number: F27B5/02 ,  F27D19/00 ,  F27D21/0014 ,  F27D2019/0006

Abstract: Muffle furnace consisting of a furnace, a perforated plate at the base of the interior, a structure which divides the interior of the furnace into chambers; a further perforated plate beneath the cover of the furnace. It is used for the heat treatment of materials, a gas or gas mixture being fed before, during and/or after the heat treatment into the chambers through the perforated plate beneath the cover and being fed from the chambers through the perforated plate at the base.

Abstract translation: 马弗炉由炉子，内部底部的多孔板，将炉内分成多个腔室的结构组成， 在炉盖下方的另一个多孔板。 它用于材料的热处理，气体或气体混合物在热处理之前，期间和/或之后通过盖下面的多孔板进入腔室，并从腔室通过底部的多孔板

公开(公告)号：WO2014147188A1

公开(公告)日：2014-09-25

申请号：PCT/EP2014/055626

申请日：2014-03-20

Applicant: EVONIK INDUSTRIES AG ,  FOUNDATION FOR RESEARCH AND TECHNOLOGY - HELLAS ,  WOLF, Dorit ,  BORRMANN, Rüdiger ,  AZAP, Cengiz ,  VAMVAKAKI, Maria ,  PASPARAKIS, George

Inventor： WOLF, Dorit ,  BORRMANN, Rüdiger ,  AZAP, Cengiz ,  VAMVAKAKI, Maria ,  PASPARAKIS, George

IPC: B01J31/16 ,  B01J31/22 ,  B01J31/24

CPC classification number: B01J31/1658 ,  B01J31/2273 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/16 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/842 ,  B01J2531/847

Abstract: The present invention relates to a catalyst comprising (a) a polymer, which has a weight-average molecular weight in the range of from 1000 g/mol –100000 g/mol and which polymer comprises 50 wt-% -99.9 wt-% ofunits derived from one or more non-functionalized monomeric units A, 0.1 wt-% -50 wt-% of units derived from one or more monomeric units B, 0wt-% - 30 wt-% of units derived from one or more cross-linking monomeric units C; wherein monomeric units A are selected from (meth) acrylates and monomers co-polymerizable with (meth) acrylates; wherein monomeric units B are selected from hydroxyl-functionalized (meth) acrylates and monomers copolymerizable with (meth) acrylates,which are esterified with one or more suitable precursors of phosphorousand/or nitrogen containing uncharged electron donors as coordinative groups; and wherein cross-linking monomeric units C are selected from compounds which compriseat least two olefinically unsaturated double bondsco-polymerizable with A and/or B, and (b) a catalytically-active metal compound that is bound to one or more phosphorous and/or nitrogen containing uncharged electron donors of said polymer. Furthermore, the invention relates to corresponding polymers to afore-mentioned catalyst, a process for producing the catalyst and the polymer as well as the use of the catalyst in homogeneous and/or heterogeneous catalysis.

Abstract translation: 本发明涉及一种催化剂，其包含（a）聚合物，其重均分子量在1000g / mol -100000g / mol范围内，该聚合物包含50wt％-99.9wt％的单元 衍生自一个或多个非官能化单体单元A，0.1重量％-50重量％的衍生自一个或多个单体单元B的单元，0重量％-30重量％的衍生自一个或多个交联的单元 单体单元C; 其中单体单元A选自（甲基）丙烯酸酯和与（甲基）丙烯酸酯共聚的单体; 其中单体单元B选自羟基官能化的（甲基）丙烯酸酯和可与（甲基）丙烯酸酯共聚的单体，其与一种或多种含磷和/或氮的不含电荷的电子给体的合适的前体作为配位基酯化; 并且其中交联单体单元C选自包含与A和/或B可共聚的至少两个烯属不饱和双键的化合物，和（b）与一个或多个磷和/或其结合的催化活性金属化合物 含有所述聚合物的不含电荷的电子给体的氮。 此外，本发明涉及与前述催化剂相关的聚合物，制备催化剂和聚合物的方法以及催化剂在均相和/或多相催化中的用途。

公开(公告)号：WO2008098830A1

公开(公告)日：2008-08-21

申请号：PCT/EP2008/050950

申请日：2008-01-28

Applicant: EVONIK DEGUSSA GMBH ,  WOLF, Dorit ,  RIERMEIER, Thomas ,  DRAUZ, Karlheinz ,  WEBER, Christoph

Inventor： WOLF, Dorit ,  RIERMEIER, Thomas ,  DRAUZ, Karlheinz ,  WEBER, Christoph

IPC: B01J31/22 ,  C07C209/24

CPC classification number: B01J31/226 ,  B01J2231/44 ,  B01J2231/641 ,  B01J2531/824 ,  C07B2200/07 ,  C07C209/26 ,  C07C211/27

Abstract: Catalyst systems consisting of supported or unsupported transition metal catalysts which have modifiers on the surface. The modifiers have sulphur-containing functionalities (G 0 ). In addition, the modifiers may have a spacer (Sp) and a Bronsted-basic, Bronsted-acidic or Lewis-basic functionality (G 1 ). The catalyst systems may be used for hydrogenation, reductive alkylation and reductive amination.

