VERFAHREN ZUR HERSTELLUNG KUPFERHALTIGER METALLORGANISCHER GERÜSTMATERIALIEN
    161.
    发明公开
    VERFAHREN ZUR HERSTELLUNG KUPFERHALTIGER METALLORGANISCHER GERÜSTMATERIALIEN 有权
    用于生产铜的有机金属骨架材料

    公开(公告)号:EP2049550A1

    公开(公告)日:2009-04-22

    申请号:EP07787520.1

    申请日:2007-07-13

    Applicant: BASF SE

    CPC classification number: C07F1/005

    Abstract: The present invention relates to methods for producing a porous, organometallic framework material containing a first and at least one second at least bidentate organic compound coordinatively bound to at least one copper ion, including the following steps: (a) Reaction of a reaction mixture in the liquid phase containing at least one copper compound and the first at least bidentate organic compound with formation of a complex intermediate containing at least one copper ion and the first at least bidentate organic compound, wherein the first at least bidentate organic compound derives from a dicarboxylic acid and has a hydrocarbon framework, and (b) Reaction of the complex intermediate with the at least second at least bidentate organic compound, wherein the at least second at least bidentate organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbon atoms are replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) has less than a threefold excess amount of 25 formic acid based on the copper used in the copper compound.

    VERFAHREN ZUR HERSTELLUNG VON PORÖSEN METALLORGANISCHEN GERÜSTMATERIALIEN
    162.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON PORÖSEN METALLORGANISCHEN GERÜSTMATERIALIEN 有权
    用于生产多孔金属有机骨架

    公开(公告)号:EP2027307A2

    公开(公告)日:2009-02-25

    申请号:EP07729006.2

    申请日:2007-05-11

    Applicant: BASF SE

    CPC classification number: C25B3/12

    Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

    VERFAHREN ZUR HERSTELLUNG METALLORGANISCHER GERÜSTMATERIALIEN MIT METALLEN DER IV. NEBENGRUPPE
    163.
    发明公开
    VERFAHREN ZUR HERSTELLUNG METALLORGANISCHER GERÜSTMATERIALIEN MIT METALLEN DER IV. NEBENGRUPPE 审中-公开
    制造有机金属骨架材料与IV。侧基金属的方法

    公开(公告)号:EP2010547A1

    公开(公告)日:2009-01-07

    申请号:EP07728243.2

    申请日:2007-04-18

    Applicant: BASF SE

    CPC classification number: C07F7/006 C07C51/412 C07C63/28

    Abstract: The invention relates to methods for producing a porous metal-organic framework material which contains at least one at least bidentate compound that is coordinately bound to at least one metal ion. Said method comprises the step of reacting at least one metal compound with at least one at least bidentate organic compound which is capable of coordinately binding to the metal. The metal ion of the at least one metal compound is selected from the group of metals including titanium, zirconium, and hafnium. The at least bidentate compound is derived from a di-, tri- or tetracarboxylic acid and the metal compound is an inorganic salt.

    POLYOXYMETHYLEN UND ZEOLITH ENTHALTENDE FORMMASSE
    166.
    发明授权
    POLYOXYMETHYLEN UND ZEOLITH ENTHALTENDE FORMMASSE 有权
    聚甲醛和含沸石的成型材料

    公开(公告)号:EP1838783B1

    公开(公告)日:2008-07-09

    申请号:EP06707691.9

    申请日:2006-01-10

    Applicant: BASF SE

    CPC classification number: C08L59/00

    Abstract: The invention relates to a moulding compound, comprising between 10 and 99.999 wt. % of at least one polyoxymethylene as component (A1) and between 0.001 and 10 wt. %, (in relation to the weight of the component (A1) contained in the moulding compound), of at least one zeolitic material with a pore diameter ranging between 0.3 and 0.5 nm, determined according to the DIN 66134 and DIN 66135 standards. The size of the particles of zeolitic material ranges between 3 and 7 ?m, determined according to the ISO 13320 standard. The invention also relates to moulded bodies that are produced from said moulding compound.

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