Abstract:
The present invention relates to a method for the production of trion-bis(oxime ether) derivatives of formula (I), wherein the substituents have the following meaning: R1, R3 represent unsubstituted, partially or totally halogenated C¿1?-C6-alkyl or C3-C6-cycloalkyl; R?2, R4¿ represent C¿1?-C4-alkyl or a methyl substituted by C2-C4-alkenyl, C2-C4-alkinyl or phenyl and X represents oxygen or N-OH. The invention also relates to the intermediate products obtained with said method.
Abstract:
The invention relates to cyclohexenonquinolinoyl derivatives of formula (I), wherein the variables have the following meanings: R1 means hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxyiminomethyl, alkoxy, halogenalkoxy, alkylthio, C1-C6-halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, optionally substituted aminosulfonyl, optionally substituted sulfonylamino, optionally substituted phenoxy, optionally substituted heterocyclyloxy, optionally substituted phenylthio or optionally substited heterocyclylthio; R2, R3 mean hydrogen, alkyl, halogenalkyl or halogen; and R4 means substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene. The invention also relates to the agriculturally useable salts of said derivatives, to a method for producing the derivatives, to agents containing them and to the use of the derivatives or agents containing them for combating undesirable plants.
Abstract:
The invention relates to a method for producing isoxazolene of the formula (I), where the substituents have the following meanings: R1 is hydrogen, C¿1?-C6 alkyl, R?2 is C¿1-C6 alkyl, R?3, R4, R5¿ are hydrogen, C¿1?-C6 alkyl or R?4 and R5¿ together form a linkage, R6 is a heterocyclic ring, and n is 0, 1 or 2. Said method comprises the production of an intermediate compound of the formula (VI) where R?1, R3, R4 and R5¿ have the meanings given above. This step is followed by halogenation, thiomethylation, oxidation and acylation to yield compounds of formula (I). The invention also relates to new intermediate products for producing compounds of formula (I) and new methods for producing the intermediate products.
Abstract:
The invention concerns 4-benzoyl-pyrazoles of formula (I), in which the variables have the following meanings: R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, cyano, alkyl, halogen alkyl, -OR?7, -SR7 or -NR7R10; R4¿ stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or NR8; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted pyrazol linked in position 4. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.
Abstract translation:本发明涉及式(I)的4-苯甲酰基 - 吡唑,其中各变量具有以下含义:R 1,R 2表示氢,硝基,卤素,氰基,rhodano,烷基,卤素烷基,烷氧基烷基,烯基,炔基, - OR 5,-OCOR 6,-OSO 2 R 6,-SH,-S(O)n R 7,-SO 2 OR 5,-SO 2 NR 5 R 8,-NR 8 SO 2 R 6或-NR 8 COR 6; R3代表氢,氰基,烷基,卤代烷基,-OR 7,-SR 7或-NR 7 R 10; R 4代表氢,任选取代的烷基,环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X代表氧或NR8; n等于0,1或2; R5代表氢,烷基,卤素烷基,烷氧基烷基,烯基或炔基; R6代表烷基或卤素烷基; R7代表烷基,卤代烷基,烷氧基烷基,烯基或炔基; R8代表氢或烷基; R9代表烷基,烯基,炔基,苯基或苄基; R10代表烷基,卤代烷基,烯基或炔基; Q表示在4位连接的任选取代的吡唑。还公开了用于农业的这些化合物的盐; 用于制备式(I)化合物的方法和中间产物,含有它们的试剂以及这些衍生物的用途或含有它们的试剂用于防治不希望的植物。
Abstract:
The invention concerns benzoyl derivatives of formula (I) in which the variables have the following meanings: R1, R2: hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, alkylsulphinyl, alkylsulphinyl halide, alkylsulphonyl, or C¿1?-C6 alkylsulphonyl halide; R?3¿: hydrogen, halogen or alkyl; R4, R5: hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the six last-mentioned groups can be substituted; X: O, S, NR9, CO or CR10R11; Y: O, S, NR12, CO or CR?13R14; R15¿: optionally substituted pyrazole which is bonded in position 4 and carries a hydroxy or sulphonyloxy group in position 5. The invention also concerns: the salts of these 3-heterocyclyl-substituted benzoyl derivatives which can be used for agricultural purposes; processes and intermediate products for preparing these substances; agents containing them; and the use as herbicides of these derivatives or agents containing them.
