公开(公告)号：WO2014142668A2

公开(公告)日：2014-09-18

申请号：PCT/NL2014/050157

申请日：2014-03-14

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： COLOZZI, Michele ,  PALO, Emma ,  CONTALDO, Palma ,  PEPE, Maria Rosaria ,  PALMA, Vincenzo ,  VAIANO, Vincenzo

IPC: B01D53/14

CPC classification number: C10L3/103 ,  B01D53/1456 ,  B01D53/48 ,  B01D2257/308 ,  B01J19/24 ,  B01J23/06 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/34 ,  B01J23/462 ,  B01J23/745 ,  B01J23/755 ,  B01J2219/24 ,  C07C7/14875 ,  C10L2290/06 ,  C10L2290/541

Abstract: Disclosed is method for removing carbonyl sulphide and/or carbon disulphide from a sour gas stream. The method comprises subjecting the gas stream to simultaneous contact with an absorption liquid, such as an aqueous amine solution, and with a catalyst suitable for hydrolyzing carbonyl sulphide and/or carbon disulphide. To this end, the invention also provides a reactor system wherein both an absorption liquid and a catalyst are present. In a preferred embodiment, the catalyst is a heterogeneous catalyst present on or in an absorption column, either coated on the trays of a column with trays, or contained in the packing of a packed column.

Abstract translation: 公开了用于从酸气流中除去硫化羰和/或二硫化碳的方法。 该方法包括使气流同时与吸收液体如胺水溶液接触，并与适于水解羰基硫化物和/或二硫化碳的催化剂接触。 为此，本发明还提供了其中存在吸收液和催化剂两者的反应器系统。 在一个优选的实施方案中，催化剂是存在于吸收塔上或吸收塔中的非均相催化剂，或者涂布在具有塔板的塔盘上，或者包含在填料塔的填料中。

公开(公告)号：WO2013062415A1

公开(公告)日：2013-05-02

申请号：PCT/NL2012/050748

申请日：2012-10-26

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO, Gaetano ,  ANTONETTI, Elena ,  CONTALDO, Palma

IPC: C01B3/38 ,  C01B3/48 ,  C07C29/151

CPC classification number: C01B3/26 ,  C01B3/30 ,  C01B3/38 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/1235 ,  C01B2203/141 ,  C01B2203/142 ,  C07C29/00 ,  C07C29/1518

Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a feed (100) is divided into two streams, wherein one stream is subjected to catalytic partial oxidation (CPO) (2) and the other stream is subjected to steam reforming (5) followed by a water gas shift reaction (51). The two streams are then recombined and can be used further in methanol synthesis (6). The recombined stream preferably has an R ratio, being a molar ratio (H 2 -C0 2 )/(CO+C0 2 ), in the range of 1.9 - 2.2 and preferably about 2. The invention further relates to a method for producing methanol from a hydrocarbon containing feed, wherein first synthesis gas is obtained according to the method of the invention, which synthesis gas is further used to produce methanol. Also, the invention relates to a method of adapting an existing methanol plant to the methanol production process of the invention.

Abstract translation: 用于生产甲醇生产合成气的方法本发明涉及一种由含烃进料生产合成气的方法，该合成气特别适用于随后用于甲醇生产。 在该方法中，将进料（100）分成两股料流，其中一条料流进行催化部分氧化（CPO）（2），另一条料流进行蒸汽重整（5），随后进行水煤气变换反应 51）。 然后将两种物流重组，并可以进一步用于甲醇合成（6）。 重组流优选具有在1.9-2.2的范围内的摩尔比（H 2 -CO 2）/（CO + CO 2）的R比。优选地，本发明还涉及一种从烃生产甲醇的方法 其中根据本发明的方法获得第一合成气，该合成气被进一步用于生产甲醇。 本发明还涉及使现有的甲醇装置适应本发明的甲醇生产方法。

公开(公告)号：WO2013015687A1

公开(公告)日：2013-01-31

申请号：PCT/NL2012/050533

申请日：2012-07-26

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  IAQUANIELLO, Gaetano ,  PALO, Emma ,  CONTALDO, Palma

Inventor： IAQUANIELLO, Gaetano ,  PALO, Emma ,  CONTALDO, Palma

IPC: C01B3/38 ,  C01B3/48 ,  C01B3/50 ,  C01B3/56

CPC classification number: C01B3/382 ,  C01B3/384 ,  C01B3/48 ,  C01B3/501 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01B2203/0883 ,  C01B2203/0888 ,  C01B2203/0894 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/142

Abstract: The present invention relates to a process for producing a hydrogen containing gas mixture comprising the following steps: (i) providing a preheated mixture comprising a fossil fuel, preferably methane, and steam, (ii) conducting an adiabatic reaction between the fossil fuel and the steam, in the presence of a catalyst, wherein a first reaction product mixture is formed comprising methane, hydrogen and carbon dioxide, and (iii) conducting an oxygen-assisted reforming reaction in the presence of a catalyst between said first reaction product mixture and an oxygen comprising stream, wherein the oxygen comprising stream comprises at least 40 vol% oxygen, forming a second reaction product mixture comprising hydrogen and carbon monoxide. The invention also relates to a system suitable for hydrogen production from a hydrocarbon feed according to the present invention.

Abstract translation: 本发明涉及一种含氢气体混合物的制备方法，包括以下步骤：（i）提供包含化石燃料，优选甲烷和蒸汽的预热混合物，（ii）在化石燃料与化学燃料之间进行绝热反应 蒸汽，在催化剂存在下，其中形成包含甲烷，氢气和二氧化碳的第一反应产物混合物，和（iii）在催化剂存在下，在所述第一反应产物混合物和 含氧气流，其中所述含氧气流包含至少40体积％的氧气，形成包含氢气和一氧化碳的第二反应产物混合物。 本发明还涉及适用于根据本发明的烃进料的氢气生产的系统。