公开(公告)号：WO2015187778A1

公开(公告)日：2015-12-10

申请号：PCT/US2015/033900

申请日：2015-06-03

Applicant: SOLVAY SA ,  RAYTHATHA, Rasik H. ,  SAVARY, David Jean

Inventor： RAYTHATHA, Rasik H. ,  SAVARY, David Jean

IPC: A62D3/33 ,  B09B3/00 ,  A62D101/24

CPC classification number: A62D3/33 ,  A62D2101/08 ,  A62D2101/24 ,  A62D2101/43 ,  B01D53/508 ,  B01D53/64 ,  B01D53/80 ,  B01D53/83 ,  B01D53/8693 ,  B01D2251/304 ,  B01D2251/402 ,  B01D2251/404 ,  B01D2251/60 ,  B01D2251/602 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2257/302 ,  B01D2257/60 ,  B01D2258/0283 ,  B09B3/0008 ,  B09B3/0041 ,  B09B2220/06 ,  C04B18/08 ,  C04B20/1085 ,  F23J15/003 ,  F23J2215/60 ,  Y02W30/92 ,  C04B20/023

Abstract: A treatment method for stabilizing at least a portion of at least one heavy metal contained in a sodic fly ash to reduce leachability, wherein the sodic fly ash is provided by a process whereby a sodium-based sorbent is injected in a combustion flue gas to remove pollutants therefrom. The treatment method comprises contacting the sodic fly ash with at least one water-soluble source of silicate and at least one additive comprising calcium and/or magnesium. The material obtained from the contacting step is preferably dried. The additive may be selected from the group consisting of lime kiln dust, fine limestone, quicklime, hydrated lime, dolomitic lime, dolomite, selectively calcined dolomite, hydrated dolomite, magnesium hydroxide, magnesium carbonate, magnesium oxide, and any mixture thereof. A particularly preferred additive comprises lime kiln dust and/or dolomitic lime. The heavy metal to be stabilized in the sodic fly ash may comprise selenium and/or arsenic.

Abstract translation: 一种用于稳定包含在钠粉煤灰中的至少一种重金属的至少一部分以降低浸出性的处理方法，其中通过将钠基吸附剂注入燃烧烟道气以去除 污染物。 该处理方法包括使钠粉煤灰与至少一种水溶性硅酸盐源和至少一种包含钙和/或镁的添加剂接触。 从接触步骤获得的材料优选干燥。 添加剂可选自石灰窑灰，细石灰石，生石灰，熟石灰，白云石，白云石，选择性煅烧白云石，水合白云石，氢氧化镁，碳酸镁，氧化镁及其任何混合物。 特别优选的添加剂包括石灰窑灰和/或白云石灰。 在钠粉中稳定的重金属可以包含硒和/或砷。

公开(公告)号：WO01036050A1

公开(公告)日：2001-05-25

申请号：PCT/IB1999/001975

申请日：1999-11-15

IPC: A62D3/33 ,  A62D101/02 ,  A62D101/08 ,  A62D101/20 ,  A62D101/22 ,  A62D101/24 ,  A62D101/40 ,  A62D101/43 ,  A62D101/49 ,  A62D3/00

CPC classification number: A62D3/33 ,  A62D2101/02 ,  A62D2101/08 ,  A62D2101/20 ,  A62D2101/22 ,  A62D2101/24 ,  A62D2101/40 ,  A62D2101/43 ,  A62D2101/49 ,  B09C1/02 ,  B09C1/08

Abstract: Hazardous compounds are chemically treated to remove various pollutants by subjecting the compounds (samples) to various process steps, including selecting specific solvents and using them, treating the sample at room temperature or below (30 DEG C or lower); separating fatty acids mixed with heavy metal and semi-metal compounds as well as the separation of organic substances (including halogenated compounds) added to heavy metals and semi-metals; and using sodium nitrite and sodium 1-naphthylamine-4-sulfonate in combination from specific solvents, thereby forming alkylsulfonic acid salt and alkyl sulfonium salt in the presence of sulfonic acid salt so as to fix organic substances mixed in the sample.