Abstract:
Process for the production of substituted phenylpyridines having formula (I), characterized by the fact that substituted pyridine having formula (II) is made to react with an aryl compound having formula (III).
Abstract:
The invention concerns pyridyl-phenyl- and benzylethers of formula (I), and their salts and N-oxides, in which the substituents and indices have the following meanings: Q is C(CO2CH3)=CHCH3, C(CO2CH3)=CHOCH3, C(CONH2)=NOCH3, C(CO2CH3)=NOCH3, C(CONHCH3)=NOCH3 or N(OCH3)-CO2CH3; n is 0 or 1; R1 is hydrogen or an organic group bonded via a carbon atom; R2 is hydrogen, cyano, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; R3 is hydrogen, halogen, C¿1?-C4 alkyl or C1-C2 alkyl halide; x is 0, 1 or 2; R?4¿ is cyano, nitro, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; y is 0, 1, 2 or 3; and R5 is cyano, halogen, C¿1?-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy. The invention further concerns a process and intermediate products for preparing these substances and their use.
Abstract:
The invention concerns pyridylacetic acid derivatives of formula (I), in which the substituents and the index have the following meanings: X - NOCH3, CHOCH3, CHCH3 and CHCH2CH3; Y - oxygen or NR', R' representing hydrogen or alkyl; R - cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 or 2; R1 is hydrogen and alkyl; R2 - hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkylamino or dialkylamino; R3 - hydrogen, cyano, nitro, hydroxy, amino, halogen; or optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino,aryl, aryloxy, arylthio,arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, and N-hetaryl-N-alkylamino; R4 - hydrogen, optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkylsulphonyl, cycloalkyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl, or hetarylsulphonyl. Also disclosed are the salts of the above derivatives,and methods and intermediate products for producing them and agents containing them.
Abstract:
The present invention relates to a method of combating animal pests which comprises contacting the animal pest, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal at- tack or infestation, with a pesticidally effective amount of at least one 1-(1 ,2-diphenyl- ethyl)-3-(2-hydroxyethyl)-thiourea compound I or an agriculturally acceptable salt thereof, wherein m is 0 to 5, n is 0 to 5, R3 and R4 are H or optionally substituted alkyl, haloalkyl, cycloalkyl, phenyl or benzyl, R7, R8, R9 and R10 are H or optionally substituted C1-C6-alkyl, C1-C6-haloalkyl, C1-C6- alkylamino, C1-C6-alkoxy, C3-C6-cycloalkyl, phenyl or benzyl and the variables R1, R2, R5 and R6 are as defined in the claims. The invention relates also to a method for protecting crops from attack or infestation by animal pests, a method for protecting non-living materials from attack or infestation by animal pests, novel 1-(1 ,2-diphenyl-ethyl)-3-(2-hydroxyethyl)-thiourea compounds I and their agriculturally acceptable salts as well as to an agricultural composition comprising a 1-(1 ,2-diphenyl-ethyl)-3-(2-hydroxyethyl)-thiourea compound I or a salt thereof.
Abstract:
The present invention relates to 1-(imidazolin-2-yl)amino-1,2-diphenylethane compounds of the formula I and their agriculturally acceptable salts, wherein A is a radical of the formula A1 or A2. The invention relates also to agricultural compositions and to seed comprising at least one compound I and/or a salt thereof, as well as a method of combating animal pests, a method for protecting crops from attack or infestation by animal pests and a method for protecting non-living materials from attack or infestation by animal pests, a method for the protection of seeds from animal pests and of the seedlings' roots and shoots from animal pests by applying a pesticidally effective amount of at least one 1-(imidazolin-2-yl)amino-1 ,2- diphenylethane compound I and/or a salt thereof.