公开(公告)号：EP2889316A1

公开(公告)日：2015-07-01

申请号：EP13831061.0

申请日：2013-08-20

Applicant: Asahi Glass Company, Limited

Inventor： KANEKO, Kyouichi ,  SUGIYAMA, Kazunori ,  SHIMADA, Minako ,  HIRONO, Takao ,  FUKUDA, Reika

IPC: C08F220/24 ,  C07C67/47 ,  C07C69/54 ,  C09K3/18 ,  D06M15/248 ,  D06M15/277

CPC classification number: C09K3/18 ,  C07C67/11 ,  C08F22/10 ,  C08F220/10 ,  C08F220/22 ,  C08F220/24 ,  D06M15/248 ,  D06M15/277 ,  C07C69/653

Abstract: To provide a fluorinated copolymer which presents little burden on the environment and is capable of imparting excellent water repellency to a surface of an article, a process for its production, a water repellent composition using such a fluorinated copolymer, and an article having a surface treated with such a water repellent composition.
A fluorinated copolymer comprising, in specific ratios, units derived from F(CF 2 ) 6 CH 2 CH 2 OC(O)C(CH 3 )=CH 2 , units derived from vinyl chloride, units derived from vinylidene chloride, units derived from an alkyl (meh)acrylate having a C 12-30 alkyl group, and units derived from a monomer having no fluoroalkyl group and having a cross-linkable functional group, wherein units derived from F(CF 2 ) n CH 2 CH 2 OC(O)C(CH 3 )=CH 2 (wherein n is an integer of from 1 to 5) are in at most a specific ratio; a water repellent composition containing such a fluorinated copolymer; and an article treated with such a water repellent composition.

公开(公告)号：EP2166059B1

公开(公告)日：2015-09-02

申请号：EP08765482.8

申请日：2008-06-11

Applicant: Asahi Glass Company, Limited

Inventor： SUGIYAMA, Kazunori ,  KANEKO, Kyouichi ,  OOMORI, Yuuichi

IPC: C08F220/24 ,  C09K3/18 ,  C08F216/12 ,  C08F218/04 ,  C08F220/22 ,  D06M15/277 ,  D06M15/256 ,  D06M15/263 ,  D06M15/53 ,  C08F220/36 ,  C09D133/16 ,  C08F220/28 ,  C08F238/00 ,  C08F220/18

CPC classification number: D06M15/277 ,  C08F220/24 ,  C08F220/36 ,  C08F238/00 ,  C08F2220/1891 ,  C08F2220/286 ,  C09D133/16 ,  D06M15/256 ,  D06M15/263 ,  D06M15/53 ,  D06M2200/11 ,  D06M2200/12

公开(公告)号：EP2703466A1

公开(公告)日：2014-03-05

申请号：EP12777818.1

申请日：2012-04-19

Applicant: Asahi Glass Company, Limited

Inventor： KANEKO, Kyouichi ,  SUGIYAMA, Kazunori ,  FUKUDA, Reika ,  HIRONO, Takao

IPC: C09K3/18 ,  C08F220/22 ,  C08K5/06 ,  C08K5/20 ,  C08L33/16

CPC classification number: C09D5/00 ,  C08F214/06 ,  C08F214/18 ,  C08F214/182 ,  C08F214/184 ,  C08F220/22 ,  C08K5/06 ,  C08K5/20 ,  D06M15/248 ,  D06M15/263 ,  D06M15/273 ,  D06M15/277 ,  D06M15/3562 ,  D06M15/3564 ,  D06M2200/11 ,  D06M2200/12 ,  C08F218/08 ,  C08F2220/1875 ,  C08F220/20 ,  C08F214/08 ,  C08F220/18 ,  C08L33/16

Abstract: To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition.
A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C 1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20°C, monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.