Abstract translation: 对化合物（样品）进行各种处理步骤进行化学处理以除去各种污染物，包括选择特定溶剂并使用它们，在室温或低于（30℃或更低）下处理样品; 分离与重金属和半金属化合物混合的脂肪酸以及添加到重金属和半金属中的有机物质（包括卤化物）的分离; 并从特定溶剂中组合使用亚硝酸钠和1-萘胺-4-磺酸钠，由此在磺酸盐存在下形成烷基磺酸盐和烷基锍盐，以固定混入样品中的有机物质。

公开(公告)号：WO00048201A1

公开(公告)日：2000-08-17

申请号：PCT/US2000/003498

申请日：2000-02-10

IPC: A62D3/00 ,  A62D3/32 ,  A62D3/34 ,  A62D3/36 ,  A62D101/06 ,  A62D101/20 ,  A62D101/22 ,  A62D101/24 ,  A62D101/26 ,  A62D101/28 ,  B01D11/00 ,  B01J8/00 ,  B09B3/00 ,  B09C1/02 ,  B09C1/08 ,  C02F1/70 ,  G21F20060101 ,  G21F9/00 ,  G21F9/28

CPC classification number: B09C1/08 ,  G21F9/001 ,  G21F9/30

Abstract: Methods for decontaminating toxic waste, particularly solid carrier materials, such as soil contaminated with a toxin, or solid mixed wastes are more efficiently decontaminated with solvated electrons by first extracting the toxin from the carrier with a nitrogenous base at elevated temperatures, followed by a temperature reduction before initiating chemical reduction of the toxin with solvated electrons. Pre-extraction of the toxin at elevated temperatures followed by temperature reduction minimizes competing side reactions, improves selectivity of solvated electrons for the toxin and improves the economics of the process with more efficient metal utilization. The process can be performed without separation of the toxin from the extraction vessel holding the solid carrier material. Alternatively, elevated temperatures can be used to perform one or more extractions of toxin with nitrogenous base followed by reduction with solvated electrons by performing the reaction in a separate reactor. The processes of the invention are useful in the destruction of virtually any chemically reducible hazardous substance.

Abstract translation: 用有毒废物，特别是固体载体材料（如毒素污染的土壤）或固体混合废物进行净化的方法，通过首先在高温下用含氮碱从载体中提取毒素，再用溶剂化电解进行更有效的净化，然后加入温度 在用溶剂化电子开始化学还原毒素之前还原。 在升高的温度下预先提取毒素，随后温度降低可以减少相互竞争的副反应，提高溶剂化电子对毒素的选择性，并通过更有效的金属利用来改善该方法的经济性。 该过程可以在不将毒素从保持固体载体材料的萃取容器中分离的情况下进行。 或者，升高的温度可用于用含氮碱进行一次或多次毒素提取，然后通过在单独的反应器中进行反应而用溶剂化电子还原。 本发明的方法可用于几乎任何化学还原性有害物质的破坏。

公开(公告)号：WO99044688A1

公开(公告)日：1999-09-10

申请号：PCT/IT1998/000046

申请日：1998-03-04

IPC: A62D3/33 ,  A62D3/36 ,  A62D101/08 ,  A62D101/24 ,  A62D101/43 ,  A62D3/00

CPC classification number: A62D3/33 ,  A62D3/36 ,  A62D2101/08 ,  A62D2101/24 ,  A62D2101/43

Abstract: Method for treating waste material contaminated with heavy metals so as to make it inert, characterized in that the material to be made inert, optionally at least in part neutralized, is subjected to the following operations, optionally under stirring: addition of a concentrate aqueous solution of orthophosphoric acid and of an alkaline or alkaline earth salt thereof in a molar ratio ranging from 1:5 to 5:1; optionally addition of water to give the homogeneous paste thus obtained a sufficient moisture content; addition of calcium hydroxide and/or calcium oxide; the resulting homogeneous paste being placed in the open air to help it dry out. The material thus obtained is fit to be disposed according to local environmental legislation.

