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231 条记录 (耗时 0.021 秒)

    Method and apparatus for producing monomolecular layers
    92.
    发明公开
    Method and apparatus for producing monomolecular layers 失效
    Verfahren und Vorrichtung zur Herstellung von monomolekularen Schichten

    公开(公告)号：EP0841099A1

    公开(公告)日：1998-05-13

    申请号：EP97119294.3

    申请日：1997-11-05

    申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD

    发明人： Otake, Tadashi ,  Mino, Norihisa ,  Nakagawa, Tohru ,  Soga, Mamoru ,  Ogawa, Kazufumi ,  Nomura, Takaiki ,  Takebe, Yasuo

    IPC分类号： B05D1/28

    CPC分类号： B82Y30/00 ,  B05D1/283 ,  B05D3/0486 ,  B82Y40/00

    摘要： A method for forming a molecular film includes the steps of:

    coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate 2 is supplied to a chamber 11 in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber 11.

    摘要翻译： 形成分子膜的方法包括以下步骤：用含有至少一个选自氯基团的反应性基团的硅烷类化合物的涂布溶液在其表面上涂布具有活性氢原子的基材的表面 ，烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应，从而将硅烷类化合物共价键合到基板的表面。 将基板2供给到气氛保持低水蒸气密度的室11。 通过使用转印元件，将含有硅烷类化合物和溶剂的涂布液涂布在基材的表面上。 在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。 此后，在室11内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液

    Contamination-resistant float glass and process of producing the same
    98.
    发明公开
    Contamination-resistant float glass and process of producing the same 失效
    Gegen VerschmutzungbeständigesFloatglas und Verfahren zu dessen Herstellung

    公开(公告)号：EP0799806A1

    公开(公告)日：1997-10-08

    申请号：EP97105534.8

    申请日：1997-04-03

    申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD

    发明人： Nomura, Takaiki ,  Ogawa, Kazufumi ,  Oe, Jun ,  Ohtake, Tadashi ,  Nakagawa, Tohru ,  Kurumizawa, Toshimitsu ,  Tokumitsu, Shuzou ,  Shibata, Tsuneo ,  Kawanishi, Hidekata ,  Shimizu, Satoshi ,  Isogai, Mamoru

    IPC分类号： C03C17/30

    CPC分类号： C03C17/30 ,  F24C15/04 ,  Y10T428/31601

    摘要： This invention provides a contamination-resistant float glass showing even quality in durability and its good quality sufficienty. The film for contamination-resistance is formed only on the top-side surface of a float glass. The surface, free from tin diffused from a float bath, can be identified by ultraviolet irradation. A solution including a chemical adsorbent like fluoroalkyltrichlorosilane is applied to the top-side surface by a roller coater. The adsorbent can be prevented from hydrolyzing with dry air around the coating portion of the coater. Surplus solution can be removed with dry air blown on the surface to make the contamination-resistant property and the appearance better. The chemical adsorbent is bonded to the surface via a siloxane bond to form a thin film. The contamination-resistant float glass is installed in the front door of an apparatus like a toaster oven with the film facing the inside of the oven. The film on the top-side surface shows higher contact angles than that on the bottom-side surface in durability tests.

    摘要翻译： 本发明提供一种抗污染的浮法玻璃，其耐久性质量均匀，质量好。 用于防污染的膜仅在浮法玻璃的顶侧表面上形成。 可以通过紫外线照射来识别从浮法浴槽中不含锡的表面。 将包含化学吸附剂如氟烷基三氯硅烷的溶液通过辊式涂布机施加到顶侧表面。 可以防止吸附剂与涂布机涂层部分周围的干燥空气水解。 可以用表面上吹的干燥空气除去剩余的溶液，使其耐污染性和外观更好。 化学吸附剂通过硅氧烷键与表面结合形成薄膜。 防污浮浮玻璃安装在像烤箱一样的设备的前门中，薄膜面向烤箱的内部。 在耐久性试验中，顶侧表面的薄膜表现出比底侧表面更高的接触角。

    A method for manufacturing a chemically adsorbed film and a chemical adsorbent solution for the method
    100.
    发明公开
    A method for manufacturing a chemically adsorbed film and a chemical adsorbent solution for the method 失效
    一种制造化学吸附剂的化学吸附膜和溶液用于该方法的方法

    公开(公告)号：EP0748658A2

    公开(公告)日：1996-12-18

    申请号：EP96109503.1

    申请日：1996-06-13

    申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD

    发明人： Ogawa, Kazufumi

    IPC分类号： B05D1/18 ,  B05D1/36

    CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  C03C17/30 ,  C09D4/00 ,  C08G77/04

    摘要： The methods of forming a chemically adsorbed film by contacting a substrate with a solution mixture containing an alkoxysilane surface active agent, a non-aqueous solvent and a silanol-condensing catalyst to form a film covalently bonded to the substrate via siloxane bonds. These methods do not generate hydrochloric acid gas in forming the films and allow practical reaction rates.

    摘要翻译： 通过接触基板与含有表面活性剂的烷氧基硅烷的混合溶液形成的化学吸附膜的方法中，非水溶剂和硅烷醇缩合催化剂，以形成通过硅氧烷键共价键合于基板的薄膜。 这些方法不会在形成薄膜产生盐酸气体，并允许实际的反应速率。