Abstract translation: 提供一种拒水/油性组合物，其可赋予足够的空气后干燥拒水/油性到制品的表面上，并且其呈现出低的环境影响，并制品具有在其表面处理与拒水/油性组合物 ， 甲拒水/油性组合物，包含具有基于单体的构成单元的共聚物（A）（a）中，基于单体的结构单元（b），基于单体（c）和/或结构单元的结构单元基于一个 单体（d）; 和水性介质（b）含有水和成膜助剂（x）和/或成膜助剂（Y）。 单体（a）：具有C 1-6氟烷基的单体，单体（b）：偏二氯乙烯，单体（c）：单体，其均聚物具有至少20℃，单体（玻璃化转变温度 D）：特定的酰胺溶剂，成膜助剂（Y）：具有交联性官能团，成膜助剂（X）的单体的具体二醇溶剂。

公开(公告)号：EP3009488A1

公开(公告)日：2016-04-20

申请号：EP14811439.0

申请日：2014-06-11

Applicant: Asahi Glass Company, Limited

Inventor： SUGIYAMA, Kazunori ,  KANEKO, Kyouichi ,  MASUDA, Sho

IPC: C09K3/18

Abstract: To provide a water/oil repellent composition which is excellent in the stability as a working liquid and the water repellency whereby the occurrence of scum having a high adhesion is low, to provide its production process and to provide an article of which the surface is treated with the water/oil repellent composition whereby the occurrence of dirt is suppressed.
A water/oil repellent composition which comprises a nonionic surfactant having a melting point of from 50°C to 70°C, a fluorinated copolymer (for example, a copolymer of a (meth)acrylate having a C 6 perfluoroalkyl group) and a medium containing water.

Abstract translation: 提供一种拒水/油性组合物，所有这些都具有优异的稳定性作为工作液体和防水性，由此具有高的粘附性的浮渣的发生低，以提供其生产过程，并提供给其中的物品的表面进行处理 与拒水/油性组合物，其中的污垢的发生被抑制。 甲拒水/油性组合物，包括具有熔点的非离子型表面活性剂从50℃至70℃，含氟共聚物（例如，（甲基的共聚物）丙烯酸酯具有C 6全氟烷基）和一个介质 含有水。

公开(公告)号：EP2166059A1

公开(公告)日：2010-03-24

申请号：EP08765482.8

申请日：2008-06-11

Applicant: Asahi Glass Company, Limited

Inventor： SUGIYAMA, Kazunori ,  KANEKO, Kyouichi ,  OOMORI, Yuuichi

IPC: C09K3/18 ,  C08F216/12 ,  C08F218/04 ,  C08F220/22 ,  D06M15/277

CPC classification number: D06M15/277 ,  C08F220/24 ,  C08F220/36 ,  C08F238/00 ,  C08F2220/1891 ,  C08F2220/286 ,  C09D133/16 ,  D06M15/256 ,  D06M15/263 ,  D06M15/53 ,  D06M2200/11 ,  D06M2200/12

Abstract: To provide a water/oil repellent composition which can impart water/oil repellency to a surface of an article without having its texture deteriorated, and has excellent durability against washing and stability, a method for producing such a composition, and an article treated with such a water/oil repellent composition.
A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z-Y) n X; wherein Z is a C 1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no R f group and having a C 12-18 alkyl group; and monomer (c) is monomer (c1) having no R f group and having a blocked isocyanate group or monomer (c2) having no R f group and having at least two polymerizable unsaturated groups.

Abstract translation: 提供一种斥水斥油剂组合物，其可以赋予制品表面斥水斥油性，而不会使其质地恶化，并且具有优异的耐洗涤耐久性和稳定性，制备这种组合物的方法和用这种方法处理的制品 斥水斥油剂组合物。 包含具有衍生自单体（a）的聚合单元，衍生自单体（b）的聚合单元和源自单体（c）的聚合单元）的共聚物的斥水斥油剂组合物。 这里，单体（a）是由式（Z-Y）n X表示的化合物， 其中Z为C 1-6全氟烷基等; Y是二价有机基团或单键; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有R f基并具有C 12-18烷基的（甲基）丙烯酸酯; 单体（c）是不具有R f基且具有封端异氰酸酯基的单体（c1）或不具有R f基且具有至少两个可聚合不饱和基团的单体（c2）。

公开(公告)号：EP2703466B1

公开(公告)日：2018-07-11

申请号：EP12777818.1

申请日：2012-04-19

Applicant: Asahi Glass Company, Limited

Inventor： KANEKO, Kyouichi ,  SUGIYAMA, Kazunori ,  FUKUDA, Reika ,  HIRONO, Takao