Abstract translation: 用于处理被重金属污染的废物以使其变得惰性的方法，其特征在于，任选地至少部分中和的待制成惰性的材料，任选地在搅拌下进行以下操作：加入浓缩水溶液 的正磷酸及其碱金属或碱土金属盐的摩尔比为1:5至5:1; 任选加入水，得到均匀的糊状物，从而得到足够的水分含量; 加入氢氧化钙和/或氧化钙; 所得均匀的糊状物置于露天的空气中以帮助其干燥。 由此获得的材料适合根据当地环境立法处理。

公开(公告)号：WO2022224951A1

公开(公告)日：2022-10-27

申请号：PCT/JP2022/018147

申请日：2022-04-19

Applicant: 株式会社トクヤマ

Inventor： 安孫子　大祐 ,  三浦　公大 ,  一ノ瀬　亘 ,  磯村　武範

IPC: C07C29/74 ,  C07C31/125 ,  A62D3/176 ,  A62D101/24 ,  B01J19/12 ,  B01J19/24

Abstract: 棒状の紫外線光源の周りに、紫外線被照射物が流通する流通管が螺旋状に巻回されている、紫外線照射装置を提供する。また、不純物として、有機鉛化合物を含む有機化合物を精製する方法であって、上記の紫外線照射装置を用いて、前記有機化合物に紫外線を照射する工程と、前記有機化合物から、前記有機鉛化合物に前記紫外線を照射することにより生成する鉛成分を除去する工程と、を含む、有機化合物の精製方法を提供する。

公开(公告)号：WO2019050389A1

公开(公告)日：2019-03-14

申请号：PCT/MY2018/050025

申请日：2018-05-02

Applicant: UNIVERSITI SAINS MALAYSIA

Inventor： FURUSAWA, Go ,  CHIANG, Pui Nyuk ,  CHONG, Shu Chien @ Alexander ,  ABDULLAH, Amirul Al-Ashraf Balakrishnan

IPC: C02F3/34 ,  C02F1/52 ,  C02F1/62 ,  C02F1/64 ,  C02F101/20 ,  C02F101/30 ,  A62D3/02 ,  A62D101/20 ,  A62D101/24 ,  A62D101/40 ,  C12N11/00

Abstract: The present invention relates to a method of producing an article suitable for use as a bioflocculant or a biosorbent for waste material and heavy metal removal. The method preferably comprises the steps of growing cells of a marine filamentous bacterium in a culture medium to achieve a log phase of bacteria growth (100); harvesting by way of separating the said cells of marine filamentous bacterium from the culture medium (200), wherein the step of harvesting includes centrifugation; and fixing the harvested cells of marine filamentous bacterium by subjecting the same to treatment with formaldehyde (300), wherein the said article comprises the fixed cells of marine filamentous bacterium.

公开(公告)号：WO2014086921A1

公开(公告)日：2014-06-12

申请号：PCT/EP2013/075651

申请日：2013-12-05

Applicant: SOLVAY SA

Inventor： RAYTHATHA, Rasik H. ,  SAVARY, David Jean Lucien

IPC: B09B3/00 ,  B01D53/73 ,  B01D53/81 ,  C22B7/02 ,  A62D101/24

CPC classification number: A62D3/33 ,  A62D2101/08 ,  A62D2101/24 ,  A62D2101/43 ,  B01D53/40 ,  B01D53/83 ,  B01D2251/304 ,  B01D2251/402 ,  B01D2257/204 ,  B01D2257/302 ,  B01D2257/404 ,  B09B3/0008 ,  B09B3/0041 ,  B09B2220/06

Abstract: A treatment method for reducing the leachability of selenium contained in a sodic fly ash which is provided by a combustion process when a sodium-based sorbent comes in contact with a flue gas generated by combustion to remove at least a portion of pollutants contained in the flue gas. The method comprises: (a) contacting the sodic fly ash with at least one additive in the presence of water; and (b) drying the material (preferably a paste) from step (a) to form a dried matter. The additive may comprise at least one strontium-containing compound, at least one barium-containing compound, dolomite, a dolomite derivative such as calcined or hydrated dolomite, at least one silicate-containing compound, or any combinations of two or more thereof. A particularly suitable additive may comprise strontium chloride, strontium hydroxide, pulverized dolomitic lime, sodium silicate, or any combinations of two or more thereof.

