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    MANGANESE BASED COMPLEXES AND USES THEREOF FOR HOMOGENEOUS CATALYSIS
    1.
    发明申请
    MANGANESE BASED COMPLEXES AND USES THEREOF FOR HOMOGENEOUS CATALYSIS 审中-公开
    锰基配合物及其用于均相催化的用途

    公开(公告)号：WO2017137984A1

    公开(公告)日：2017-08-17

    申请号：PCT/IL2017/050152

    申请日：2017-02-08

    Applicant: YEDA RESEARCH AND DEVELOPMENT CO. LTD. ,  NERUSH, Arkadi

    Inventor： MILSTEIN, David ,  VOGT, Matthias ,  MUKHERJEE, Arup ,  ESPINOSA-JALAPA, Noel Angel ,  CHAKRABORTY, Subrata

    IPC: C07B41/02 ,  C07B41/06 ,  C07B41/12 ,  C07B43/00 ,  C07B43/06 ,  C07B43/08 ,  C07F13/00

    CPC classification number: C07F13/00 ,  C07B41/02 ,  C07B41/06 ,  C07B41/12 ,  C07B43/00 ,  C07B43/06 ,  C07B43/08 ,  C07C29/149 ,  C07C67/40 ,  C07C231/10 ,  C07C249/02 ,  C07C253/30 ,  C07C2601/14 ,  C07C251/24 ,  C07C251/08 ,  C07C255/41 ,  C07C255/19 ,  C07C255/31 ,  C07C233/05 ,  C07C233/65 ,  C07C233/66 ,  C07C233/03 ,  C07C69/24 ,  C07C31/125 ,  C07C31/08 ,  C07C31/1355 ,  C07C33/22 ,  C07C33/20 ,  C07C31/20 ,  C07C31/38 ,  C07C33/03

    Abstract: The present invention relates to novel manganese complexes and their use, inter alia , for homogeneous catalysis in (1) the preparation of imine by dehydrogenative coupling of an alcohol and amine; (2) C-C coupling in Michael addition reaction using nitriles as Michael donors; (3) dehydrogenative coupling of alcohols to give esters and hydrogen gas (4) hydrogenation of esters to form alcohols (including hydrogenation of cyclic esters (lactones) or cyclic di-esters (di- lactones), or polyesters); (5) hydrogenation of amides (including cyclic dipeptides, lactams, diamide, polypeptides and polyamides) to alcohols and amines (or diamine); (6) hydrogenation of organic carbonates (including polycarbonates) to alcohols or hydrogenation of carbamates (including polycarbamates) or urea derivatives to alcohols and amines; (7) dehydrogenation of secondary alcohols to ketones; (8) amidation of esters (i.e., synthesis of amides from esters and amines); (9) acylation of alcohols using esters; (10) coupling of alcohols with water and a base to form carboxylic acids; and (11) preparation of amino acids or their salts by coupling of amino alcohols with water and a base. (12) preparation of amides (including formamides, cyclic dipeptides, diamide, lactams, polypeptides and polyamides) by dehydrogenative coupling of alcohols and amines; (13) preparation of imides from diols.

    Abstract translation: 本发明涉及新型锰络合物及其用于（1）通过醇和胺的脱氢偶联制备亚胺的均相催化的用途，尤其是用于均相催化： （2）使用腈作为迈克尔供体的迈克尔加成反应中的C-C偶联; （3）醇的脱氢偶联以得到酯和氢气;（4）酯的氢化形成醇（包括环酯（内酯）或环二酯（二内酯）或聚酯的氢化）; （5）酰胺（包括环状二肽，内酰胺，二酰胺，多肽和聚酰胺）到醇和胺（或二胺）的氢化; （6）有机碳酸酯（包括聚碳酸酯）氢化成醇或氨基甲酸酯（包括聚氨基甲酸酯）或脲衍生物氢化成醇和胺; （7）仲醇脱氢为酮; （8）酯的酰胺化（即由酯和胺合成酰胺）; （9）使用酯酰化醇; （10）醇与水和碱偶联形成羧酸; 和（11）通过氨基醇与水和碱的偶联制备氨基酸或其盐。 （12）通过醇和胺的脱氢偶联制备酰胺（包括甲酰胺，环状二肽，二酰胺，内酰胺，多肽和聚酰胺）; （13）从二醇制备酰亚胺。

    LIQUID-ORGANIC HYDROGEN CARRIER SYSTEMS BASED ON CATALYTIC PEPTIDE FORMATION AND HYDROGENATION
    2.
    发明申请
    LIQUID-ORGANIC HYDROGEN CARRIER SYSTEMS BASED ON CATALYTIC PEPTIDE FORMATION AND HYDROGENATION 审中-公开
    基于催化肽形成和加氢的液体有机氢载体系统

    公开(公告)号：WO2016035081A1

    公开(公告)日：2016-03-10

    申请号：PCT/IL2015/050888

    申请日：2015-09-03

    Applicant: YEDA RESEARCH AND DEVELOPMENT CO. LTD.