IPC: C09K3/18 ,  C08F220/22 ,  C08K5/06 ,  C08K5/20 ,  C08L33/16 ,  C09D133/16 ,  D06M15/277 ,  C08L71/02 ,  C09D127/08

CPC classification number: C09D5/00 ,  C08F214/06 ,  C08F214/18 ,  C08F214/182 ,  C08F214/184 ,  C08F220/22 ,  C08K5/06 ,  C08K5/20 ,  D06M15/248 ,  D06M15/263 ,  D06M15/273 ,  D06M15/277 ,  D06M15/3562 ,  D06M15/3564 ,  D06M2200/11 ,  D06M2200/12 ,  C08F218/08 ,  C08F2220/1875 ,  C08F220/20 ,  C08F214/08 ,  C08F220/18 ,  C08L33/16

Abstract: To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C 1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20°C, monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.

公开(公告)号：EP3315578A1

公开(公告)日：2018-05-02

申请号：EP16814283.4

申请日：2016-06-17

Applicant: Asahi Glass Company, Limited

Inventor： KANEKO, Kyouichi ,  SUGIYAMA, Kazunori ,  FUKUDA, Reika

IPC: C09K3/18 ,  C08F214/08 ,  C08F220/18 ,  C08F220/24 ,  C08F220/56 ,  D06M15/248 ,  D06M15/263 ,  D06M15/277 ,  D06M15/295

CPC classification number: C09K3/18 ,  C08F214/08 ,  C08F220/24 ,  C08F220/58 ,  D06M15/248 ,  D06M15/263 ,  D06M15/277 ,  D06M15/295 ,  D06M2200/12 ,  C08F2220/1875

Abstract: To provide a water repellent composition whereby it is possible to obtain an article having excellent hot water repellency and dry soil resistance, a method for producing the water repellent composition, and an article excellent in hot water repellency and dry soil resistance. The water repellent composition comprises a copolymer having structural units based on monomer (a), structural units based on monomer (b), and structural units based on monomer (c) in specific proportions, and an aqueous medium. Monomer (a): compound represented by R F -Q-Z-C(O)C(R)=CH 2 (R F : C 4-6 perfluoroalkyl group, Q: divalent hydrocarbon group or single bond, Z: -O- or -NH-, R: methyl group or chlorine atom). Monomer (b): (meth)acrylate having cyclic hydrocarbon group, of which the homopolymer has a glass transition temperature of at least 50°C. Monomer (c): vinylidene chloride.

Abstract translation: 为了提供可以获得具有优异的热水排斥性和耐干污垢性的制品的防水剂组合物，制备该防水剂组合物的方法，以及具有优异的防水性和耐干污性的制品。 拒水组合物包含具有特定比例的基于单体（a）的结构单元，基于单体（b）的结构单元和基于单体（c）的结构单元的共聚物以及水性介质。 单体（a）：RF-QZC（O）C（R）= CH 2（RF：C 4-6全氟烷基，Q：二价烃基或单键，Z：-O-或-NH-，R： 甲基或氯原子）。 单体（b）：具有环状烃基的（甲基）丙烯酸酯，其均聚物的玻璃化转变温度至少为50℃。 单体（c）：偏二氯乙烯。

公开(公告)号：EP2006343A9

公开(公告)日：2009-07-29

申请号：EP07740422.6

申请日：2007-03-29

Applicant: Asahi Glass Company, Limited

Inventor： FURUTA, Shoji ,  SHIMADA, Minako ,  KANEKO, Kyouichi ,  SUGIYAMA, Kazunori

IPC: C09K3/18 ,  C08F220/22 ,  C09D133/16 ,  D06M15/277

CPC classification number: C08F220/24 ,  C08F220/18 ,  C08F2220/325 ,  C08F2220/365 ,  C08L33/16 ,  C08L2205/02 ,  C09D133/16 ,  C09K3/18 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12 ,  C08L2666/06

