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公开(公告)号：WO2016012116A1
公开(公告)日：2016-01-28
申请号：PCT/EP2015/060309
申请日：2015-05-11
Inventor： CHIAPPE, Cinzia , POMELLI, Christian , MEZZETTA, Andrea , MASCIOCCHI, Barbara , GENTILE, Alessio
CPC classification number: C11B1/10 , C11B1/04 , C12N1/06 , C12N1/12 , C12P7/6463
Abstract: In the present invention a method for treating algae is disclosed, which method comprises the steps of (a) providing an ionic liquid, which is a conjugate of an organic base with pK a at least 6 and an acid, (b) providing algae, (c) subjecting algae to cell lysis with the ionic liquid, whereby at least two phases are formed, including a hydrophobic phase and a hydrophilic phase, and (d) separating the hydrophobic phase containing lipids.
Abstract translation: 在本发明中，公开了一种处理藻类的方法，该方法包括以下步骤：（a）提供离子液体，其为有机碱与pKa至少为6的结合物和酸，（b）提供藻类（ c）使藻类与离子液体进行细胞裂解，由此形成至少两个相，包括疏水相和亲水相，和（d）分离含有疏水相的脂质。
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公开(公告)号：WO2014142668A2
公开(公告)日：2014-09-18
申请号：PCT/NL2014/050157
申请日：2014-03-14
Inventor： COLOZZI, Michele , PALO, Emma , CONTALDO, Palma , PEPE, Maria Rosaria , PALMA, Vincenzo , VAIANO, Vincenzo
IPC: B01D53/14
CPC classification number: C10L3/103 , B01D53/1456 , B01D53/48 , B01D2257/308 , B01J19/24 , B01J23/06 , B01J23/22 , B01J23/26 , B01J23/28 , B01J23/34 , B01J23/462 , B01J23/745 , B01J23/755 , B01J2219/24 , C07C7/14875 , C10L2290/06 , C10L2290/541
Abstract: Disclosed is method for removing carbonyl sulphide and/or carbon disulphide from a sour gas stream. The method comprises subjecting the gas stream to simultaneous contact with an absorption liquid, such as an aqueous amine solution, and with a catalyst suitable for hydrolyzing carbonyl sulphide and/or carbon disulphide. To this end, the invention also provides a reactor system wherein both an absorption liquid and a catalyst are present. In a preferred embodiment, the catalyst is a heterogeneous catalyst present on or in an absorption column, either coated on the trays of a column with trays, or contained in the packing of a packed column.
Abstract translation: 公开了用于从酸气流中除去硫化羰和/或二硫化碳的方法。 该方法包括使气流同时与吸收液体如胺水溶液接触，并与适于水解羰基硫化物和/或二硫化碳的催化剂接触。 为此，本发明还提供了其中存在吸收液和催化剂两者的反应器系统。 在一个优选的实施方案中，催化剂是存在于吸收塔上或吸收塔中的非均相催化剂，或者涂布在具有塔板的塔盘上，或者包含在填料塔的填料中。
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3.发明申请
公开(公告)号：WO2012154043A1
公开(公告)日：2012-11-15
申请号：PCT/NL2012/050310
申请日：2012-05-07
Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER , MOLINARI, Lucio , ANGELINI, Fabio , BARBATO, Lucia
Inventor： MOLINARI, Lucio , ANGELINI, Fabio , BARBATO, Lucia
CPC classification number: C01B3/065 , B01D53/8612 , B01D2251/102 , B01D2256/16 , B01J19/24 , B01J19/245 , B01J2219/0015 , B01J2219/00157 , B01J2219/24 , C01B3/02 , C01B3/04 , C01B17/0413 , C01B17/0495 , C01B2203/0255 , C01B2203/06 , Y02E60/364 , Y02P20/129
Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H 2 S-containing gas stream, with zero emissions. The method comprises the thermal oxidative cracking of H 2 S so as to form H 2 and S 2 . Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The ratio H 2 S/O 2 in the feedstock is higher than 2:1, preferably in the range of 3:1-5: 1.
Abstract translation: 公开了一种从含H2S的气流同时生产氢和硫的方法，零排放。 该方法包括H2S的热氧化裂化，形成H2和S2。 优选地，使用富氧空气，优选纯氧进行氧化。 原料中H 2 S / O 2的比例高于2:1，优选在3：1-5：1的范围内。
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公开(公告)号：WO2014054945A3
公开(公告)日：2014-04-10
申请号：PCT/NL2013/050698
申请日：2013-10-01
Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER , PELLEGRINI, Laura Annamaria
Inventor： PELLEGRINI, Laura Annamaria
Abstract: The invention relates to a process for the removal of CO 2 from acid gas by cryogenic distillation performed in two steps. The feed mixture is first distilled at high pressure (at least 45 bar) in a first distillation column. The top product or a part thereof is then, after heating, subjected to a second distillation step at a lower pressure (lower than 45 bar). The top product of the second distillation step is methane of high purity (more than 99 mol.%). The bottom product of the second distillation step is recycled back to the first distillation column. The method according to the invention allows complete separation of methane also at higher level of acidic components, is economical and does not result in solid CO 2 build-up, which is a common problem in cryogenic distillation.