    Inventor： MILSTEIN, David ,  HU, Peng ,  FOGLER, Eran

    IPC: C01B3/00 ,  C07C209/50 ,  C07C213/00 ,  C07C29/149 ,  C07C31/08

    CPC classification number: C01B3/0015 ,  C01B3/00 ,  C07C29/149 ,  C07C209/50 ,  C07C211/00 ,  C07C211/10 ,  C07C213/00 ,  C07C215/08 ,  C07C231/08 ,  C07C231/10 ,  C07C233/36 ,  C07C237/08 ,  C07C249/02 ,  C07C251/08 ,  C07D241/08 ,  Y02E60/327 ,  Y02E60/328 ,  C07C31/08

    Abstract: The present invention provides a system and method of storing hydrogen (H 2 ) and releasing it on demand, comprising and making use of diaminoalkanes and alcohols, or aminoalcohols as liquid-organic hydrogen carrier systems (LOHC). 2-aminoethanol (AE) or its N-methyl derivative 2-(methylamino)ethanol undergo catalytic dehydrogenation to form a cyclic dipeptide (glycine anhydride - GA) or its N,N-dimethyl derivative ( N,N- dimethyl GA) with release of hydrogen. Similarly, ethylenediamine (ED) and ethanol undergo catalytic dehydrogenation to form N,N '-diacetylethylenediamine (DAE) with release of hydrogen. Glycine anhydride (GA) or N,N -dimethyl-GA may be hydrogenated back to 2-aminoethanol (AE) or 2-(methylamino)ethanol, respectively, each of which functions as a hydrogen storage system. N,N'-diacetylethylenediamine (DAE) may be hydrogenated back to ED and ethanol, which functions as a hydrogen storage system. These reactions may be catalyzed by a variety of compounds or complexes, including Ruthenium complexes as described herein.

    Abstract translation: 本发明提供一种存储氢（H 2）并根据需要释放的系统和方法，包括并利用二氨基烷烃和醇，或氨基醇作为液 - 有机氢载体系统（LOHC）。 2-氨基乙醇（AE）或其N-甲基衍生物2-（甲基氨基）乙醇进行催化脱氢以形成环状二肽（甘氨酸酐-GA）或其N，N-二甲基衍生物（N，N-二甲基氨基） 的氢。 类似地，乙二胺（ED）和乙醇经历催化脱氢以形成N，N'-二乙酰基乙二胺（DAE），释放氢气。 甘氨酸酐（GA）或N，N-二甲基-GA可以分别氢化回2-氨基乙醇（AE）或2-（甲基氨基）乙醇，它们各自用作储氢体系。 N，N'-二乙酰基乙二胺（DAE）可以被氢化回ED和乙醇，其用作氢存储系统。 这些反应可以由各种化合物或络合物催化，包括本文所述的钌络合物。

    NEW METHOD FOR THE PREPARATION OF METAL CARBENE COMPLEXES
    3.
    发明申请
    NEW METHOD FOR THE PREPARATION OF METAL CARBENE COMPLEXES 审中-公开
    用于制备金属碳复合物的新方法

    公开(公告)号：WO2002083698A1

    公开(公告)日：2002-10-24

    申请号：PCT/IL2002/000304

    申请日：2002-04-15

    Applicant: YEDA RESEARCH AND DEVELOPMENT CO. LTD. ,  MILSTEIN, David ,  GANDELMAN, Mark ,  ASHKENAZI, Nissan ,  RYBTCHINSKI, Boris

    Inventor： MILSTEIN, David ,  GANDELMAN, Mark ,  ASHKENAZI, Nissan ,  RYBTCHINSKI, Boris

    IPC: C07F15/00

    CPC classification number: C07F15/0046 ,  C07C381/00 ,  C07F15/002

    Abstract: The present invention provides a process for preparing a metal carbene complex of formula (I): wherein M is a transition metal atom selected from the group consisting of ruthenium, rhodium, iron , cobalt, osmium and iridium; L denotes neutral donor ligands ligated to said metal, such groups being the same or different; X is an anionic ligand; R1 and R2 are each independently selected from the group consisting of hydrogen, substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C2-C20 alkenyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted vinyl, a is 2 or 3 and b is 1 or 2, such process comprising reacting a sulfur ylide of the formula Ar 2 S=CR 1 R 2 or its precursor with an appropriate metal complex comprising a transition metal atom selected from the group consisting of ruthenium, rhodium, iron, cobalt, osmium and iridium, said metal complex being also in dimeric form, at a temperature between +80 °C and -80 °C, in an inert solvent and under inert atmosphere.

    Abstract translation: 本发明提供了制备式（I）的金属卡宾络合物的方法：其中M是选自钌，铑，铁，钴，锇和铱的过渡金属原子; L表示与所述金属连接的中性供体配体，这些基团相同或不同; X是阴离子配体; R 1和R 2各自独立地选自氢，取代或未取代的C 1 -C 20烷基，取代或未取代的C 2 -C 20烯基，取代或未取代的环烷基，取代或未取代的杂环烷基，取代或未取代的芳基， 取代或未取代的乙烯基，a为2或3，b为1或2，该方法包括使式Ar> 2 R 2或其前体的硫叶立德与合适的金属络合物反应， 选自钌，铑，铁，钴，锇和铱的过渡金属原子，在惰性溶剂中，在+ 80℃至-80℃之间的温度下，所述金属络合物也是二聚体形式，和 在惰性气氛下。

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