公开(公告)号：WO2011022226A1

公开(公告)日：2011-02-24

申请号：PCT/US2010/044670

申请日：2010-08-06

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi ,  MIELE, Philip, Francis ,  ASRAR, Jawed

IPC: D04H1/64 ,  C08B37/00 ,  C08L5/00 ,  C03C25/32 ,  B27N3/00 ,  C08G14/14 ,  C08L97/02 ,  C09J101/00 ,  C09J105/00

CPC classification number: C08L1/00

Abstract: Provided is a cellulosic composite comprised of cellulosic material and a binder. The binder comprises an aldehyde or ketone and amine salt of an inorganic acid. The composition when mixed with cellulosic material and cured forms a cellulosic composite.

Abstract translation: 提供了由纤维素材料和粘合剂组成的纤维素复合材料。 粘合剂包含无机酸的醛或酮和胺盐。 当与纤维素材料混合并固化时的组合物形成纤维素复合材料。

公开(公告)号：WO2006124256A3

公开(公告)日：2006-11-23

申请号：PCT/US2006/016617

申请日：2006-05-02

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi ,  FISLER, Diana, Kim

IPC: B32B17/02

Abstract: Provided is a fiberglass binder composition which comprises epoxidized oil and a multifunctional carboxylic acid or anhydride. The resultant binder provides minimal processing difficulties and a fiberglass product which exhibits minimal water absorption.

公开(公告)号：WO2006101724A2

公开(公告)日：2006-09-28

申请号：PCT/US2006/008098

申请日：2006-03-07

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi ,  ASRAR, Jawed

IPC: C08K5/00

CPC classification number: C08K5/04 ,  C08K5/16 ,  C08L67/08

Abstract: Provided is a fiberglass binder composition which comprises maleinized polyenes and a reactive component selected from the group consisting of alkanolamines, polyols, and monomers containing terminal unsaturation. The resultant binder provides minimal processing difficulties and a fiberglass product which exhibits good water absorption properties.

Abstract translation: 提供一种玻璃纤维粘合剂组合物，其包含马来化多烯和选自链烷醇胺，多元醇和含有末端不饱和单体的反应性组分。 所得到的粘合剂提供最小的加工困难和显示出良好吸水性能的玻璃纤维产品。

公开(公告)号：WO2015016873A1

公开(公告)日：2015-02-05

申请号：PCT/US2013/052902

申请日：2013-07-31

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi ,  LESTER, Uranchimeg ,  ASRAR, Jawed

IPC: D04H1/4242 ,  D04H1/64 ,  C09J161/34 ,  D04H1/587 ,  C08L61/34 ,  C08L73/02 ,  C03C25/24 ,  C03C25/34

CPC classification number: D04H1/64 ,  C03C25/25 ,  C03C25/34 ,  C08G16/0256 ,  C08L61/22 ,  D04H1/4242 ,  D04H1/587

Abstract: Formaldehyde-free binder compositions are described that include an aldehyde or ketone, an organic anhydride, an alkanol amine, and a nitrogen-containing salt of an inorganic acid. The binder compositions may be applied to fibers, such as glass fibers, to make formaldehyde-free, fiber-reinforced composites. Methods of making fiber- reinforced composites are also described, where such methods may include mixing an alkanol amine with an organic anhydride to make a first mixture, and adding a reducing sugar to the first mixture to make a second mixture. A nitrogen-containing salt may be added to the second mixture to make a binder composition, which may be applied to fibers to form a binder-fiber amalgam. The amalgam may be heated to cure the binder composition and form the fiber-reinforced composite.

Abstract translation: 描述了不含甲醛的粘合剂组合物，其包括醛或酮，有机酸酐，链烷醇胺和无机酸的含氮盐。 粘合剂组合物可以施加到诸如玻璃纤维的纤维上，以制造不含甲醛的纤维增强复合材料。 还描述了制备纤维增强复合材料的方法，其中这些方法可包括将烷醇胺与有机酸酐混合以制备第一混合物，并向第一混合物中加入还原糖以制备第二混合物。 可以向第二混合物中加入含氮盐以制备粘合剂组合物，其可以施加到纤维上以形成粘合剂 - 纤维汞齐。 可以将汞齐加热以固化粘合剂组合物并形成纤维增强复合材料。

