NEW ABSORBER FOR ORGANIC HETEROJUNCTION SOLAR CELLS
    5.
    发明公开
    NEW ABSORBER FOR ORGANIC HETEROJUNCTION SOLAR CELLS 审中-公开
    NEER ABSORBERFÜRORGANISCHE HETEROVERBINDUNGS-SOLARZELLEN

    公开(公告)号:EP3036782A1

    公开(公告)日:2016-06-29

    申请号:EP14750740.4

    申请日:2014-08-14

    Applicant: BASF SE

    Abstract: The present invention relates to a photoactive material comprising a donor substance and an acceptor substance, wherein the donor substance comprises or consists of one or more compounds of formula (I) described below, or the acceptor substance comprises or consists of one or more compounds of formula (I) described below, or the donor substance comprises or consists of a first compound of formula (I) described below and the acceptor substance comprises a second compound of formula (I) described below with the proviso that the first and second compound are not the same, as well as to an organic solar cell or photodetector comprising said photoactive material. The present invention also relates to a photoelectric conversion device comprising or consisting of two or more organic solar cells comprising said photoactive material and to compounds of formula (I) as described below for use as donor substance or as acceptor substance in a photoactive material.

    Abstract translation: 本发明涉及包含供体物质和受体物质的光活性材料,其中供体物质包含一种或多种下述式(I)化合物或由其组成,或受体物质包含或由一种或多种 式(I)或供体物质包含下述式(I)的第一化合物或由其组成,受体物质包含下述第二化合物(I),条件是第一和第二化合物为 不同的是,以及包含所述光活性材料的有机太阳能电池或光电探测器。 本发明还涉及一种光电转换装置,其包含两种或多种包含所述光活性材料的有机太阳能电池或由以下所述的式(I)化合物或用作光活性材料中的受体物质或作为受体物质的有机太阳能电池组成。

    LATENT ACIDS AND THEIR USE
    10.
    发明公开
    LATENT ACIDS AND THEIR USE 审中-公开
    LATENTESÄURENUND IHRE VERWENDUNG

    公开(公告)号:EP2539316A1

    公开(公告)日:2013-01-02

    申请号:EP11702482.8

    申请日:2011-02-10

    Applicant: BASF SE

    Abstract: The invention pertains to a compound generating an acid of the formula (I) or (II), for instance corresponding sulfonium and iodonium salts, as well as corresponding sulfonyloximes, Formula (I) and Formula (II), wherein X is CH
    2 or CO; Y is O, NR
    4 , S, O(CO), O(CO)O, O(CO)NR
    4 , OSO
    2 , O(CS), or O(CS)NR
    4 ; R
    1 is for example C
    1 -C
    18 alkyl, C
    1 -C
    10 haloalkyl, C
    2 -C
    12 alkenyl, C
    4 -C
    30 cycloalkenyl, phenyl-C
    1 -C
    3 -alkyl, C
    3 -C
    30 cycloalkyl, C
    3 -C
    30 cycloalkyl-C
    1 -C
    18 alkyl, interrupted C
    2 -C
    18 alkyl, interrupted C
    3 -C
    30 cycloalkyl, interrupted C
    3 -C
    30 cycloalkyl-C
    1 -C
    18 alkyl, interrupted C
    4 -C
    30 cycloalkenyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or heteroaryl, all unsubstituted or are substituted; or R
    1 is NR
    12 R
    13 ; R
    2 and R
    3 are for example C
    3 -C
    30 cycloalkylene, C
    3 -C
    30 cycloalkyl-C
    1 -C
    18 alkylene, C
    1 -C
    18 alkylene, C
    1 -C
    10 haloalkylene, C
    2 -C
    12 alkenylene, C
    4 -C
    30 cycloalkenylene, phenylene, naphthylene, anthracylene, phenanthrylene, biphenylene or heteroarylene; all unsubstituted or substituted; R
    4 is for example C
    3 -C
    30 cycloalkyl, C
    3 -C
    30 cycloalkyl-C
    1 -C
    18 alkyl, C
    1 -C
    18 alkyl, C
    1 -C
    10 haloalkyl, C
    2 -C
    12 alkenyl, C
    4 -C
    30 cycloalkenyl, phenyl-C
    1 -C
    3 -alkyl; R
    12 and R
    13 are for example C
    3 -C
    30 cycloalkyl, C
    3 -C
    30 cycloalkyl-C
    1 -C
    18 alkyl, C
    1 -C
    18 alkyl, C
    1 -C
    10 haloalkyl, C
    2 -C
    12 alkenyl, C
    4 -C
    30 cycloalkenyl, phenyl-C
    1 -C
    3 -alkyl, Ar, (CO)R
    15 , (CO)OR
    15 or SO
    2 R
    15 ; and Ar is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl or heteroaryl, all unsubstituted or substituted.

    Abstract translation: 本发明涉及产生式(I)或(II)的酸的化合物,例如相应的锍盐和碘鎓盐,以及相应的磺酰肟,式(I)和式(II),其中X是CH 2或CO ; Y是O,NR4,S,O(CO),O(CO)O,O(CO)NR4,OSO2,O(CS)或O(CS)NR4; R1是例如C1-C18烷基,C1-C10卤代烷基,C2-C12链烯基,C4-C30环烯基,苯基-C1-C3-烷基,C3-C30环烷基,C3-C30环烷基-C1-C18烷基,间断的C 2 -C 18烷基,间断的C 3 -C 30环烷基, 间断的C 3 -C 30环烷基-C 1 -C 18烷基,间断的C 4 -C 30环烯基,苯基,萘基,蒽基,菲基,联苯基,芴基或杂芳基,全部未取代或被取代; 或R1为NR12R13; R 2和R 3例如为C 3 -C 30亚环烷基,C 3 -C 30环烷基-C 1 -C 18亚烷基,C 1 -C 18亚烷基,C 1 -C 10卤代亚烷基,C 2 -C 12亚烯基,C 4 -C 30亚环烯基,亚苯基,亚萘基,亚蒽基,亚菲基,亚联苯基或亚杂芳基。 全部未取代或取代; R4是例如C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12链烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基; R 12和R 13例如为C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基,Ar,(CO)R 15( CO)OR15或SO2R15; 并且Ar是苯基,联苯基,芴基,萘基,蒽基,菲基或杂芳基,全部是未取代或取代的。

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