PRODUCTION OF HYDROGEN FROM NON-CYCLIC ORGANIC SUBSTANCES HAVING MULTIPLE ALCOHOL FUNCTIONALITY
    106.
    发明公开
    PRODUCTION OF HYDROGEN FROM NON-CYCLIC ORGANIC SUBSTANCES HAVING MULTIPLE ALCOHOL FUNCTIONALITY 审中-公开
    氢从具有多羧酸官能无环有机物质的生产

    公开(公告)号:EP1926680A2

    公开(公告)日:2008-06-04

    申请号:EP06801420.8

    申请日:2006-08-14

    IPC分类号: C01B3/32

    摘要: A method of producing hydrogen gas from a reaction of an organic substance having multiple alcohol functionality with a base. Hydrogen can be produced in a reaction of a base with an organic substance having multiple alcohol functionality that may proceed through the formation of a bicarbonate or carbonate compound as a byproduct. In some embodiments, the reaction may occur in the presence of water. The preferred organic substances include diols, triols, and higher order alcohols. Non-cyclic (linear or branched) organic substances having multiple alcohol functionality are among the preferred reactants. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the corresponding conventional reformation reactions of the organic substances and can produce hydrogen at less extreme reaction conditions. The preferred reactants further include low volatility organic substances having multiple alcohol functionality. Such reactants permit the efficient formation of hydrogen in a liquid phase system and enable a continuous reaction capability in the liquid phase without the need to condense volatilized reactant.

    PRODUCTION OF HYDROGEN VIA A BASE-FACILITATED REACTION OF CARBON MONOXIDE
    109.
    发明公开
    PRODUCTION OF HYDROGEN VIA A BASE-FACILITATED REACTION OF CARBON MONOXIDE 审中-公开
    氢水基地基炭反应产生的

    公开(公告)号:EP1858800A2

    公开(公告)日:2007-11-28

    申请号:EP06735769.9

    申请日:2006-02-22

    IPC分类号: C01B3/12

    摘要: A method of producing hydrogen gas from a reaction of carbon monoxide with a base. Hydrogen is produced in a reaction of a base with carbon monoxide that proceeds through the formation of a bicarbonate or carbonate compound as a by-product. In some embodiments, the reaction may occur in the presence of water and may produce carbon dioxide as a by-product. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the water-gas shift reaction and are able to produce hydrogen gas from carbon monoxide at greater reaction rates than is possible with the water-gas shift reaction. Carbon monoxide in a purified or unpurified state or as a component within a mixture of gases is suitable for use in the instant invention. Metal hydroxides are the preferred base reactant. The base reactant can be in the solid phase, molten phase, liquid phase or solution phase.