公开(公告)号：WO2004060930A3

公开(公告)日：2004-08-26

申请号：PCT/US0338263

申请日：2003-12-03

Applicant: UNIVATION TECH LLC

Inventor： AGAPIOU AGAPIOS K ,  HAGERTY ROBERT O ,  HUSSEIN F DAVID ,  MUHLE MICHAEL E ,  PANNELL RICHARD B ,  RUSSELL KATHRYN ANN ,  SANTANA ROBERT LYNN ,  ZHANG X SIMON

IPC: C08F2/34 ,  C08F2/38 ,  C08F10/00 ,  C08F210/16

CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2410/05 ,  Y10S526/901 ,  C08F2/42 ,  C08F210/08 ,  C08F2500/24

Abstract: Processes for transitioning among polymerization catalyst systems, preferably catalyst systems that are incompatible with each other. In particular, the processes relate to transitioning from olefin polymerizations utilizing metallocene catalyst systems to olefin polymerizations utilizing traditional Ziegler-Natta catalyst systems.

Abstract translation: 在聚合催化剂体系，优选彼此不相容的催化剂体系之间转换的方法。 具体而言，所述方法涉及利用茂金属催化剂体系从烯烃聚合转变为使用传统齐格勒 - 纳塔催化剂体系的烯烃聚合。

公开(公告)号：WO2004060921A3

公开(公告)日：2004-12-23

申请号：PCT/US0338269

申请日：2003-12-03

Applicant: UNIVATION TECH LLC

Inventor： GOODE MARK G ,  BURDETT IAN ,  CAI PING P ,  EISINGER RONALD E ,  HUSSEIN F DAVID ,  KINNAN MICHAEL A ,  MUHLE MICHAEL E ,  SWECKER JAMES L

IPC: B01J8/24 ,  C08F2/00 ,  C08F2/34 ,  C08F4/659 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16

CPC classification number: C08F10/02 ,  B01J8/1872 ,  C08F4/65912 ,  C08F4/65916 ,  C08F210/16 ,  C08F2410/05 ,  Y10S526/901 ,  C08F10/00 ,  C08F4/65927 ,  C08F2/42 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24

Abstract: This invention relates to processes for transitioning among polymerization catalyst systems, preferably catalyst systems, which are incompatible with each other. Particularly, the invention relates to processes for transitioning among olefin polymerization reactions utilizing Ziegler-Natta catalyst systems, metallocene catalyst systems and chromium­-based catalyst systems.

Abstract translation: 本发明涉及在彼此不相容的聚合催化剂体系，优选催化剂体系之间转换的方法。 特别地，本发明涉及使用齐格勒 - 纳塔催化剂体系，茂金属催化剂体系和铬基催化剂体系在烯烃聚合反应中转换的方法。

公开(公告)号：WO2013028283A8

公开(公告)日：2013-08-22

申请号：PCT/US2012047027

申请日：2012-07-17

Applicant: UNIVATION TECH LLC ,  CANN KEVIN J ,  MOORHOUSE JOHN H ,  CAO PHUONG A ,  GOODE MARK G ,  HARLAN C JEFF ,  MARIOTT WESLEY R ,  ZILKER JR DANIEL P ,  HUSSEIN F DAVID ,  SUN LIXIN

Inventor： CANN KEVIN J ,  MOORHOUSE JOHN H ,  CAO PHUONG A ,  GOODE MARK G ,  HARLAN C JEFF ,  MARIOTT WESLEY R ,  ZILKER JR DANIEL P ,  HUSSEIN F DAVID ,  SUN LIXIN

IPC: C08F210/16 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F2410/02 ,  C08F4/64148 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/025

Abstract: Catalyst systems and methods for making and using the same are provided. The catalyst system can include a catalyst compound having (1) at least one cyclopentadienyl ligand and at least one heteroatom ligand; (2) two non-bridged cyclopentadienyl ligands; or (3) two or more heteroatom ligands. The catalyst system further comprise a support comprising fluorinated silica. The support may be essentially free of alumina. The catalyst system further comprises an aluminoxane, preferably methylaluminoxane, modified methylaluminoxane, or a combination thereof.