Abstract translation: 由负载或未负载的过渡金属催化剂组成的催化剂体系，其表面具有改性剂。 改性剂具有含硫官能团（G 0 O）。 此外，改性剂可以具有间隔物（Sp）和布朗斯台德碱性，布朗斯特 - 酸性或路易斯碱性官能团（G 1 N 1）。 催化剂体系可用于氢化，还原烷基化和还原胺化。

公开(公告)号：WO2014147192A1

公开(公告)日：2014-09-25

申请号：PCT/EP2014/055632

申请日：2014-03-20

Applicant: EVONIK INDUSTRIES AG ,  FOUNDATION FOR RESEARCH AND TECHNOLOGY - HELLAS ,  WOLF, Dorit ,  BORRMANN, Rüdiger ,  AZAP, Cengiz ,  VAMVAKAKI, Maria ,  PASPARAKIS, George

Inventor： WOLF, Dorit ,  BORRMANN, Rüdiger ,  AZAP, Cengiz ,  VAMVAKAKI, Maria ,  PASPARAKIS, George

IPC: B01J31/16 ,  B01J31/24 ,  B01J31/22

CPC classification number: B01J31/1658 ,  B01J31/2273 ,  B01J31/2404 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/16 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/842 ,  B01J2531/847

Abstract: The present invention relates to a catalyst comprising (a) a polymer, which has a weight-average molecular weight in the range of from 1000 g/mol – 100000 g/mol and which polymer comprises 50 wt-% - 99.9 wt-% of units derived from one or more non-functionalized monomeric units A, 0.1 wt-% - 50 wt-% of units derived from one or more functionalized monomeric units B, 0 wt-% - 30 wt-% of units derived from one or more cross-linking monomeric units C, wherein monomeric units A are selected from (meth)acrylates and monomers co-polymerizable with (meth)acrylates; wherein monomeric units B are selected from (meth)acrylates and monomers co-polymerizable with (meth)acrylates, which contain one or more phosphorous and/or nitrogen containing uncharged electron donors as coordinative groups; and wherein cross-linking monomeric units C are selected from compounds which comprise at least two olefinically unsaturated double bonds co-polymerizable with A and/or B; and (b) a catalytically-active metal compound that is bound to one or more phosphorous and/or nitrogen containing uncharged electron donors of said polymer. Furthermore, the invention relates to corresponding polymers of afore-mentioned catalyst, a process for producing the catalyst and the polymer as well as the use of the catalyst in homogeneous and/or heterogeneous catalysis.

Abstract translation: 本发明涉及一种催化剂，其包含（a）聚合物，其重均分子量在1000g / mol-100000g / mol范围内，该聚合物包含50wt％-99.9wt％的 衍生自一种或多种非官能化单体单元A的单元，0.1重量％-50重量％的衍生自一个或多个官能化单体单元B的单元，0重量％-30重量％衍生自一个或多个 交联单体单元C，其中单体单元A选自（甲基）丙烯酸酯和与（甲基）丙烯酸酯共聚的单体; 其中单体单元B选自（甲基）丙烯酸酯和与（甲基）丙烯酸酯共聚的单体，其含有一个或多个含磷和/或氮的不带电荷的电子给体作为配位基团; 并且其中交联单体单元C选自包含与A和/或B可共聚的至少两个烯属不饱和双键的化合物; 和（b）催化活性金属化合物，其与所述聚合物的一个或多个含磷和/或氮的不带电的电子给体结合。 此外，本发明涉及上述催化剂的相应聚合物，用于制备催化剂和聚合物的方法以及催化剂在均相和/或多相催化中的用途。

