COATING LIQUID, METHOD FOR MANUFACTURING OPTICAL COMPONENT, AND PHOTOGRAPHIC OPTICAL SYSTEM
    2.
    发明申请
    COATING LIQUID, METHOD FOR MANUFACTURING OPTICAL COMPONENT, AND PHOTOGRAPHIC OPTICAL SYSTEM 审中-公开
    涂料液,制造光学元件的方法和摄影光学系统

    公开(公告)号:WO2011162400A2

    公开(公告)日:2011-12-29

    申请号:PCT/JP2011/064610

    申请日:2011-06-20

    IPC分类号: C07F3/00

    摘要: A coating liquid including a fluorine-containing organic magnesium compound represented by the following chemical formula (1), a method for manufacturing an optical component having an optical film obtained from the coating liquid, and a photographic optical system are disclosed: Chemical formula (1) Mg(OR11)(OR22) where R11 represents an alkyl group that may have a substituent group having 1 or more and 6 or less carbon atoms having at least a fluorine atom, R22 represents an alkyl group that may have a substituent group having 1 or more and 6 or less carbon atoms that may have a fluorine atom, or an aromatic cyclic group that may have a substituent group, and R11 is different from R22.

    摘要翻译: 公开了包含由以下化学式(1)表示的含氟有机镁化合物的涂布液,具有由涂布液获得的光学膜的光学部件的制造方法和照相光学系统。化学式(1 )Mg(OR 11)(OR 22)其中R 11表示可以具有至少具有氟原子的碳原子数为1以上且6以下的取代基的烷基,R 22表示可以具有取代基的烷基, 可以具有氟原子的碳原子数为6个以下,也可以具有取代基的芳香族环状基团,R 11与R 22不同。

    DIESTER-BASED LUBRICANTS AND METHODS OF MAKING SAME
    3.
    发明申请
    DIESTER-BASED LUBRICANTS AND METHODS OF MAKING SAME 审中-公开
    基于喷射剂的润滑剂及其制备方法

    公开(公告)号:WO2008100822A3

    公开(公告)日:2008-10-09

    申请号:PCT/US2008053420

    申请日:2008-02-08

    IPC分类号: C10M141/02

    摘要: The present invention is generally directed to diester-based lubricant compositions. The present invention is also directed to methods of making these and other similar lubricant compositions. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor and/or low value Fischer-Tropsch (FT) olefins and/or alcohols so as to produce high value diester-based lubricants. In some embodiments, such diester-based lubricants are derived from FT olefins and fatty acids. The fatty acids can be from a bio-based source (i.e., biomass, renewable source) or can be derived from FT alcohols via oxidation.

    摘要翻译: 本发明一般涉及基于二酯的润滑剂组合物。 本发明还涉及制备这些和其它类似润滑剂组合物的方法。 在一些实施方案中,制备这种基于二酯的润滑剂的方法利用生物质前体和/或低价值的费 - 托(FT)烯烃和/或醇,以便产生高价值的基于二酯的润滑剂。 在一些实施方案中,这种基于二酯的润滑剂衍生自FT烯烃和脂肪酸。 脂肪酸可以来自生物基源(即生物质,可再生能源),或者可以通过氧化从FT醇衍生。

    DIESTER-BASED LUBRICANTS AND METHODS OF MAKING SAME
    4.
    发明申请
    DIESTER-BASED LUBRICANTS AND METHODS OF MAKING SAME 审中-公开
    基于二腈的润滑剂及其制备方法

    公开(公告)号:WO2008100822A2

    公开(公告)日:2008-08-21

    申请号:PCT/US2008/053420

    申请日:2008-02-08

    IPC分类号: C07C69/34 C10M105/36

    摘要: The present invention is generally directed to diester-based lubricant compositions. The present invention is also directed to methods of making these and other similar lubricant compositions. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor and/or low value Fischer-Tropsch (FT) olefins and/or alcohols so as to produce high value diester-based lubricants. In some embodiments, such diester-based lubricants are derived from FT olefins and fatty acids. The fatty acids can be from a bio-based source (i.e., biomass, renewable source) or can be derived from FT alcohols via oxidation.