Abstract translation: 一种用于降低由钠基吸附剂与燃烧产生的烟道气接触的燃烧过程中所提供的钠液中的硒的浸出性的处理方法，以除去烟道中所含的至少一部分污染物 加油站。 该方法包括：（a）在水存在下使钠粉与至少一种添加剂接触; 和（b）从步骤（a）中干燥材料（优选糊状物）以形成干物质。 添加剂可以包含至少一种含锶化合物，至少一种含钡化合物，白云石，白云石衍生物如煅烧或水合白云石，至少一种含硅酸盐的化合物，或其两种或多种的任何组合。 特别合适的添加剂可以包括氯化锶，氢氧化锶，粉碎的白云石石灰，硅酸钠或其两种或更多种的任何组合。

公开(公告)号：WO2009057300A1

公开(公告)日：2009-05-07

申请号：PCT/JP2008/003091

申请日：2008-10-29

Applicant: 日本板硝子株式会社 ,  中村浩一郎

Inventor： 中村浩一郎

IPC: A62D3/30 ,  A62D3/176 ,  B01J35/02 ,  A62D101/24 ,  A62D101/43 ,  A62D101/47

CPC classification number: A62D3/10 ,  A62D3/176 ,  A62D3/30 ,  A62D3/33 ,  A62D2101/24 ,  A62D2101/43 ,  A62D2101/47 ,  B01J21/063 ,  B01J23/10

Abstract: 　ヒ素等を含む有害化合物を効率的に無害化するのに有益な有害化合物の無害化方法を提供することを目的とする。 　本発明の有害化合物の無害化方法は、メチルラジカル、及び／又はカルボキシメチルラジカルを、ヒ素、アンチモン、セレンからなる群から選択される少なくとも１種の元素を含有する有害化合物に接触させることにより前記有害化合物を無害化することを特徴とする。また、本発明の有害化合物の無害化方法の好ましい実施態様において、前記ラジカルを、光照射により生じさせることを特徴とする。また、本発明の有害化合物の無害化方法の好ましい実施態様において、前記ラジカルの供給源が、酢酸、メタノール、エタノール、無水酢酸、プロピオン酸、ブタン酸又は蟻酸からなる群から選択される少なくとも1種であることを特徴とする。

Abstract translation: 公开了一种有毒化合物解毒方法，其有效地用于含砷等有毒化合物的解毒。 有毒化合物解毒方法的特征在于使甲基和/或羧甲基基团与含有选自砷，锑和硒中的至少一种元素的有毒化合物接触以使毒性化合物解毒。 在毒性化合物解毒方法的优选实施方案中，通过用光照射产生自由基。 在毒性化合物解毒方法的另一个优选实施方案中，自由基的供应源是选自乙酸，甲醇，乙醇，乙酸酐，丙酸，丁酸和甲酸中的至少一种。

公开(公告)号：WO98030499A1

公开(公告)日：1998-07-16

申请号：PCT/US1998/000789

申请日：1998-01-12

IPC: A62D3/00 ,  A62D3/30 ,  A62D3/38 ,  A62D101/20 ,  A62D101/22 ,  A62D101/24 ,  A62D101/26 ,  A62D101/43 ,  A62D101/45 ,  A62D101/49 ,  C22B7/00 ,  C22B21/00 ,  C01F7/00 ,  C09K3/00

CPC classification number: A62D3/38 ,  A62D2101/20 ,  A62D2101/24 ,  A62D2101/43 ,  A62D2101/45 ,  A62D2101/49 ,  A62D2203/02 ,  C22B7/007 ,  C22B21/0069 ,  Y02P10/234

Abstract: The method of the present invention detoxifies spent aluminum potliners to remove hazardous cyanides, fluorides, and polynuclear aromatics by reacting crushed potliners with a CaC12/HC1 leach mill solution in the presence of iron. The method produces a solid waste suitable for landfill disposal and a recyclable reaction liquor. The reaction to destroy the polynuclear aromatics preferably occurs at a pH of no more than about 0.2, at about 120 DEG C and 80 psig following destruction of the cyanides and converting of the fluorides to florspar in an initial oxidation at a lower temperature, lower pressure, and higher pH.