公开(公告)号：WO2011107417A1

公开(公告)日：2011-09-09

申请号：PCT/EP2011/052885

申请日：2011-02-28

Applicant: EVONIK DEGUSSA GMBH ,  INSTITUTE OF ORGANIC CHEMISTRY POLISH ACADEMY OF SCIENCES ,  AZAP, Cengiz ,  WOLF, Dorit ,  ABBENHUIS, Hendrikus Cornelis Louis ,  GERRITSEN, Gijsbert ,  GRELA, Karol ,  WILTING, Jos B.M. ,  LESZCZYNSKA, Kinga ,  CZABAN, Justyna ,  WOJTASIEWICZ, Anna

Inventor： AZAP, Cengiz ,  WOLF, Dorit ,  ABBENHUIS, Hendrikus Cornelis Louis ,  GERRITSEN, Gijsbert ,  GRELA, Karol ,  WILTING, Jos B.M. ,  LESZCZYNSKA, Kinga ,  CZABAN, Justyna ,  WOJTASIEWICZ, Anna

IPC: C07F7/21

CPC classification number: C08G77/398 ,  C07F7/21 ,  C08G77/388 ,  C08G77/395

Abstract: Polyhedral oligomeric silsesquioxanes (POSS) linked ligand of the general formula (I): L [(R 1a ) n-1 (SiO 1,5 ) n R 2a ] k [(R 1b ) n-1 SiO 1,5 ) n R 2b ] | [(R 1C ) n-1 SiO 1,5 ) n R 2c ] m in which (R 1a,b,c ) n-1 (SiO 1,5 ) n is a polyhedral oligomeric silsesquioxanes (POSS) with n = 4, 6, 8,10, 12, 14, 16 or 18 and R 1a , R 1b ,R 1c is each independently selected from the group consisting of same or different branched or linear C 1 -C 20 alkyl chains, cyclo alkyl, C 1 -C 20 alkoxy, aryl, aryloxy, heteroaryl and arylalkyl groups, k, l, m is 0 or 1 provided that k+l+m ≥ 1, R 2a , R 2b , R 2c is a spacer that binds the polyhedral oligomeric silsesquioxane (POSS) to the ligand L and ligand L is an uncharged electron donor.

Abstract translation: 通式（I）的多面体低聚倍半硅氧烷（POSS）连接配体：L [（R1a）n-1（SiO1,5）n R2a] k [（R1b）n-1SiO1,5）n R2b] [（R1C）n-1SiO1,5）n R2c] m其中（R1a，b，c）n-1（SiO1,5）n是具有n = 4,6,8,10的多面体低聚倍半硅氧烷（POSS） ，12,14,16或18，并且R 1a，R 1b，R 1c各自独立地选自相同或不同的支链或直链C 1 -C 20烷基链，环烷基，C 1 -C 20烷氧基，芳基，芳氧基，杂芳基和芳基烷基 基团k，l，m为0或1，条件是k + 1 + m = 1，R2a，R2b，R2c是将多面体低聚倍半硅氧烷（POSS）与配体L结合的间隔基，配体L是不带电子的电子给体 。

公开(公告)号：WO2010003729A1

公开(公告)日：2010-01-14

申请号：PCT/EP2009/056277

申请日：2009-05-25

Applicant: EVONIK DEGUSSA GMBH ,  BRAUSCH, Nicole ,  EBBERS, André ,  STOCHNIOL, Guido ,  TROCHA, Martin ,  ÖNAL, Yücel ,  SAUER, Jörg ,  STÜTZEL, Bernhard ,  WOLF, Dorit ,  STÜGER, Harald

Inventor： BRAUSCH, Nicole ,  EBBERS, André ,  STOCHNIOL, Guido ,  TROCHA, Martin ,  ÖNAL, Yücel ,  SAUER, Jörg ,  STÜTZEL, Bernhard ,  WOLF, Dorit ,  STÜGER, Harald

IPC: C01B33/04

CPC classification number: C01B33/04

Abstract: Process for preparing higher hydridosilanes of the general formula H-(SiH 2 ) n -H where n ≥ 2, in which - one or more lower hydridosilanes - hydrogen, and - one or more transition metal compounds comprising elements of transition group VIII of the Periodic Table and the lanthanides are reacted at a pressure of more than 5 bar absolute, subsequently depressurized and the higher hydridosilanes are separated off from the reaction mixture obtained.

Abstract translation: 制备通式为H-（SiH 2）n H的高级羟基硅烷的方法，其中n = 2，其中 - 一个或多个低级羟基硅烷 - 氢，以及 - 一种或多种包含元素周期表第八族元素的过渡金属化合物和 镧系元素在绝对压力大于5巴的压力下反应，随后减压，从所得反应混合物中分离出较高的氢硅烷。