公开(公告)号：EP2417087A2

公开(公告)日：2012-02-15

申请号：EP10711395.3

申请日：2010-03-29

Applicant: BASF SE

Inventor： ABILLARD, Olivier ,  PINKOS, Rolf ,  TEBBEN, Gerd-Dieter ,  SIRCH, Tilman ,  URBANCZYK, Daniel ,  URTEL, Heiko ,  TOMPERS, Rolf

IPC: C07C29/149 ,  C07C31/20 ,  C08J11/16 ,  B01J23/76

CPC classification number: C07C45/33 ,  C07C29/149 ,  C07C29/50 ,  C07C51/313 ,  C07C67/08 ,  C07C2601/14 ,  C07C31/20 ,  C07C35/08 ,  C07C49/403 ,  C07C55/14 ,  C07C69/44

Abstract: The invention relates to a method for the hydrogenation of oligo- and/or polyesters which can be obtained by the esterification of a dicarboxylic acid solution with a diol or diol mixture, the hydrogenation being carried out in the presence of a catalyst, the precursor of said catalyst containing copper oxide, aluminum oxide and at least one oxide of lanthanum, iron, tungsten, molybdenum, titanium or zirconium. The invention also relates to a method for producing 1,6-hexanediol by the catalytic hydrogenation of ester mixtures which contain oligo- and polyesters of the adipic acid and 6-hydroxycaproic acid as the main components and which can be obtained by the esterification of a dicarboxylic acid solution with diols and especially 1,6-hexanediol or diol mixtures.

Abstract translation: 要求通过催化剂成型体将低聚和/或聚酯（通过二醇或二醇混合物的二羧酸溶液酯化获得）的氢化反应，其中催化剂的前体是通过（a）提供包含铜的氧化物质 氧化物，氧化铝或至少一种镧系元素，钨，钼，钛，锆或铁的氧化物，（b）向氧化物质中加入粉末状金属铜，铜片，粉末状水泥和/或石墨，和（c） 得到的混合物成型成型体。 要求通过催化剂成型体将低聚和/或聚酯（通过二羧酸溶液与二醇或二醇混合物的酯化得到）的氢化反应，其中：催化剂的前体是通过（a）提供氧化物质制备的， 氧化铜，氧化铝或至少一种镧系元素，钨，钼，钛，锆或铁的氧化物，（b）向氧化物质中加入粉末状金属铜，铜片，粉末状水泥和/或石墨，和（c） 所得混合物成型体; 氧化物通过同时或顺次沉淀活性成分铜，铝或镧系元素，钨，钼，钛或锆的氧化物而得到，随后干燥和煅烧，并且在步骤（c）之后模塑或压片后煅烧催化剂成型体 ）。 包括用于制备1,6-己二醇的独立权利要求，其包括（a1）将环己烷与氧或含氧气体氧化成环己醇，环己酮和羧酸的混合物至多6℃，（a2）使得到的反应混合物 从步骤（a1）用水分离二羧酸与液体两相反应混合物，（a3）将由步骤（a2）获得的二羧酸溶液与醇进行酯化，（a4）得到的酯混合物的催化氢化 从步骤（a3）和（a5）蒸馏得到的氢化产物，其中步骤（a3）中的酯化用至少一种2-12C二醇进行，步骤（a3）中获得的酯化混合物在液相中氢化 在上述催化剂成型体的存在下。

公开(公告)号：EP2367783A1

公开(公告)日：2011-09-28

申请号：EP09752383.1

申请日：2009-11-18

Applicant: BASF SE

Inventor： BREUNINGER, Daniel ,  ADAM, Johannes ,  SCHELLING, Heiner ,  STROEFER, Eckhard ,  KRÄMER, Markus ,  EIERMANN, Matthias ,  THIELE, Kai ,  ZOELLINGER, Michael ,  PINKOS, Rolf

IPC: C07C263/10 ,  C07C265/14 ,  C07C209/90

CPC classification number: C07C263/10 ,  C07C265/14

Abstract: The invention relates to a method for producing an isocyanate, comprising hydrogenation of an amimne-ciontaining mixture (Gi) in the presence of a copper containing hydrogenation catalyst to give a mixture (Gii) containing the amine and reacting the mixture (Gii) with phosgene to give a mixture (Gii) containing the isocyanate. The invention further relates to the isocyanate which may be produced by said method.

公开(公告)号：EP2225220A1

公开(公告)日：2010-09-08

申请号：EP08863798.8

申请日：2008-12-10

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  TEBBEN, Gerd-Dieter ,  BREUNINGER, Daniel ,  SIRCH, Tilman ,  BAUDUIN, Christophe ,  GUIXA GUARDIA, Maria ,  KRUG, Thomas

IPC: C07D313/04

CPC classification number: C07D313/04

Abstract: The invention relates to a method for producing ε-caprolactone from 6-hydroxycapronic acid ester in the gaseous phase in the presence of active carbon as catalyst and subsequent distillation.

