Invention Grant
- Patent Title: Process for preparing methacrylic acid or methacrylic esters
- Patent Title (中): 制备甲基丙烯酸或甲基丙烯酸酯的方法
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Application No.: US12602593Application Date: 2008-05-30
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Publication No.: US09234218B2Publication Date: 2016-01-12
- Inventor: Achim Marx , Markus Poetter , Stefan Buchholz , Alexander May , Hermann Siegert , Birgit Alber , Georg Fuchs , Lothar Eggeling
- Applicant: Achim Marx , Markus Poetter , Stefan Buchholz , Alexander May , Hermann Siegert , Birgit Alber , Georg Fuchs , Lothar Eggeling
- Applicant Address: DE Darmstadt
- Assignee: EVONIK ROEHM GmbH
- Current Assignee: EVONIK ROEHM GmbH
- Current Assignee Address: DE Darmstadt
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: EPPCT/EP2007/055394 20070601
- International Application: PCT/EP2008/056707 WO 20080530
- International Announcement: WO2008/145737 WO 20081204
- Main IPC: C12P7/42
- IPC: C12P7/42 ; C12P7/52 ; C12N9/02 ; C12P7/40 ; C12P7/62 ; C08F120/06 ; C08F120/10 ; C12N9/10 ; C12N9/16 ; C12N9/88

Abstract:
The present invention relates to a process for the preparation of methacrylic acid or methacrylic esters, comprising the process steps of IA) preparation of 3-hydroxyisobutyric acid by a process comprising the process step of bringing a cell which has been genetically modified in comparison with its wild type in such a way that it is capable of forming more 3-hydroxyisobutyric acid, or polyhydroxyalkanoates based on 3-hydroxyisobutyric acid in comparison with its wild type, into contact with a nutrient medium comprising, as carbon source, carbohydrates, glycerol, carbon dioxide, methanol, L-valine or L-glutamate under conditions under which 3-hydroxyisobutyric acid or polyhydroxyalkanoates based on 3-hydroxyisobutyric acid are formed from the carbon source, if appropriate, isolation of the 3-hydroxyisobutyric acid from the nutrient medium and also, if appropriate, neutralization of the 3-hydroxyisobutyric acid, IB) dehydration of the 3-hydroxyisobutyric acid with formation of methacrylic acid and also, where appropriate, esterification methacrylic acid. The invention also relates to a process for the preparation of polymethacrylic acid or polymethacrylic esters.
Public/Granted literature
- US20100291644A1 PROCESS FOR PREPARING METHACRYLIC ACID OR METHACRYLIC ESTERS Public/Granted day:2010-11-18
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