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11.发明公开VERFAHREN ZUR HERSTELLUNG VON AMEISENSÄURE DURCH UMSETZUNG VON KOHLENDIOXID MIT WASSERSTOFF 有权用于生产FORMIC的二氧化碳与氢反应
公开(公告)号：EP2588439A1
公开(公告)日：2013-05-08
申请号：EP11726423.4
申请日：2011-06-21
Applicant: BASF SE
Inventor： SCHAUB, Thomas , FRIES, Donata Maria , PACIELLO, Rocco , MOHL, Klaus-Dieter , SCHÄFER, Martin , RITTINGER, Stefan , SCHNEIDER, Daniel
Abstract: A process is proposed for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst containing an element from group 8, 9 or 10 of the Periodic Table, of a tertiary amine containing at least 12 carbon atoms per molecule, and of a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates, which are subsequently cleaved thermally, the workup of the outputs (3) from the hydrogenation reactor (I) being performed with addition of water, and this increasing the partition coefficient of the catalyst between the upper phase (4) and the lower phase.
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公开(公告)号：EP3114104A1
公开(公告)日：2017-01-11
申请号：EP15707978.1
申请日：2015-03-06
Applicant: BASF SE
Inventor： HICKMANN, Volker , RÜDENAUER, Stefan , DEHN, Martine , KELLER, Andreas , RENZ, Stephanie , SCHNEIDER, Daniel
IPC: C07C45/29 , C07C49/407 , A61Q11/00 , A61K8/35
CPC classification number: C07C45/512 , A61K8/35 , A61K2800/10 , A61Q11/00 , A61Q19/00 , B01J23/8892 , C07C45/29 , C07C45/298 , C07C49/407 , C07C2601/14
Abstract: The present invention relates to a method for reacting isopulegol to menthone in the gas phase, using a copper catalyst, and to the use of the reaction products so produced as additives in foods, cosmetics, pharmaceutical products, tobacco formulations, household products and laundry care products.
Abstract translation: 本发明涉及在气相中异丙醇与薄荷酮反应的方法以及如此制备的反应产物作为食品，化妆品，药物，烟草制剂，家用产品和洗衣护理产品中的添加剂的用途。
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公开(公告)号：EP2794540A1
公开(公告)日：2014-10-29
申请号：EP12791502.3
申请日：2012-11-29
Applicant: BASF SE
Inventor： BASLER, Peter , RITTINGER, Stefan , SCHNEIDER, Daniel , FRIES, Donata Maria , MOHL, Klaus-Dieter , TELES, Joaquim Henrique , SCHÄFER, Martin , PASCHOLD, Jürgen
CPC classification number: C07C51/44 , C07C51/02 , C07C51/412 , C07C53/02 , C07C53/06
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.
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公开(公告)号：EP2794539A1
公开(公告)日：2014-10-29
申请号：EP12809717.7
申请日：2012-12-14
Applicant: BASF SE
Inventor： SCHNEIDER, Daniel , MOHL, Klaus-Dieter , SCHÄFER, Martin , FRIES, Donata, maria , TELES, Joaquim, Herinque , BASSLER, Peter , RITTINGER, Stefan , SCHRAUB, Thomas
CPC classification number: C07C51/02 , C07C51/09 , C07C51/41 , C07C51/412 , C07C51/48 , C07C53/02 , C07C53/06
Abstract: The invention relates to a method for obtaining formic acid by thermally separating a flow containing formic acid and a tertiary amine (I), wherein a liquid flow containing formic acid, tertiary amine (I), and water is produced by bringing together a tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed, and formic acid is removed from the obtained liquid flow by means of distillation in a distillation device, wherein the removed flow containing water and organic decomposition products of the tertiary amine (I) is separated into two liquid phases, the upper liquid phase is removed, and the lower liquid phase containing water is fed back to the formic acid source.
Abstract translation: 本发明涉及一种通过热分离含甲酸和叔胺（I）的流动物来获得甲酸的方法，其中通过将叔胺（I）和叔胺 （I）和甲酸源的存在下，除去叔胺（I）的水和有机分解产物，并通过蒸馏装置中的蒸馏从所得液体流中除去甲酸，其中 将含有水的被除去的流体和叔胺（I）的有机分解产物分离成两个液相，将上层液相除去，将含有水的下层液体回流至甲酸源。
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15.发明公开VERFAHREN ZUR HERSTELLUNG VON AMEISENSÄURE DURCH UMSETZUNG VON KOHLENDIOXID MIT WASSERSTOFF 有权VERFAHREN ZUR HERSTELLUNG VONAMEISENSÄUREDURCH UMSETZUNG VON KOHLENDIOXID MIT WASSERSTOFF
公开(公告)号：EP2588438A1
公开(公告)日：2013-05-08
申请号：EP11726411.9
申请日：2011-06-16
Applicant: BASF SE
Inventor： SCHAUB, Thomas , FRIES, Donata Maria , PACIELLO, Rocco , MOHL, Klaus-Dieter , SCHÄFER, Martin , RITTINGER, Stefan , SCHNEIDER, Daniel
Abstract: A process is proposed for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst containing an element from group 8, 9 or 10 of the Periodic Table, of a tertiary amine containing at least 12 carbon atoms per molecule, and of a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols and butanols, and water, to form formic acid/amine adducts as intermediates, which are subsequently cleaved thermally, with workup of the outputs (3) from the hydrogenation reactor (I) in several process steps, a stream (13) comprising tertiary amine from the workup being used as a selective solvent for the catalyst.