公开(公告)号：WO2006096321A2

公开(公告)日：2006-09-14

申请号：PCT/US2006/006072

申请日：2006-02-21

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi ,  FISLER, Diana, Kim

IPC: C08F4/80

CPC classification number: C08F220/28 ,  C08F4/34 ,  C08F4/80 ,  H05K1/0366 ,  Y10T428/2964 ,  Y10T442/2992

Abstract: A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises a substantially unpolymerized acrylate and/or methacrylate primarily having no more than approximately six recurring moieties. The composition is either unpolymerized at the time of its application to the fiberglass or in the form of an oligomer. The curable composition is coated on fiberglass and thereafter is cured to form a secure binder. In a preferred embodiment the fiberglass is the form of building insulation. In other embodiments the product is a microglass-based substrate useful for as a printed circuit board, battery separator, filter stock, or reinforcement scrim.

Abstract translation: 提供了一种与玻璃纤维一起使用的可固化的不含甲醛的结合组合物。 这种可固化组合物包含基本上未聚合的丙烯酸酯和/或甲基丙烯酸酯，主要具有不超过约六个重复部分。 组合物在其应用于玻璃纤维时或在低聚物的形式下是未聚合的。 将可固化组合物涂覆在玻璃纤维上，然后固化以形成牢固的粘合剂。 在优选实施例中，玻璃纤维是建筑隔热的形式。 在其它实施方案中，该产品是可用作印刷电路板，电池隔板，过滤材料或增强稀松布的基于玻璃基的基底。

公开(公告)号：WO2011019590A1

公开(公告)日：2011-02-17

申请号：PCT/US2010/044668

申请日：2010-08-06

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi

IPC: D04H1/64 ,  C08B37/00 ,  C08L5/00 ,  C03C25/32

CPC classification number: C08G12/06 ,  C08K7/14 ,  C08L61/22

Abstract: A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises an aldehyde or ketone and an amine salt of an inorganic acid. The composition when applied to fiberglass is cured to form a water- insoluble binder which exhibits good adhesion to glass. In a preferred embodiment the fiberglass is in the form of building insulation or reinforcement for a roofing membrane. In other embodiments the product is a microglass-based substrate for use in a printed circuit board, battery separator, filter stock, or reinforcement scrim.

Abstract translation: 提供了一种与玻璃纤维一起使用的可固化的不含甲醛的结合组合物。 这种可固化组合物包含醛或酮和无机酸的胺盐。 当将组合物施加到玻璃纤维上时，固化以形成对玻璃具有良好粘附性的水不溶性粘合剂。 在一个优选实施例中，玻璃纤维是用于屋顶隔膜的建筑隔热或增强的形式。 在其它实施方案中，该产品是用于印刷电路板，电池隔板，过滤材料或增强稀松布的基于玻璃的基板。

公开(公告)号：WO2007078483A3

公开(公告)日：2007-07-12

申请号：PCT/US2006/045734

申请日：2006-11-29

Applicant: JOHNS MANVILLE ,  SHOOSHTARI, Kiarash, Alavi ,  ASRAR, Jawed

Inventor： SHOOSHTARI, Kiarash, Alavi ,  ASRAR, Jawed

IPC: C08G14/02

Abstract: A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises a reaction product of a multi- aldehyde or multi-ketone and a phenolic compound. When heated, the reaction product undergoes curing to form a water-insoluble cured benzohydro-benzofurane binder which exhibits good adhesion to glass. In a preferred embodiment, a reaction product of a multi-aldehyde and a phenolic compound having more than one phenolic group initially is formed. The fiberglass can be provided in various configurations when bound by the binding composition of the present invention, and preferably is in the form of a non-woven. In a particularly preferred embodiment, the final product is a mat or building insulation.

公开(公告)号：WO2011022222A1

公开(公告)日：2011-02-24

申请号：PCT/US2010/044651

申请日：2010-08-06

Applicant: JOHNS MANVILLE

Inventor： SHOOSHTARI, Kiarash, Alavi ,  HAMILTON, James, Patrick ,  ASRAR, Jawed

IPC: D04H1/64 ,  C03C25/32 ,  C08B37/00 ,  C08L5/00 ,  C09J179/00

CPC classification number: C08G69/50 ,  D04H1/587 ,  Y10T442/60

Abstract: Provided are nonwoven polymeric fiber webs using an improved curable composition. Such curable composition comprises a reaction product of an amine and a reactant in the form of an ammo-amide intermediate. To the ammo-amide is added an aldehyde or ketone to form the curable binder composition. The composition when applied to the polymeric fibers is cured to form a water-insoluble polymer binder which exhibits good adhesion and thermo-dimensional stability.