公开(公告)号：EP2041059B1

公开(公告)日：2010-06-16

申请号：EP07765652.8

申请日：2007-06-27

Applicant: BASF SE

Inventor： TELES, Joaquim Henrique ,  RÖSSLER, Beatrice ,  PINKOS, Rolf ,  TEBBEN, Gerd ,  MÜLLER, Christian ,  RUST, Harald

IPC: C07C45/28 ,  C07C45/62 ,  C07C45/85 ,  C07C49/413 ,  C07C49/607

CPC classification number: C07C45/28 ,  C07C45/62 ,  C07C45/80 ,  C07C45/81 ,  C07C45/82 ,  C07C45/85 ,  C07C2601/18 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

Abstract: The invention relates to a method for producing a cyclic ketone that has 7 to 16 C atoms. Said method encompasses at least the following stages: (a) a composition (i) at least containing a cyclic alkene with 7 to 16 C atoms, including at least one C-C double bond, is oxidized by means of dinitrogen monoxide so as to obtain a composition (A); (b) composition (A) is treated with at least one base so as to obtain a composition (B); (c) composition (B) is hydrogenated in the presence of at least one catalyst so as to obtain a composition (C); (d) composition (C) is purified in at least the following steps: (di) composition (C) is thermally treated with at least one acid or at least one catalyst containing at least one transition metal; (dii) composition (C) is further purified by means of a process selected from the group comprising distillation, extraction, and crystallization.

Abstract translation: 本发明涉及一种制备具有7至16个碳原子的环酮的方法，其至少包括步骤（a）包含至少一种具有7至16个碳原子的环烯烃的组合物（I）的氧化 和至少一种C-C双键，得到组合物（A），（b）用至少一种碱处理组合物（A），得到组合物（B），（c）氢化 在组合物（B）的存在下，在至少一种催化剂的存在下，得到组合物（C），（d）组合物（C）的纯化，至少包括步骤（ii）组合物（C）的热处理， 至少一种酸或至少一种包含至少一种过渡金属的催化剂，（dii）通过选自蒸馏，萃取和结晶的方法进一步纯化。

公开(公告)号：EP1545767B1

公开(公告)日：2010-04-14

申请号：EP03798903.5

申请日：2003-09-12

Applicant: BASF SE

Inventor： SCHLITTER, Stephan ,  HAUBNER, Martin ,  HESSE, Michael ,  KÄSHAMMER, Stefan ,  PINKOS, Rolf ,  SIGWART, Christoph

IPC: B01J21/16 ,  C08G61/12 ,  C08G65/26

CPC classification number: C08G61/125 ,  B01J21/16 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/108 ,  C08G65/2657

公开(公告)号：EP2041060B1

公开(公告)日：2009-12-16

申请号：EP07786855.2

申请日：2007-06-27

Applicant: BASF SE

Inventor： TELES, Joaquim Henrique ,  RÖSSLER, Beatrice ,  PINKOS, Rolf ,  TEBBEN, Gerd ,  MÜLLER, Christian

IPC: C07C45/28 ,  C07C49/413 ,  C07C49/607

CPC classification number: C07C45/28 ,  C07C45/62 ,  C07C45/85 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

Abstract: The invention relates to a method for producing a cyclic ketone that has 7 to 16 C atoms. Said method encompasses at least the following stages: (a) a composition (I) at least containing a cyclic olefin with 7 to 16 C atoms, including at least one C-C double bond, is oxidized by means of dinitrogen monoxide so as to obtain a composition (A); (b) composition (A) is treated with at least one base so as to obtain a composition (B).

Abstract translation: 本发明涉及一种制备具有7至16个碳原子的环酮的方法，其至少包括步骤（a）包含至少一种具有7至16个碳原子的环烯烃的组合物（I）的氧化 和至少一个CC双键，得到组合物（A），（b）用至少一个碱处理组合物（A）以得到组合物（B）。

公开(公告)号：EP2046702A1

公开(公告)日：2009-04-15

申请号：EP07802378.5

申请日：2007-07-16

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  HEIMANN, Jens ,  POLKA, Hans-Martin ,  URTEL, Heiko ,  WINDECKER, Gunther

IPC: C07B63/00 ,  C07C29/149 ,  C07C209/48 ,  C07C31/20

CPC classification number: C07B63/00 ,  C07C29/149 ,  C07C29/86 ,  C07C209/48 ,  C07C211/12 ,  C07C31/20 ,  C07C31/207 ,  C07C31/04 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12 ,  C07C31/202 ,  C07C31/205

Abstract: The present invention relates to a process for separating solvents from solvent-containing hydrogenation product mixtures from a catalytic hydrogenation process, which mixtures contain a water-soluble hydrogenation product having an alcohol, lactone, ether, lactam or amino group in a solvent which is immiscible or not fully miscible with water and has a boiling point below 100°C, characterized in that water is added to the hydrogenation product mixture and the solvent-containing phase is separated off and recirculated to the hydrogenation.