Abstract translation: 提出了一种通过在含有元素周期表第8,9或10族元素的催化剂存在下在氢化反应器（I）中使二氧化碳（1）与氢气（2）反应来制备甲酸的方法， 每分子包含至少12个碳原子的叔胺和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和水的极性溶剂以形成甲酸/胺加合物作为中间体，其随后被热裂解 在几个工艺步骤中处理来自氢化反应器（I）的输出物（3），包含来自处理的叔胺的物流（13）用作催化剂的选择性溶剂。
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Patent Agency Ranking
公开(公告)号：EP3114104B1
公开(公告)日：2019-07-17
申请号：EP15707978.1
申请日：2015-03-06
Applicant: BASF SE
Inventor： HICKMANN, Volker , RÜDENAUER, Stefan , DEHN, Martine , KELLER, Andreas , RENZ, Stephanie , SCHNEIDER, Daniel
IPC: C07C45/29 , C07C49/407 , A61Q11/00 , A61K8/35
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公开(公告)号：EP3386919A1
公开(公告)日：2018-10-17
申请号：EP16809745.9
申请日：2016-12-07
Applicant: BASF SE
Inventor： VAUTRAVERS, Nicolas , TELES, Joaquim, Henrique , PELZER, Ralf , SCHNEIDER, Daniel , GARLICHS, Florian , KELLER, Andreas , PARVULESCU, Andrei-Nicolae , MÜLLER, Ulrich , CHATURVEDULA, Sumana
CPC classification number: C01B39/12 , B01J29/86 , B01J2229/183 , B01J2229/34 , B01J2229/37 , C01B39/026 , C01P2002/70 , C01P2002/82 , C01P2002/84 , C01P2006/12 , C07C45/54 , C07C67/39 , C07C69/07 , C07C47/21
Abstract: An incipient wetness impregnation method for preparing a tin-containing zeolitic material having framework type BEA, a novel tin-containing zeolitic material having framework type BEA and its use.
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公开(公告)号：EP2794539B1
公开(公告)日：2015-05-27
申请号：EP12809717.7
申请日：2012-12-14
Applicant: BASF SE
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公开(公告)号：EP2445860A2
公开(公告)日：2012-05-02
申请号：EP10725137.3
申请日：2010-06-11
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , MOHL, Klaus-Dieter , SCHNEIDER, Daniel , SCHÄFER, Martin , RITTINGER, Stefan
IPC: C07C51/00
CPC classification number: C07C51/00 , B01J31/0237 , B01J31/24 , B01J31/2414 , B01J2231/625 , B01J2531/821 , C07C51/44 , Y02P20/582 , C07C53/02
Abstract: The invention relates to a method for producing formic acid by hydrogenation of carbon dioxide in the presence of a catalyst which contains an element of the 8th, 9th or 10th group of the periodic system, a tertiary amine and a polar solvent, at a pressure of 0.2 to 30 MPa abs and a temperature of 20 to 200°C, thereby producing two liquid phases, and separation of the two liquid phases. The liquid phase (B) enriched by the tertiary amine is returned to the hydrogenation reactor and the formic acid/amine addition product from the liquid phase (A) enriched by the formic acid/amine addition product and the polar solvent is thermally separated into free formic acid and free tertiary amine in a distillation unit and the tertiary amine released during separation and the polar solvent are returned to the hydrogenation reactor.
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20.发明公开VERFAHREN ZUR HERSTELLUNG VON METHYLFORMIAT DURCH UMSETZUNG VON METHANOL MIT KOHLENMONOXID IN GEGENWART EINES KATALYSATORSYSTEMS, DAS ALKALIFORMIAT UND ALKALIALKOHOLAT ENTHÄLT 有权PROCESS FOR通过甲醇与一氧化碳在催化剂体系存在下反应生产甲酸甲酯，所述碱金属的甲酸盐和碱金属CONTAINS
公开(公告)号：EP2922815A1
公开(公告)日：2015-09-30
申请号：EP13795269.3
申请日：2013-11-26
Applicant: BASF SE
Inventor： SCHNEIDER, Daniel , MOHL, Klaus-Dieter , SCHÄFER, Martin , PASCHOLD, Jürgen , TELES, Joaquim Henrique , RITTINGER, Stefan
Abstract: The invention relates to a method for producing methyl formate by carbonylating methanol with carbon monoxide in a carbonylation reactor in the presence of a catalyst system containing alkali formate and alkali alcoholate, thereby obtaining a reaction mixture (R
G ) which contains methyl formate, alkali formate, alkali alcoholate and optionally unreacted methanol and unreacted carbon monoxide and which is removed from the carbonylation reactor. The reaction mixture (R
G ) contains at least 0.5 wt.% alkali alcoholate, based on the total weight of the reaction mixture (R
G ), and the molar ratio of alkali formate to alkali alcoholate in the reaction mixture (R
G ) is greater than 1.Abstract translation: 本发明涉及一种通过在催化剂体系包含碱格式和碱金属醇，从而获得反应混合物（RG），其含有甲酸甲酯，碱格式的存在下甲醇羰基与一氧化碳在羰基化反应器中生产甲酸甲酯的方法， 这是从羰基化反应器中除去碱金属醇以及任选的未反应的甲醇和未反应的一氧化碳和全部。 将反应混合物（RG）含有至少0.5重量％的醇化物碱，基于反应混合物（RG），并且碱格式在反应混合物中的碱性醇化物（RG）的摩尔比的总重量计大于1 ，
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