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公开(公告)号：WO2013002643A3
公开(公告)日：2013-01-03
申请号：PCT/NL2012/050464
申请日：2012-06-29
Inventor： FACCHI, Edoardo
Abstract: Disclosed is a reactor system for the production of polyester pre-condensate. The system comprises at least two reaction zones, operating at substantially different pressure. Reactants fed into the first zone are allowed to initially react and are then allowed to enter a second zone by means of pressure flow. In the second zone, a system of concentric spacers is present so as to ensure a sufficient path length of the reaction mixture to form a pre-condensate, as well as in internal heat exchanger. The pre-condensate is allowed to flow to a next (polymerization) stage by means of gravity flow on account of a standpipe present in the second reaction zone. Said standpipe has an inlet above the internal heating system in the second reaction zone.
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Patent Agency Ranking6.发明申请
公开(公告)号：WO2012154041A1
公开(公告)日：2012-11-15
申请号：PCT/NL2012/050308
申请日：2012-05-07
Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER , ANGELINI, Fabio , BARBATO, Lucia
Inventor： ANGELINI, Fabio , BARBATO, Lucia
CPC classification number: C01B17/0495 , B01D53/8612 , B01D2251/102 , B01D2256/16 , B01J8/00 , C01B3/02 , C01B3/04 , C01B17/0404 , C01B17/0408 , C01B17/0426 , Y02E60/364 , Y02P20/129
Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H 2 S-containing gas stream, with reduced, and preferably zero, emissions. The method comprises the catalytic oxidative cracking of H 2 S so as to form H 2 and S 2 . Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The process is conducted in a reaction chamber comprising a bifunctional catalyst material, so as to favor both the partial oxidation of H 2 S and the dissociation thereof.
Abstract translation: 公开了一种从含H 2 S的气流同时生产氢和硫的方法，具有减少的，优选为零的排放。 该方法包括H2S的催化氧化裂化，形成H2和S2。 优选地，使用富氧空气，优选纯氧进行氧化。 该方法在包含双官能催化剂材料的反应室中进行，以有利于H2S的部分氧化和其解离。
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公开(公告)号：WO2012096572A1
公开(公告)日：2012-07-19
申请号：PCT/NL2012/050007
申请日：2012-01-05
Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER , IAQUANIELLO, Gaetano , SALLADINI, Annarita
Inventor： IAQUANIELLO, Gaetano , SALLADINI, Annarita
CPC classification number: C01B3/382 , C01B3/38 , C01B3/503 , C01B3/505 , C01B2203/0233 , C01B2203/0405 , C01B2203/041 , C01B2203/043 , C01B2203/06 , C01B2203/0833 , C01B2203/0844 , C01B2203/1064 , C01B2203/1082 , C01B2203/1235 , C01B2203/1241 , C01B2203/127 , C01B2203/1294 , C01B2203/142 , C01B2203/143 , C01B2203/147
Abstract: The invention relates to the production of hydrogen by steam reforming comprising the steps of (i) providing a fossil fuel, preferably methane, and steam, (ii) conducting a steam reforming reaction between the fossil fuel and the steam under heating, wherein a reaction mixture is formed comprising hydrogen and carbon dioxide, (iii) separating hydrogen from the reaction mixture by membrane separation, wherein a permeate is formed comprising hydrogen and a retentate comprising carbon dioxide, (iv) purifying carbon dioxide from the retentate, and (v) using said carbon dioxide as a heat exchange medium to supply heat at least for the steam reforming reaction (ii). The method of the invention can also be used for the production of pressurised carbon dioxide characterised by a high purity. Further, the invention relates to a system for hydrogen production and to the use of pressurised carbon dioxide as heat exchange medium.