Abstract translation: 本发明涉及一种从含有溶剂的加氢产物混合物中分离出来的催化氢化方法中的溶剂的方法，该混合物含有在不溶混的溶剂中含有醇，内酯，醚，内酰胺或氨基的水溶性氢化产物 或不完全与水混溶并具有低于100℃的沸点，其特征在于将水加入到氢化产物混合物中，并将含溶剂相分离并再循环至氢化。

公开(公告)号：EP2041059A1

公开(公告)日：2009-04-01

申请号：EP07765652.8

申请日：2007-06-27

Applicant: BASF SE

Inventor： TELES, Joaquim Henrique ,  RÖSSLER, Beatrice ,  PINKOS, Rolf ,  TEBBEN, Gerd ,  MÜLLER, Christian ,  RUST, Harald

IPC: C07C45/28 ,  C07C45/62 ,  C07C45/85 ,  C07C49/413 ,  C07C49/607

CPC classification number: C07C45/28 ,  C07C45/62 ,  C07C45/80 ,  C07C45/81 ,  C07C45/82 ,  C07C45/85 ,  C07C2601/18 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

Abstract: The invention relates to a method for producing a cyclic ketone that has 7 to 16 C atoms. Said method encompasses at least the following stages: (a) a composition (i) at least containing a cyclic alkene with 7 to 16 C atoms, including at least one C-C double bond, is oxidized by means of dinitrogen monoxide so as to obtain a composition (A); (b) composition (A) is treated with at least one base so as to obtain a composition (B); (c) composition (B) is hydrogenated in the presence of at least one catalyst so as to obtain a composition (C); (d) composition (C) is purified in at least the following steps: (di) composition (C) is thermally treated with at least one acid or at least one catalyst containing at least one transition metal; (dii) composition (C) is further purified by means of a process selected from the group comprising distillation, extraction, and crystallization.

Abstract translation: 本发明涉及生产具有7至16个C原子的环酮的方法。 所述方法至少包括以下阶段：（a）通过一氧化二氮将至少含有具有7至16个C原子的环烯烃（包括至少一个CC双键）的组合物（i）用一氧化二氮氧化以获得 组成（A）; （b）用至少一种碱处理组合物（A）以获得组合物（B）; （c）将组合物（B）在至少一种催化剂存在下氢化以获得组合物（C）; （d）至少在下列步骤中纯化组合物（C）：（di）用至少一种酸或至少一种含至少一种过渡金属的催化剂热处理组合物（C）; （dii）组合物（C）通过选自蒸馏，萃取和结晶的方法进一步纯化。

公开(公告)号：EP1272270B1

公开(公告)日：2009-01-21

申请号：EP01936136.9

申请日：2001-03-23

Applicant: BASF SE

Inventor： FISCHER, Rolf-Hartmuth ,  PINKOS, Rolf ,  SCHUNK, Stephan, Andreas ,  WULFF-DÖRING, Joachim

IPC: B01J23/36

CPC classification number: C07C29/149 ,  B01J21/18 ,  B01J23/36 ,  B01J23/6567 ,  B01J23/8896 ,  C07C2601/18 ,  C07C31/207 ,  C07C31/205 ,  C07C31/133 ,  C07C31/12

Abstract: The invention relates to a method for the production of alcohols, by catalytic hydrogenation of carbonyl compounds, using a catalyst with 0,01 to 50 wt. % rhenium and 0 to 20 wt. % of a further metal, chosen from Zn, Cu, Ag, Au, Ni, Fe, Cr or V, based upon total catalyst weight, supported on oxidatively pre-treated activated charcoal.

Abstract translation: 催化剂（I）在氧化预处理的活性炭载体上包含0.01-50重量％的铼和0-20重量％的包含Zn，Cu，Ag，Au，Ni，Fe，Cr或V的另外的金属。 包括通过催化剂（I）羰基化合物的催化氢化生产醇的独立权利要求。

公开(公告)号：EP2004590A1

公开(公告)日：2008-12-24

申请号：EP07727808.3

申请日：2007-04-04

Applicant: BASF SE

Inventor： BAUDUIN, Christophe ,  FISCHER, Wolfgang ,  PINKOS, Rolf ,  SCHOLTEN, Edzard

IPC: C07C67/08 ,  C07C69/40 ,  C07D307/08 ,  C07D307/32 ,  C07C29/149 ,  C07C31/20

CPC classification number: C07C29/149 ,  C07C67/08 ,  C07D207/263 ,  C07D307/08 ,  C07D307/33 ,  Y02P20/127 ,  C07C69/40 ,  C07C31/12 ,  C07C31/207

Abstract: The present invention relates to a novel method of producing polycarboxylic alkyl esters from an aqueous solution of an ammonium salt of the polycarboxylic acid by reactive distillation, and also to a method for hydrogenating the carboxylic alkyl esters produced in this manner.