Abstract translation: 本发明的方法通过在铁的存在下使压碎的锅炉与CaCl 2 / HCl浸出机溶液反应来消除废铝锅炉以除去有害的氰化物，氟化物和多环芳烃。 该方法产生适合垃圾填埋处理的固体废物和可回收的反应液。 破坏多核芳族化合物的反应优选在不超过约0.2的pH下，在氰化物破坏后在约120℃和80psig下进行，并且在较低温度下的初始氧化中将氟化物转化成florspar ，和较高的pH值。

公开(公告)号：WO2018065949A1

公开(公告)日：2018-04-12

申请号：PCT/IB2017/056178

申请日：2017-10-06

Applicant: EUREKA RICERCA E SOLUZIONI GLOBALI SOCIETA' COOPERATIVA

Inventor： NASTATI, Enzo

IPC: B09C1/00 ,  B09C1/08 ,  B09C1/10 ,  A62D3/02 ,  C02F3/00 ,  C02F11/14 ,  A62D101/04 ,  A62D101/22 ,  A62D101/24 ,  A62D101/41 ,  C02F103/06

Abstract: A method is described for preparing a product adapted for stimulation and enhancement of processes of reduction, transformation and metabolization of polluting substances that are present in soils and/or waters, the method comprising the following steps: a first step comprising: - preparing a totally natural mineral substance based on Magnesium Potassium Sulphate, "activating" said mineral substance by mixing it for a time of 3' 23", with a tolerance of plus-minus 10 seconds; a second step comprising: making an organic -base product obtained by burying bovine manure inserted in cow horns into weakly calcareous soil (pH 7.5-8.0) for a period lasting from the autumn to the following spring; - thereafter, dynamizing said organic -base product by mixing a part thereof into 99 parts of distilled water, thereby obtaining a liquid substance; said dynamization comprising a first active phase of succussions for 60 seconds, followed by a pause of 80 seconds, in turn followed by a second active phase of succussions for additional 60 seconds, said liquid substance is then diluted again with distilled water in a proportion of 1 to 99 and then further dynamized with said succussions followed by pauses, repeated 5 more times; a third step comprising: combining the product obtained in the first step with the product obtained in the second step, in a proportion of 1 ml of product of the second step for 1 kg of product of the first step; "activating" said combination by mixing it for a period of 5' 25" (with a tolerance of plus-minus 10 seconds), thereby obtaining said product adapted for stimulation and enhancement.

Abstract translation: 描述了一种用于制备适用于刺激和增强存在于土壤和/或水中的污染物质的还原，转化和代谢过程的产品的方法，所述方法包括以下步骤：a 第一步包括： - 制备基于硫酸镁钾的完全天然的矿物质，“活化” 所述矿物质通过混合3'23“的时间，具有正负10秒的耐受性; 第二步包括：将通过将插入牛角中的牛粪埋入弱石灰质土壤（pH7.5-8.0）中获得的有机碱产物持续从秋季到随后的春季; 之后，通过将其一部分混合到99份蒸馏水中来使所述有机碱产物动态化，从而获得液体物质; 所述动力化包括持续60秒的第一积极活跃阶段，随后是80秒的暂停，随后又持续60秒的第二积极活动阶段，然后所述液体物质再次用蒸馏水稀释，其比例为 1到99，然后进一步动力化，然后再次停顿5次; 第三步骤包括：将第一步骤中获得的产物与第二步骤中获得的产物以1ml第一步骤的产物的第二步骤的产物的比例组合; ＆QUOT;激活＆QUOT; 所述组合通过将其混合5'25“ （具有正负10秒的容差），从而获得适用于刺激和增强的所述产品。