    摘要翻译: 本发明总体上涉及二酯基润滑剂组合物。 本发明还涉及制造这些和其他类似润滑剂组合物的方法。 在一些实施方案中,用于制造这种基于二酯的润滑剂的方法利用生物质前体和/或低价值费 - 托(FT)烯烃和/或醇以生产高价值的二酯基润滑剂。 在一些实施方案中,这种二酯基润滑剂衍生自FT烯烃和脂肪酸。 脂肪酸可以来自生物基源(即生物质,可再生来源)或可以通过氧化从FT醇衍生而来。

    ClO DIALDEHYDE, SYNTHETIC METHOD THEREOF, AND SYNTHETIC METHOD OF BETA-CAROTENE USING THE SAME
    5.
    发明申请
    ClO DIALDEHYDE, SYNTHETIC METHOD THEREOF, AND SYNTHETIC METHOD OF BETA-CAROTENE USING THE SAME 审中-公开
    二氢吲哚,其合成方法及其合成方法

    公开(公告)号:WO2006038764A1

    公开(公告)日:2006-04-13

    申请号:PCT/KR2005/002273

    申请日:2005-07-15

    IPC分类号: C07C403/14

    摘要: The novel intermediate compound which can be efficiently utilized in the synthesis of carotenoid compounds based on the sulfone chemistry, the preparation method of the same, and the practical synthetic process for preparing β-carotene by the use of the above novel compound are disclosed. The synthesis of β-carotene is characterized by the double elimination reactions of the C 40 compound containing both the benzenesulfonyl group and the group X (either halogen or ether), which can be prepared by the coupling reaction of the novel C 10 dialdehyde with two equivalents of the C 15 allylic sulfone, followed by the functional group transformation of the resulting C 40 diol either to the corresponding halide or to the ether, to produce the fully conjugated polyene chain.

    摘要翻译: 公开了可以有效利用基于砜化学的类胡萝卜素化合物的新型中间体化合物及其制备方法,以及通过使用上述新化合物制备β-胡萝卜素的实际合成方法。 β-胡萝卜素的合成的特征在于含有苯磺酰基和X基团(卤素或醚)的C 40 SO 4化合物的双重消除反应,其可以通过偶联反应制备 该新的C 10二醛与两当量的C 15-20烯丙基砜,随后将所得C 40-40二醇的官能团转化为 相应的卤化物或醚,以产生完全共轭的多烯链。

    AN IMPROVED PROCESS FOR THE SYNTHESIS OF UNSATURATED ALCOHOLS
    6.
    发明申请
    AN IMPROVED PROCESS FOR THE SYNTHESIS OF UNSATURATED ALCOHOLS 审中-公开
    用于合成不饱和醇的改进方法

    公开(公告)号:WO2005040077A2

    公开(公告)日:2005-05-06

    申请号:PCT/US2004/030020

    申请日:2004-09-14

    IPC分类号: C07C29/44

    摘要: A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.

    摘要翻译: 一种制备不饱和醇(烯烃)的方法,例如均聚单醇或均烯基多元醇,包括保护羟基取代的不饱和脂肪酸或脂肪酸酯如蓖麻油酸甲酯,其衍生自 种子油,形成羟基保护的不饱和脂肪酸或脂肪酸酯; 羟基保护的不饱和脂肪酸或脂肪酸酯的均匀化或交叉变性以产生含有羟基保护的非饱和复分解产物的产物混合物; 并在足以制备不饱和醇的条件下脱保护羟基保护的不饱和复分解产物。 优选地,蓖麻油酸甲酯通过交叉复分解或均一复分解转化成均相烯醇1-癸烯-4-醇或均烯基多元醇9-十八碳烯-7,12-二醇。

    METATHESIS SYNTHESES OF PHEROMONES OR THEIR COMPONENTS
    7.
    发明申请
    METATHESIS SYNTHESES OF PHEROMONES OR THEIR COMPONENTS 审中-公开
    金属或其组分的特征合成

