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    SULFONIUM DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS
    11.
    发明公开
    SULFONIUM DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS 审中-公开
    锍衍生物和它们作为递延ACIDS

    公开(公告)号：EP2288599A1

    公开(公告)日：2011-03-02

    申请号：EP09761637.9

    申请日：2009-06-02

    Applicant: BASF SE

    Inventor： NISHIMAE, Yuichi ,  ASAKURA, Toshikage ,  YAMATO, Hitoshi

    IPC: C07D327/08 ,  C07D339/08 ,  G03F7/00

    CPC classification number: C07D339/08 ,  C07D327/08

    Abstract: Compounds of the formula (I), wherein R
    1 , R
    2 and R
    3 for example are hydrogen, halogen, CN, C
    1 -C
    18 alkyl, C
    1 -C
    10 haloalkyl, (CO)R
    8 , (CO)OR
    4 , or (CO)NR
    5 R
    6 ; Y is O, S or CO; D
    2 , D
    3 and D
    4 for example are a direct bond, O, S, NR
    7 , CO, O(CO), (CO)O, S(CO), (CO)S, NR
    7 (CO), (CO)NR
    7 , SO, SO
    2 , or OSO
    2 , C
    1 -C
    18 alkylene, C
    3 -C
    30 cycloalkylene, C
    2 -C
    12 alkenylene, C
    4 -C
    30 cycloalkenylene, Ar
    1 ; Ar
    1 , Ar
    2 and Ar
    3 are for example phenylene, R
    4 , R
    5 , R
    6 , R
    7 and R
    8 are for example hydrogen, C
    3 -C
    30 cycloalkyl, C
    1 -C
    18 alkyl, C
    1 -C
    10 haloalkyl, C
    2 -C
    12 alkenyl, C
    4 -C
    30 cycloalkenyl, phenyl-C
    1 C
    3 -alkyl; X
    - is Formulae (IA), (IB) or (IC); R
    10 is for example C
    1 -C
    18 alkyl, C
    1 -C
    10 haloalkyl, camphoryl, phenyl-C
    1 -C
    3 alkyl, C
    3 -C
    30 cycloalkyl; and R
    11 , R
    12 , R
    13 , R
    14 and R
    15 are for example C
    1 -C
    10 haloalkyl; are useful as polymerizable photolatent acids.

    OXIME ESTER PHOTOINITIATORS
    14.
    发明公开
    OXIME ESTER PHOTOINITIATORS 有权
    OXIME酯摄影师

    公开(公告)号：EP2847167A1

    公开(公告)日：2015-03-18

    申请号：EP13721682.6

    申请日：2013-05-06

    Applicant: BASF SE

    Inventor： NISHIMAE, Yuichi ,  KURA, Hisatoshi ,  KUNIMOTO, Kazuhiko ,  YAMAGAMI, Ryuhei ,  TANAKA, Keita

    IPC: C07D209/88 ,  G03F7/031

    CPC classification number: G03F7/027 ,  C07D209/86 ,  C07D209/88 ,  C08F122/20 ,  C09D135/02 ,  G02B5/20 ,  G03F7/0007 ,  G03F7/031 ,  G03F7/033 ,  G03F7/20 ,  G03F7/2002 ,  G03F7/2037 ,  G03F7/26 ,  G03F7/30

    Abstract: Oxime ester compounds of the formula V wherein Z 2 is for example unsubstituted or substituted C 7 -C 20 aroyl; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 for example are hydrogen, halogen, or unsubstituted or substituted C 1 -C 20 alkyl, unsubstituted or substituted C 6 -C 20 aryl, or unsubstituted or substituted C 4 -C 20 heteroaryl; R 10 for example is hydrogen, halogen, OR 16 , unsubstituted or substituted C 1 -C 20 alkyl; R 14 is for example unsubstituted or substituted C 6 -C 20 aryl or C 3 -C 20 heteroaryl Q 3 is for example phenylene; L is for example O-alkylene-O-; R 15 is for example hydrogen or C 1 -C 20 alkyl; R 20 is for example hydrogen, or unsubstituted or substituted C 1 -C 20 alkyl; are effective photoinitiators.

    Abstract translation: 式I，II，III，IV或V的肟酯化合物，其中Z为例如（式A）; Z 1为NO 2，未取代或取代的C 7 -C 20芳酰基或未取代或取代的C 4 -C 20杂芳酰基; 条件是至少一个Z 1不是NO 2; Z 2例如为未取代的或取代的C 7 -C 20芳酰基; 例如R 1，R 2，R 3，R 4，R 5和R 6为氢，卤素或未取代或取代的C 1 -C 20烷基，未取代或取代的C 6 -C 20芳基或未取代或取代的C 4 - C20杂芳基; 例如R 9，R 10，R 11，R 12和R 13是氢，卤素，OR 16，未取代或取代的C 1 -C 20烷基; 条件是R 9和R 13既不是氢也不是氟; R 14例如为未取代或取代的C 6 -C 20芳基或C 3 -C 20杂芳基，Q为例如C 6 -C 20亚芳基或C 3 -C 20杂亚芳基; Q 1是-C 1 -C 20亚烷基-CO-; Q 2是萘并萘; Q 3例如是亚苯基; L例如是O-亚烷基-O-; R 15例如是氢或C 1 -C 20烷基; R 20例如为氢，或未取代或取代的C 1 -C 20烷基; 是有效的光引发剂。

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