Abstract translation: 本发明涉及通过蒸汽重整生产氢，其包括以下步骤：（i）提供化石燃料，优选甲烷和蒸汽，（ii）在加热下在化石燃料和蒸汽之间进行蒸汽重整反应，其中反应 形成包含氢气和二氧化碳的混合物，（iii）通过膜分离从反应混合物中分离氢，其中形成包含氢气和包含二氧化碳的渗余物的渗透物，（iv）从渗余物中提纯二氧化碳，和（v） 使用所述二氧化碳作为热交换介质至少为蒸汽重整反应（ii）供应热量。 本发明的方法也可用于生产特征为高纯度的加压二氧化碳。 此外，本发明涉及一种用于制氢和使用加压二氧化碳作为热交换介质的系统。
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公开(公告)号：WO2016010416A1
公开(公告)日：2016-01-21
申请号：PCT/NL2015/050262
申请日：2015-04-21
Inventor： IAQUANIELLO, Gaetano , DOBREE, Joey
IPC: C07C273/04 , C01B3/38 , C01B3/48
CPC classification number: C07C273/04 , B01J19/245 , B01J2219/00024 , B01J2219/24 , C01B3/382 , C01B3/386 , C01B3/48 , C01B32/50 , C01B2203/0261 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/068 , C01B2203/1235 , C01B2203/1241 , C01B2203/141 , C01C1/0405 , C01C1/0417 , C01C1/0488
Abstract: The present invention provides a method for increasing the capacity of a urea production complex, the method comprising a step of adding to an existing urea production complex a CO 2 production unit, which unit employs a CO 2 production method comprising: i) subjecting a hydrocarbon feed to short contact time catalytic partial oxidation (SCT- CPO) to produce a first gas mixture comprising H 2 , CO and CO 2 , ii) subjecting said first gas mixture to a water gas shift reaction yielding a second gas mixture, iii) separating CO 2 from said second gas mixture yielding a purified CO 2 stream and a hydrogen containing stream and subsequently iv) reacting said purified CO 2 stream with ammonia from the ammonia production unit to produce urea. The invention also provides a urea production complex realized by the application of this method and a urea production method.
Abstract translation: 本发明提供了一种增加尿素生产复合物的能力的方法，该方法包括向现有的尿素生产复合体中加入二氧化碳生产单元的步骤，该单元采用二氧化碳生产方法，该方法包括：i）使烃进料 短接触时间催化部分氧化（SCT-CPO）以产生包含H 2，CO和CO 2的第一气体混合物，ii）使所述第一气体混合物经受产生第二气体混合物的水煤气变换反应，iii）将CO 2从所述第二气体分离 气体混合物产生纯化的CO 2流和含氢气流，随后iv）使所述纯化的CO 2流与来自氨生产单元的氨反应以产生尿素。 本发明还提供了通过应用该方法和尿素生产方法实现的尿素生产复合体。
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公开(公告)号：WO2014193224A2
公开(公告)日：2014-12-04
申请号：PCT/NL2014/050333
申请日：2014-05-27
Inventor： BARSI, Adriano , IAQUANIELLO, Gaetano
IPC: F03G6/06
Abstract: Disclosed is a thermal energy storage system for storing collected solar thermal energy. The system comprises a solar thermal energy collection facility in the form of a field of parabolic troughs, which is in thermal communication with a molten salt circuit. The molten salt circuit is in fluid communication with a molten salt storage facility comprising at least three storage tanks that are each in fluid communication with the molten salt circuit. The multiple tanks set-up allows using cheaper materials, and a more efficient storage of thermal energy.
Abstract translation: 公开了一种用于存储收集的太阳能热能的热能存储系统。 该系统包括与熔盐电路热连通的抛物槽区域形式的太阳能热能收集设备。 熔融盐电路与包括至少三个储存罐的熔融盐储存设备流体连通，每个储罐与熔盐回路流体连通。 多个坦克设置允许使用更便宜的材料，并且更有效地储存热能。
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公开(公告)号：WO2013095130A1
公开(公告)日：2013-06-27
申请号：PCT/NL2012/050901
申请日：2012-12-18
Inventor： IAQUANIELLO, Gaetano , CUCCHIELLA, Barbara , ANTONETTI, Elena
IPC: C01B3/02 , C01B3/38 , C01B3/48 , C01C1/04 , C07C273/04 , C07C273/10
CPC classification number: C07C273/10 , C01B3/025 , C01B3/26 , C01B3/382 , C01B3/384 , C01B3/386 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/04 , C01B2203/043 , C01B2203/0445 , C01B2203/0475 , C01B2203/068 , C01B2203/1241 , C01B2203/141 , C01B2203/146 , C01C1/04
Abstract: Disclosed is a process for the production of ammonia comprising a step wherein synthesis gas is formed in two different ways, viz. by catalytic partial oxidation (31) and by steam reforming, and wherein the combined streams of synthesis gas are subjected to a water gas shift reaction (50). Also disclosed is a process of producing urea, wherein ammonia is formed (90) in a process involving said combined streams and wherein carbon dioxide (110) formed in the same process is reacted with said ammonia so as to form urea.
Abstract translation: 公开了一种生产氨的方法，包括以两种不同方式形成合成气的步骤，即， 通过催化部分氧化（31）和通过蒸汽重整，并且其中合成气流经受水煤气变换反应（50）。 还公开了一种生产尿素的方法，其中在涉及所述组合料流的方法中形成氨（90），并且其中在相同方法中形成的二氧化碳（110）与氨反应以形成尿素。
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