    公开(公告)号:WO01036368A2

    公开(公告)日:2001-05-25

    申请号:PCT/US2000/031549

    申请日:2000-11-17

    摘要: The present invention relates to metathesis syntheses for insect sex-attractant pheromones or their components, such as E-5-decenyl acetate, the major component of the Peach Twig Borer pheromone; (5R, 6S)-6-acetoxy-5-hexadecanolide, the mosquito oviposition attractant pheromone; E9, Z11-hexadecadienal, the pecan nut casebearer moth pheromone; 9-tetradecenyl formate, an analog of the Diamondback Moth (DBM) pheromone; 11-tetradecenyl acetate, the Omnivorous Leafroller (OLR) pheromone; E-4-tridecenyl acetate, the major component of the Tomato Pinworm (TPW) pheromone; E,E-8,10-dodecadienol, the Codling Moth (CM) pheromone. The syntheses preferably employ a Class I-IV metathesis catalyst, entail few reaction steps, use generally commercially available starting materials, and have relatively short process times. These syntheses produce good yields without the need for expensive or sophisticated equipment. The invention also provides an inexpensive route for producing omega-haloalkenols by cross-metathesizing alpha-omega-diacetoxy alkenes and alpha-omega-dihalides to yield omega-haloalkenols, which are easily converted into omega-haloalkanols under traditional hydrogenation methods.

    摘要翻译: 本发明涉及昆虫性引诱物信息素或其组分的复分解合成,例如桃ig r信息素的主要组分乙酸E-5-癸烯酯; (5R,6S)-6-乙酰氧基-5-十六内酯,蚊子引诱物信息素; E9,Z11-十六碳二烯醛,山核桃坚果壳蛾信息素; 菱形背蛾(DBM)信息素的类似物; 食品级十四碳烯(Omnivorous Rollroller)(OLR)信息素; 番茄蚕(TPW)信息素的主要组成部分为乙酸E-4-十三碳烯酯; E,E-8,10-dodecadienol,Codling Moth(CM)信息素。 该合成优选使用I-IV族复分解催化剂,需要几个反应步骤,通常使用市售的起始原料,并具有相对短的加工时间。 这些合成产生良好的产率,而不需要昂贵或复杂的设备。 本发明还提供了一种用于通过将α-ω-二乙酰氧基链烯和α-ω-二卤化物交错分离来产生ω-卤代烯醇的廉价途径,以产生ω-卤代链烯醇,其在传统氢化方法下易于转化成ω-卤代烷醇。

    POLYMERS PREPARED FROM MEVALONOLACTONE AND DERIVATIVES
    9.
    发明申请
    POLYMERS PREPARED FROM MEVALONOLACTONE AND DERIVATIVES 审中-公开
    由梅洛酮和衍生物制备的聚合物

    公开(公告)号:WO2016077555A1

    公开(公告)日:2016-05-19

    申请号:PCT/US2015/060335

    申请日:2015-11-12

    申请人: VISOLIS, INC.

    摘要: Described herein polymer precursor compounds (aka polymer building blocks) of derived from biobased compounds, and specifically biobased mevalonolactone and its related derivatives. Through oxidation these biobased precursors can be reacted to yield building blocks for (unsaturated-) polyesters, polyester polyols and polyamides, as well as precursors for glycidyl esters and omega-alkenyl esters. Through reduction, these biobased precursors can be reacted to yield building blocks for (unsaturated-) polyesters, polyester polyols, polycarbonates, as well as precursors for glycidyl ethers and omega-alkenyl ethers. Through nucleophilic ring opening and/or amidation, these biobased precursors can be reacted to yield building blocks for polyester polyols, chain-extender for polyurethanes, or polyester-amides.

    摘要翻译: 本文描述了衍生自生物基化合物的聚合物前体化合物(又名聚合物结构单元),特别是生物基甲羟戊酸内酯及其相关衍生物。 通过氧化,这些生物基的前体可以反应以产生(不饱和的)聚酯,聚酯多元醇和聚酰胺以及缩水甘油酯和ω-链烯基酯的前体的结构单元。 通过还原,这些生物基前体可以反应以产生(不饱和的)聚酯,聚酯多元醇,聚碳酸酯以及缩水甘油醚和ω-烯基醚的前体的结构单元。 通过亲核开环和/或酰胺化,这些生物基前体可以反应,以产生聚酯多元醇的结构单元,聚氨酯的增链剂或聚酯酰胺。