摘要:
The present invention provides a proton conducting polymer which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. The proton conducting compound is produced by polymerization of a salt of a melamine compound represented by the following equation (2) and a Bronsted acid:
wherein, R 1 , R 2 , R 3 , R 4 , and R 5 each is independently an alkyl group, an aryl group, a heterocyclic group, or hydrogen and at least one of them is an alkyl group, an aryl group, or a heterocyclic group; R 2 and R 3 or R 4 and R 5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, and the heterocyclic group each may have a substituent selected from the group of alkyl groups of 1 to 6 carbon atoms, aryl groups of 6 to 12 carbon atoms, heterocyclic groups, an amino group, alkylamino groups of 1 to 6 carbon atoms, a nitro group, a carboxyl group, acryl groups of 1 to 6 carbon atoms, acyloxy groups of 1 two 6 carbon atoms, a cyano group, alkylsulfonyl groups of 1 to 6 carbon atoms, alkylsulfonyloxy groups of 1 to 6 carbon atoms, a sulfoxide group, a sulfonic acid group, alkoxycarbonyl groups of 1 to 6 carbon atoms, aryloxycarbonyl groups of 6 to 12 carbon atoms, aryloxy groups of 6 to 12 carbon atoms, and alkynyl groups of 2 to 6 carbon atoms; R 6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1,
摘要翻译:本发明提供质子传导性聚合物,其在不加湿的情况下提供质子传导性,并且适用于电化学装置材料,例如用于燃料电池的固体电解质和用于电池的电解质。 质子传导性化合物是通过聚合由下式(2)表示的三聚氰胺化合物的盐和布朗斯台德酸来制备的:其中,R 1,R 2,R 3,R 4和R 5各自独立地为烷基 基团,芳基,杂环基或氢,并且它们中的至少一个是烷基,芳基或杂环基; R 2和R 3或R 4和R 5可以连接在一起形成杂环结构; 烷基,芳基和杂环基各自可以具有选自1〜6个碳原子的烷基,6〜12个碳原子的芳基,杂环基,氨基,烷基氨基 1〜6个碳原子的硝基,羧基,1〜6个碳原子的丙烯酰基,1〜6个碳原子的酰氧基,1〜6个碳原子的氰基,烷基磺酰基,1〜6个碳原子的烷基磺酰氧基 6个碳原子,亚砜基,磺酸基,1〜6个碳原子的烷氧基羰基,6〜12个碳原子的芳氧基羰基,6〜12个碳原子的芳氧基,2〜6个碳原子的炔基 ; R 6是氢或烷基,n是等于或大于1的整数,
摘要:
It is possible to obtain a resin with a favorable index of refraction and transparency even without using heavy atoms or inorganic oxide fine particles by means of a polymerizable monomer having a 1,3,5-triazine ring represented by formula 1.
(In formula 1: A is a group represented by formula 2, (in formula 2: R 1 represents a hydrogen atom or a methyl group, T represents an alkylene having 1-10 carbon atoms, and R 2 represents O or NH), and B1 and B2 are each independently groups represented by formula 3, formula 4, or formula 5 (in formulas 3-5: R 3 , R 4 , and R 5 represent an alkyl group having 1-10 carbon atoms, an aryl group, or an aryloxy group, n1 and n3 are integers from 0-5, and n2 is an integer from 0-7, however when there are at least two of each of R 3 , R 4 , and R 5 , these may be the same or different from each other).)
摘要:
An object of the invention is to provide curable compositions for transfer materials suited for nanoimprinting processes, which compositions have high dry etching resistance against argon gas and high selectivity of dry etching rate between by argon gas and by oxygen gas, and can be fabricated into fine patterns used as resists or the like. A curable composition for transfer materials includes a (meth)acrylate compound having a triazine skeleton which is obtainable by reacting an aminotriazine compound, a compound having a hydroxyl group and a (meth) acryloyl group in the molecule, and an aldehyde.
摘要:
A multiphoton curable photoreactive composition including hydantoin hexaacrylate and a photoinitiator system. In some embodiments, the multiphoton curable photoreactive composition consists essentially of hydantoin hexaacrylate and a photoinitiator system. Additionally, the applying a multiphoton curable photoreactive composition comprising hydantoin hexaacrylate and a photoinitiator system may be applied to a substrate and a portion of the multiphoton curable photoreactive composition may be at least partially cured to form an at least partially cured structure.
摘要:
It is an object of the invention to provide a method of producing a crosslinked poly(meth)acrylic acid compound, in particular a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound, which is a radical compound excellent in solvent stability. The invention is a method of producing a crosslinked poly(meth)acrylic acid compound resulting from crosslinking of a poly(meth) acrylic acid compound represented by the general formula (1): (in the formula, n Z 1 s represent a hydrogen atom(s) and/or an oxygen atom(s) having one unpaired electron, R represents a hydrogen atom or a methyl group and n represents an integer of 5 to 1000000), which method is characterized by comprising a polymerization step of polymerizing a (meth)acrylic acid compound represented by the general formula (2): (in the formula, Z 2 represents a hydrogen atom when Z 1 is a hydrogen atom, or a hydrogen atom or an oxygen atom having one unpaired electron when Z 1 is an oxygen atom having one unpaired electron; and R represents the same group as R in the above general formula (1)) in the presence of a crosslinking agent.
摘要:
The invention relates to antimicrobial polymers comprising at least one moiety of formula
wherein R is hydrogen or methyl, R 1 is C 6-18 alkyl, m and n independently are 0 or 1, with the proviso that at least one of m and n is 1, A is C 1-4 alkanediyl or -( p -C 6 H 4 -CH 2 )-, and E is selected from the group consisting of -C(=O)-, -OC(=O)- and -NH-C(=O)-. The amino group-containing side chain imparts antimicrobial properties to the polymers, which may be homo- or copolymers. The polymers can be prepared by homo- or copolymerization of suitably substituted vinylic compounds which are also part of the invention.
摘要:
The instant invention relates to a process for the preparation of polymeric nitroxide radicals by group transfer polymerization. Further aspects of the invention are the polymers containing the nitroxide radicals as well as their use, in particular as active electrode materials in organic radical batteries.
摘要:
A cationically stabilizable amino-functional polymer having a number-average molecular weight of > 3000, exists in the presence of water as a solution or stable emulsion only when the pH is ≤ 8. Upon drying the polymer contains ethylenically unsaturated moieties selected from the group consisting of acrylic, methacrylic, and enamine. The polymer is useful to promote adhesion of curable inks and other coatings for plastic film. The invention further relates to a plastic film comprising such polymer.