Abstract translation: 提供了使用改进的可固化组合物的非织造聚合物纤维网。 这种可固化组合物包含胺和以氨基酰胺中间体形式的反应物的反应产物。 向氨基酰胺中加入醛或酮以形成可固化粘合剂组合物。 固化聚合物纤维时的组合物，形成表现出良好的粘合性和热稳定性的水不溶性聚合物粘合剂。

公开(公告)号：WO2007044632A1

公开(公告)日：2007-04-19

申请号：PCT/US2006/039327

申请日：2006-10-06

Applicant: JOHNS MANVILLE ,  SHOOSHTARI, Kiarash, Alavi ,  FISLER, Diana, Kim

Inventor： SHOOSHTARI, Kiarash, Alavi ,  FISLER, Diana, Kim

IPC: B32B17/04

CPC classification number: C09D4/00 ,  H05K1/0366 ,  Y10T428/31725

Abstract: A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises a conjugate addition product of an amine and an unsaturated reactant in the form of a β-amino-ester or β-amino-amide intermediate. The composition when coated on fiberglass is cured to form a water-insoluble polyamide or polyimide binder which exhibits good adhesion to glass. In a preferred embodiment the fiberglass is in the form of building insulation. In other embodiments the product is a microglass-based substrate for use in a printed circuit board, battery separator, filter stock, or reinforcement scrim.

Abstract translation: 提供了一种与玻璃纤维一起使用的可固化的不含甲醛的结合组合物。 这种可固化组合物包含胺与β-氨基酯或β-氨基 - 酰胺中间体形式的不饱和反应物的共轭加成产物。 固化玻璃纤维上的组合物，以形成对玻璃具有良好粘附性的水不溶性聚酰胺或聚酰亚胺粘合剂。 在优选的实施例中，玻璃纤维是建筑隔热的形式。 在其它实施方案中，该产品是用于印刷电路板，电池隔板，过滤材料或增强稀松布的基于玻璃的基板。

公开(公告)号：WO2007044631A2

公开(公告)日：2007-04-19

申请号：PCT/US2006/039326

申请日：2006-10-06

Applicant: JOHNS MANVILLE ,  SHOOSHTARI, Kiarash, Alavi ,  ASRAR, Jawed

Inventor： SHOOSHTARI, Kiarash, Alavi ,  ASRAR, Jawed

IPC: C03C25/26

CPC classification number: C03C25/10 ,  C03C25/323 ,  C08F8/28 ,  C08L29/14 ,  C09D129/14 ,  H01M2/1613 ,  H05K1/0366 ,  Y10T428/2933

Abstract: A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises an acid-catalyzed reaction product of an aldehyde or ketone with a multihydric alcohol. When heated, the composition forms polyacetal or polyketal that undergoes curing to form a water-insbluble resin binder which exhibits good adhesion to glass. In a preferred embodiment, maleic anhydride initially serves as a catalyst and subsequently enters into a cross-linking reaction during curing to form a poly(ester-acetal). Also, in a preferred embodiment, the fiberglass is in the form of building insulation. In other embodiments the product can be a microglass-based substrate for use in a printed circuit board, battery separator, filter stock, or reinforcement scrim.

Abstract translation: 提供了一种与玻璃纤维一起使用的可固化的不含甲醛的结合组合物。 这种可固化组合物包含醛或酮与多元醇的酸催化反应产物。 当加热时，组合物形成聚缩醛或聚缩酮，其经历固化以形成对玻璃具有良好粘附性的不溶于水的树脂粘合剂。 在优选的实施方案中，马来酸酐最初用作催化剂，随后在固化期间进入交联反应以形成聚（酯 - 缩醛）。 而且，在一个优选实施例中，玻璃纤维是建筑隔热的形式。 在其它实施方案中，该产品可以是用于印刷电路板，电池隔板，过滤材料或增强稀松布的基于玻璃基的基底。