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    VERFAHREN ZUR HERSTELLUNG VON EPOXIDIERTEN POLYSULFIDEN
    6.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON EPOXIDIERTEN POLYSULFIDEN 审中-公开
    用于生产环氧多硫化物

    公开(公告)号：EP1483307A1

    公开(公告)日：2004-12-08

    申请号：EP03743857.9

    申请日：2003-03-08

    申请人： Thioplast Chemicals GmbH & Co. Kg

    发明人： ZEITLER, Michael ,  KOTTNER, Nils ,  BERGFELD, Manfred

    IPC分类号： C08G59/00 ,  C08G59/30 ,  C08G59/02

    CPC分类号： C08G59/02 ,  C08G2650/02 ,  C08L81/04

    摘要： Disclosed is a method for producing polymeric polysulfides containing terminal epoxy groups, according to which polysulfides containing terminal thiol groups are reacted with an excess of epichlorohydrin and alkaline lye, water is azeotropically distilled away with epichlorohydrin, the epichlorohydrin-containing epoxidized polysulfide solution is separated from the eliminated salt, the epichlorohydrin is distilled away, and the residue is optionally purified by means of thin film distillation. The reaction product is particularly suitable for the production of high-quality sealants, adhesives, and coatings. Said product has a high degree of purity and an extremely low chlorine content. The inventive method does not require any additional organic solvents and is very environmentally friendly.

    Poly(arylene ether sulfone) having sulfoalkoxy group, process of producing the same, and polymer electrolyte membrane comprising the same
    8.
    发明公开
    Poly(arylene ether sulfone) having sulfoalkoxy group, process of producing the same, and polymer electrolyte membrane comprising the same 有权
    聚含Sulfoalkoxy基团，制备它们的方法和它们的用途在聚合物电解质膜（亚芳基醚砜）

    公开(公告)号：EP1314751A1

    公开(公告)日：2003-05-28

    申请号：EP02025617.8

    申请日：2002-11-19

    申请人： Tosoh Corporation

    发明人： Oguri, Motohiro ,  Ikeda, Ryuji ,  Okisaki, Fumio

    IPC分类号： C08G75/23 ,  C08G65/48 ,  H01M8/10

    CPC分类号： C08L81/06 ,  C08G2650/02 ,  H01M8/1027 ,  H01M8/1032

    摘要： A novel poly(arylene ether sulfone) having a sulfoalkoxy group, which has both of heat resistance and electroconductivity, is suitable as polymer electrolyte membranes used for high performance polymer electrolyte fuel cells, and does not use fluorine so that loads to the environment are small in the synthesis or disposal, a process of producing the same, and a polymer electrolyte membrane comprising the same. The poly(arylene ether sulfone) having a sulfoalkoxy group has a structural unit represented by the formula (1) mentioned hereinabove, and is produced by reacting a poly(arylene ether sulfone) having a hydroxyl group with a specific alkali metal compound and/or an organic base compound, followed by reacting with a specific sulfonating agent and then with a specific acid. A polymer electrolyte membrane is produced by film formation of the polymer.

    摘要翻译： 一种新颖的聚具有sulfoalkoxy基，同时具有耐热性和导电性（亚芳基醚砜），是适合作为用于高性能聚合物电解质燃料电池的聚合物电解质膜，并且不使用氟所以没有负载到环境中是小 在合成或处理，从而产生相同的处理，和高分子电解质膜，其包含相同的。 具有sulfoalkoxy基的聚（亚芳基醚砜）具有由式（1）在上述表示的结构单元，并且是通过使聚（亚芳基醚砜）具有与特定的碱金属化合物的羟基产生和/或 有机碱化合物的，通过用特定的磺化剂，然后用特定的酸反应其次。 聚合物电解质膜由聚合物膜形成产生。