Abstract: To provide a liquid repellent composition which is excellent in liquid repellency and durability and an article having a liquid repelling film.
A liquid repellent composition comprising a copolymer (I) and a copolymer (II), characterized in that the copolymer (I) containing from 65 to 95 mass% of a polymerized unit (a) (referred to as "[a 1 ]") and from 1 to 30 mass% of a polymerized unit (b); and the copolymer (II) containing from 25 to 80 mass% of a polymerized unit (a) (referred to as "[a 2 ]") and from 1 to 50 mass% of a polymerized unit (c) are contained in an amount of the copolymer (I)/the copolymer (II)=10/90 to 95/5 (mass ratio), and [a 1 ]-[a 2 ]≧10 (mass%).

公开(公告)号：EP2006343B1

公开(公告)日：2011-01-26

申请号：EP07740422.6

申请日：2007-03-29

Applicant: Asahi Glass Company, Limited

Inventor： FURUTA, Shoji ,  SHIMADA, Minako ,  KANEKO, Kyouichi ,  SUGIYAMA, Kazunori

IPC: C09K3/18 ,  C08F220/22 ,  C09D133/16 ,  D06M15/277 ,  C08L33/16

CPC classification number: C08F220/24 ,  C08F220/18 ,  C08F2220/325 ,  C08F2220/365 ,  C08L33/16 ,  C08L2205/02 ,  C09D133/16 ,  C09K3/18 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12 ,  C08L2666/06

Abstract: To provide a liquid repellent composition which is excellent in liquid repellency and durability and an article having a liquid repelling film. A liquid repellent composition comprising a copolymer (I) and a copolymer (II), characterized in that the copolymer (I) containing from 65 to 95 mass% of a polymerized unit (a) (referred to as "[a 1 ]") and from 1 to 30 mass% of a polymerized unit (b); and the copolymer (II) containing from 25 to 80 mass% of a polymerized unit (a) (referred to as "[a 2 ]") and from 1 to 50 mass% of a polymerized unit (c) are contained in an amount of the copolymer (I)/the copolymer (II)=10/90 to 95/5 (mass ratio), and [a 1 ]-[a 2 ]‰§10 (mass%).

公开(公告)号：EP2006343A2

公开(公告)日：2008-12-24

申请号：EP07740422.6

申请日：2007-03-29

Applicant: Asahi Glass Company, Limited

Inventor： FURUTA, Shoji ,  SHIMADA, Minako ,  KANEKO, Kyouichi ,  SUGIYAMA, Kazunori

IPC: C09K3/18 ,  C08F220/22 ,  C09D133/16 ,  D06M15/277

CPC classification number: C08F220/24 ,  C08F220/18 ,  C08F2220/325 ,  C08F2220/365 ,  C08L33/16 ,  C08L2205/02 ,  C09D133/16 ,  C09K3/18 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12 ,  C08L2666/06

Abstract: To provide a liquid repellent composition which is excellent in liquid repellency and durability and an article having a liquid repelling film.
A liquid repellent composition comprising a copolymer (I) and a copolymer (II), characterized in that the copolymer (I) containing from 65 to 95 mass% of a polymerized unit (a) (referred to as "[a 1 ]") and from 1 to 30 mass% of a polymerized unit (b); and the copolymer (II) containing from 25 to 80 mass% of a polymerized unit (a) (referred to as "[a 2 ]") and from 1 to 50 mass% of a polymerized unit (c) are contained in an amount of the copolymer (I)/the copolymer (II)=10/90 to 95/5 (mass ratio), and [a 1 ]-[a 2 ]≧10 (mass%).

Abstract translation: 提供一种防液剂组合物的所有其具有优异的防液性和耐久性和制品具有液体排斥电影。 甲防液剂组合物包含共聚物（I）和共聚物（II），在没有通过的聚合单元（a）中的质量含有65〜95％的共聚物（I）为特征的（通过向称为“[一个]”） 和1至30％的聚合单元的质量（b）; 和由聚合单元（a）的质量含有25〜80％的共聚物（II）（简称“[2]”）和1至50质量％的聚合单元（c）的质量包含在量 共聚物（I）/共聚物（II）= 10/90至95/5（质量比），和[A 1] - [2]‰§10（质量％）。