Abstract:
L'invention concerne un procédé de synthèse d'un polymère porteur d'un ou plusieurs groupements hydroxyaryle pendants comprenant la réaction d'un polymère portant une ou plusieurs fonctions époxyde pendantes avec un composé nucléophile à la fois porteur du groupement hydroxyaryle et porteur d'une fonction nucléophile choisie dans le groupe constitué par la fonction aminé primaire, la fonction aminé secondaire, la fonction acide carboxylique et leur forme ionique. L'invention concerne également le polymère, en particulier un élastomère, issu de ce procédé, ainsi qu'une composition de caoutchouc le contenant.
Abstract:
The present invention refers to a resin composition comprising an ester compound and a polymer, wherein the ester compound and the polymer are obtainable by reacting a diene, a dienophile and a carboxylic acid. The invention also refers to adhesive compositions comprising the resin composition.
Abstract:
Process for the production of statistic elastomeric conjugated diene-vinyl arene copolymers having a branched structure which comprises: (1) anionic copolymerization in solution of the conjugated diene and vinyl arene monomers, in the presence of randomizing agents and an initiator selected from the group of Lithium alkyls, the copolymerization being carried out until the almost total disappearance of the monomers; (2) addition to the solution of step (1) of a quantity of Lithium alkyl from 1 to 4 times the molar quantity of the Lithium alkyl of step (1); (3) addition to the polymeric solution of step (2) of a compound having the general formula R-Br, the molar ratio between R-Br and the total Lithium alkyl ranging from 0.6/1 to 1/1, preferably from 0.7/1 to 0.9/1, thus obtaining an elastomeric branched copolymer.
Abstract:
A halogenated butyl polymer having improved properties, the butyl polymer derived from a monomer mixture comprising a C4 to C8 monoolefin monomer, a C4 to C14 multiolefin monomer and a styrenic monomer with a catalyst system to produce the butyl polymer. The improved properties include faster cure, higher maximum torque, higher delta torque, relatively stable modulus over time, improved hot air aging properties and improved aged flexure properties. These improved properties are believed to result from direct interaction between the styrenic moieties in the polymer backbone with a crosslinking agent added to vulcanize the halogenated butyl rubber.
Abstract:
This present disclosure relates to catalytic processes for upgrading crude and/or refined fusel oil mixtures to higher value renewable chemicals, via mixed metal oxide or zeolite catalysts. Disclosed herein are processes passing a vaporized stream of crude and/or refined fusel oils over various mixed metal oxide catalysts, metal doped zeolites, or non-metal doped zeolites and/or metal oxides providing options to valorize fusel oil mixtures to higher value products. Renewable chemicals formed, via these upgrading catalyst platforms, are comprised of, but not limited to, methyl isobutyl ketone (MIBK), di-isobutyl ketone (DIBK), isoamylene, and isoprene.
Abstract:
A process for preparing a butyl polymer having a broad molecular weight distribution. The process comprises the step of contacting a C4 to C8 monoolefin monomers with a C4 to C14 multiolefin monomer at a temperature in the range of from about -100 DEG C to about +50 DEG C in the presence of a diluent and a catalyst mixture comprising a major amount of a dialkylalumium halide, a minor amount of a monoalkylaluminum dihalide, and a minute amount of an aluminoxane.
Abstract:
The invention relates to a method for producing powder-shaped, cationic cross-linked polymerizates based on monoethylenically unsaturated monomers which contain a quaternized or a quaternizable nitrogen atom. The inventive method is characterized in that the polymerization is carried out in supercritical carbon dioxide used as an inert diluting agent while thoroughly mixing at temperatures ranging between 31 DEG C to 150 DEG C and under pressures greater than 73 bar.