Abstract translation: 提供了催化剂体系及其制备和使用方法。 催化剂体系可以包括具有（1）至少一个环戊二烯基配体和至少一个杂原子配体的催化剂化合物; （2）两个非桥连环戊二烯基配位体; 或（3）两个或更多个杂原子配体。 催化剂体系还包含含有氟化二氧化硅的载体。 载体可以基本上不含氧化铝。 催化剂体系还包含铝氧烷，优选甲基铝氧烷，改性的甲基铝氧烷或其组合。

公开(公告)号：WO2011071900A2

公开(公告)日：2011-06-16

申请号：PCT/US2010059256

申请日：2010-12-07

Applicant: UNIVATION TECH LLC ,  APECETCHE MARIA A ,  POLLARD MARIA ,  HAGERTY ROBERT O ,  AWE MICHAEL D ,  CANN KEVIN J ,  CEVALLOS-CANDAU JOSE F ,  HUSSEIN F DAVID

Inventor： APECETCHE MARIA A ,  POLLARD MARIA ,  HAGERTY ROBERT O ,  AWE MICHAEL D ,  CANN KEVIN J ,  CEVALLOS-CANDAU JOSE F ,  HUSSEIN F DAVID

IPC: C08F2/00 ,  C08F2/34 ,  C08F4/659 ,  C08F10/02

CPC classification number: C08F4/65922 ,  C08F2/002 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/02 ,  C08F2/005 ,  C08F2/34 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14 ,  C08F4/65916

Abstract: Catalysts and methods for making and using the same are provided. The method for fabricating a catalyst may includes contacting a supported catalyst with a monomer under conditions that reduce an overall charge of the catalyst to less than about 75% of an initial charge of the catalyst. A method for polymerization may include introducing a pre-polymerized catalyst and one or more olefins into a gas phase fluidized bed reactor, operating the reactor at conditions sufficient to produce a polyolefin, wherein the polymerization is carried out in the substantial absence of any continuity additives.

Abstract translation: 提供了制备和使用催化剂及其使用方法。 制备催化剂的方法可以包括使负载的催化剂与单体在使催化剂的总电荷降低至催化剂的初始电荷的约75％的条件下接触。 聚合的方法可以包括将预聚合的催化剂和一种或多种烯烃引入气相流化床反应器中，在足以产生聚烯烃的条件下操作反应器，其中聚合基本上不存在任何连续性添加剂 。

公开(公告)号：WO2010045091A3

公开(公告)日：2010-09-30

申请号：PCT/US2009059988

申请日：2009-10-08

Applicant: UNIVATION TECH LLC ,  CAI PING ,  HUSSEIN F DAVID ,  BURDETT IAN D ,  GAINES DAVID M ,  PAINTER ROGER B

Inventor： CAI PING ,  HUSSEIN F DAVID ,  BURDETT IAN D ,  GAINES DAVID M ,  PAINTER ROGER B

IPC: B01J8/38 ,  B01J8/18

CPC classification number: B01J8/1809 ,  B01J8/007 ,  B01J8/1863 ,  B01J8/388 ,  B01J2208/00212 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2208/00309 ,  C08F210/16 ,  Y10S526/918 ,  C08F2/001 ,  C08F2/34 ,  C08F2/01 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/12

Abstract: A continuous gas phase circulating bed reactor, including: a riser for contacting a catalyst and a first gas composition comprising an olefin to form a polyolefin under fast-fluidization regime or a dilute-phase pneumatic conveying regime conditions; a downer for contacting the catalyst and a second gas composition comprising an olefin to form additional polyolefin under fast fluidization regime or a dilute-phase pneumatic conveying regime conditions; and a transport section for conveying at least a portion of the catalyst, polyolefin, and additional polyolefin from the downer to the riser. Also disclosed is a polymerization process using such a circulating bed reactor.

Abstract translation: 一种连续气相循环床反应器，包括：用于使催化剂和包含烯烃的第一气体组合物在快速流化状态或稀相气动输送状态条件下接触以形成聚烯烃的提升管; 用于使催化剂和包含烯烃的第二气体组合物在快速流化状态或稀相气动输送方案条件下形成另外的聚烯烃的下压器; 以及用于将催化剂，聚烯烃和另外的聚烯烃的至少一部分从下降器输送到提升管的输送部分。 还公开了使用这种循环床反应器的聚合方法。